Floriana Tuna

2019

A [13]rotaxane assembled via a palladium molecular capsule

Ferrando Soria, J., Fernandez Mato, A., Asthana, D., Nawaz, S., Vitorica-Yrezabal, I., Whitehead, G., Muryn, C., Tuna, F., Timco, G., Burton, N. & Winpenny, R., 16 Aug 2019, In: Nature Communications. 10, 3720.

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A Large Barrier Single-Molecule Magnet Without Magnetic Memory

Giansiracusa, M., Al-Badran, S., Kostopoulos, A., Whitehead, G., Collison, D., Tuna, F., Winpenny, R. & Chilton, N., 2019, In: Dalton Transactions. 48, p. 10795-10798

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Back-bonding between an electron-poor, high-oxidation-state metal and poor π-acceptor ligand in a uranium(V)–dinitrogen complex

Lu, E., Atkinson, B., Wooles, A., Boronski, J., Doyle, L., Tuna, F., Cryer, J., Cobb, P., Vitorica-Yrezabal, I., Whitehead, G., Kaltsoyannis, N. & Liddle, S., 19 Aug 2019, In: Nature Chemistry. 11, p. 806-811

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Capture of nitrogen dioxide and conversion to nitric acid in a porous metal-organic framework

Li, J., Han, X., Zhang, X., Sheveleva, A., Cheng, Y., Tuna, F., Mcinnes, E., McPherson, L. J. M., Teat, S. J., Daemen, L. L., Ramirez-Cuesta, A. J., Schroder, M. & Yang, S., 22 Nov 2019, In: Nature Chemistry. 11, p. 1085-1090

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Engineering electronic structure to prolong relaxation times in molecular qubits by minimising orbital angular momentum

Ariciu, A.-M., Woen, D. H., Huh, D. N., Nodaraki, L., Kostopoulos, A., Goodwin, C., Chilton, N., Mcinnes, E., Winpenny, R., Evans, W. J. & Tuna, F., 2019, In: Nature Communications. 10, 3330.

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Formation of an Interlocked Double-Chain from an Organic-Inorganic [2]Rotaxane

Ferrando-soria, J., Fernandez, A., Vitorica-yrzebal, I., Asthana, D., Muryn, C., Tuna, F., Timco, G. A. & Winpenny, R. E. P., 2019, In: Chemical Communications. 55, 20, p. 2960-2963 4 p.

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High-throughput chemical and chemoenzymatic approaches to saccharide-coated magnetic nanoparticles for MRI

Fallows, T., McGrath, A., Silva, J., McAdams, S. G., Marchesi, A., Tuna, F., Flitsch, S., Tilley, R. D. & Webb, S., 2019, In: Nanoscale Advances. 1, p. 3597-3606

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Iodine adsorption in a redox-active metal-organic framework: Electrical conductivity induced by host-guest charge-transfer

Zhang, X., Silva, I. D., Fazzi, R., Sheveleva, A., Han, X., Spencer, B., Sapchenko, S., Tuna, F., Mcinnes, E., Li, M., Yang, S. & Schroder, M., 2019, In: Inorganic Chemistry. 58, p. 14145-14150 6 p.

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Photolytic and Reductive Activations of 2‐Arsaethynolate in a Uranium‐Triamidoamine Complex: Decarbonylative Arsenic Group‐Transfer Reactions and Trapping of a Highly Bent and Reduced Form

Magnall, R., Balazs, G., Lu, E., Kern, M., Van Slageren, J., Tuna, F., Wooles, A., Scheer, M. & Liddle, S., 2019, In: Chemistry – A European Journal. 25, 62, p. 14246-14252

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Photo-redox reactivity of titanium-oxo clusters: Mechanistic insight into a two-electron intramolecular process, and structural characterisation of mixed-valent Ti(iii)/Ti(iv) products

Krämer, T., Tuna, F. & Pike, S. D., 2019, In: Chemical Science. 10, 28, p. 6886-6898 13 p.

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Preparation of Heterobimetallic Ketimido-Actinide-Molybdenum Complexes

Ayres, A. J., Wooles, A., Zegke, M., Tuna, F. & Liddle, S., 2019, In: Inorganic Chemistry. 58, p. 13077-13089

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Quantitative production of butenes from biomass-derived γ-valerolactone catalysed by hetero-atomic MFI zeolite

Lin, L., Sheveleva, A., Silva, I. D., Parlett, C., Tang, Z., Liu, Y., Fan, M., Han, X., Carter, J., Tuna, F., Mcinnes, E., Cheng, Y., Daemen, L. L., Rudic, S., Ramirez-Cuesta, A. J., Tang, C. C. & Yang, S., 16 Dec 2019, In: Nature Materials. 19, p. 86-93

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Thorium- and Uranium-Azide Reductions: A Transient Dithorium-Nitride Versus Isolable Diuranium-Nitrides

Du, J., King, D. M., Chatelain, L., Lu, E., Tuna, F., Mcinnes, E. J. L., Wooles, A., Laurent, M. & Liddle, S., 2019, In: Chemical Science. 10, p. 3738-3745

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Transferability of the anisotropic spin model coupling parameters in a family of doped chromium-based molecular rings

Antkowiak, M., Kamieniarz, G., Timco, G. A., Tuna, F. & Winpenny, R. E. P., 1 Jun 2019, In: Journal of Magnetism and Magnetic Materials. 479, p. 166-169 4 p.

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Trapping of a Highly Bent and Reduced Form of 2-Phosphaethynolate in a Mixed-Valence Diuranium-Triamidoamine Complex

Liddle, S., Magnall, R., Balazs, G., Lu, E., Tuna, F., Wooles, A. & Scheer, M., 24 May 2019, In: Angewandte Chemie International Edition. 58, 30, p. 10215-10219

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2018

Actinide-Pnictide (An-Pn) Bonds Spanning -Non-Metal, -Metalloid, and - Metal Combinations (An = U, Th; Pn = P, As, Sb, Bi)

Rookes, T., Wildman, E., Balazs, G., Gardner, B., Wooles, A., Gregson, M., Tuna, F., Scheer, M. & Liddle, S., 22 Jan 2018, In: Angewandte Chemie - International Edition. 57, 5, p. 1332-1336 5 p.

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Actinide-Transition Metal Bonding in Heterobimetallic Uranium- and Thorium-Molybdenum Paddlewheel Complexes

Ayres, A., Zegke, M., Ostrowski, J., Tuna, F., Mcinnes, E. J. L., Wooles, A. & Liddle, S., 2018, In: Chemical Communications.

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Anion-Induced N-doping of Naphthalenediimide Polymer Semiconductor in Organic Thin Film Transistors

Han, Y., Fei, Z., Lin, Y.-H., Martin, J., Tuna, F., Anthopoulos, T. D. & Heeney, M., 2018, In: npj Flexible Electronics. 2, 11.

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Catalytic Dinitrogen Reduction to Ammonia at a Triamidoamine- Titanium Complex

Doyle, L., Wooles, A., Jenkins, L. C., Tuna, F., Mcinnes, E. & Liddle, S., 15 May 2018, In: Angewandte Chemie - International Edition. 57, 21, p. 6314-6318 4 p.

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Chromium Chains as Polydentate Fluoride Ligands for Actinides and Group IV Metals

Leng, J.-D., Kostopoulos, A., Isherwood, L., Ariciu, A.-M., Tuna, F., Vitorica-Yrezabal, I., Pritchard, R., Whitehead, G., Timco, G., Mills, D. & Winpenny, R., 14 May 2018, In: Dalton Transactions. 47, 18, p. 6361-6369

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Exploring Synthetic Routes to Heteroleptic U^III, U^IV and Th^IV Bulky Bis(silyl)amide Complexes

Goodwin, C., Tuna, F., Mcinnes, E. & Mills, D., 2018, In: European Journal of Inorganic Chemistry. 20-21

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Hybrid organic-inorganic rotaxanes, including a hetero-hybrid [3]rotaxane featuring two distinct heterometallic rings and a molecular shuttle

Timco, G., Fernandez Mato, A., Kostopoulos, A., Charlton, J. F., Lockyer, S., Hailes, T. R., Adams, R., Mcinnes, E., Tuna, F., Vitorica-Yrezabal, I., Whitehead, G. & Winpenny, R., 20 Aug 2018, In: Angewandte Chemie - International Edition. 57, 34, p. 10919-10922 3 p.

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Measurement of magnetic exchange in asymmetric lanthanide dimetallics: towards a transferable theoretical framework

Giansiracusa, M., Moreno Pineda, E., Hussain, R., Marx, R., Prada, M. M., Neugebauer, P., Al-Badran, S., Collison, D., Tuna, F., Slageren, J. V., Carretta, S., Guidi, T., Mcinnes, E., Winpenny, R. & Chilton, N., 2018, In: American Chemical Society. Journal .

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Reversible adsorption of nitrogen dioxide within a robust porous metal-organic framework

Han, X., Godfrey, H. G. W., Briggs, L., Davies, A. J., Cheng, Y., Daemen, L. L., Sheveleva, A. M., Tuna, F., Mcinnes, E. J. L., Sun, J., Drathen, C., George, M. W., Ramirez-Cuesta, A. J., Thomas, K. M., Yang, S. & Schroder, M., 11 Jun 2018, In: Nature Materials. 17, 8, p. 691-696 6 p.

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Ricinoleic Acid as a Green Alternative to Oleic Acid in the Synthesis of Doped Nanocrystals

Mensah, M. B., McNaughter, P. D., McAdams, S. G., Tuna, F., Lewis, D. J., Awudza, J. A. M., Revaprasadu, N. & O'Brien, P., Dec 2018, In: ChemistrySelect. 3, 48, p. 13548-13552 5 p.

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Synthesis, Crystal Structures, and Magnetic Properties of New Hexanuclear Mn^III ₂Ln^III ₄ Complexes: SMM Behavior of the Terbium(III) Analogue

Roy, S., Ghosh, S., Martins, D. O. T. A., Tuna, F. & Mohanta, S., 13 Dec 2018, In: European Journal of Inorganic Chemistry. 2018, 48, p. 5191-5202 12 p.

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The synthesis of a monodisperse quaternary ferrite (FeCoCrO₄) from the hot injection thermolysis of the single source precursor [CrCoFeO(O₂C^{: T}Bu)₆(HO₂C^tBu)₃]

Abdulwahab, K. O., Malik, M. A., O'Brien, P., Vitorica-Yrezabal, I. J., Timco, G. A., Tuna, F. & Winpenny, R. E. P., 2018, In: Dalton Transactions. 47, 2, p. 376-381 6 p.

Research output: Contribution to journal › Article › peer-review

Uranium(III)-Carbon Multiple Bonding Supported by Arene δ-Bonding in Mixed-Valence Hexauranium Nanometre-Scale Rings

Wooles, A., Mills, D., Tuna, F., Mcinnes, E., Law, G., Fuller, A., Kremer, F., Ridgway, M., Lewis, W., Gagliardi, L., Vlaisavljevich, B. & Liddle, S., 2018, In: Nature Communications. 9, 2097.

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2017

Assessing Crystal Field and Magnetic Interactions in Diuranium-‐μ-‐ Chalcogenide Triamidoamine Complexes With UIV-‐E-‐UIV Cores (E = S, Se, Te): Implications for Determining the Presence or Absence of Actinide-‐Actinide Magnetic Exchange

Gardner, B., King, D. M., Tuna, F., Wooles, A., Chilton, N. & Liddle, S., 2017, In: Chemical Science. 8, p. 6207-6217 10 p.

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A Sub-Kelvin Cryogen-Free EPR System

Melhuish, S., Stott, C., Ariciu, A.-M., Martinis, L., Mcculloch, M., Piccirillo, L., Collison, D., Tuna, F. & Winpenny, R., 2017, In: JOURNAL OF MAGNETIC RESONANCE. 282

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Complexes of uranium and thorium with multiple bonds to tetryl and pnictide centers

Liddle, S., Seed, J., Gregson, M., Wooles, A., Tuna, F. & McInnes, E., 2 Apr 2017, In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 253

Research output: Contribution to journal › Meeting Abstract › peer-review

Crystalline Diuranium-Phosphinidiide and -μ-Phosphido Complexes with Symmetric and Asymmetric UPU Cores

Rookes, T., Gardner, B., Balazs, G., Gregson, M., Tuna, F., Wooles, A., Scheer, M. & Liddle, S., 21 Aug 2017, In: Angewandte Chemie - International Edition. 56, 35, p. 10495-10500 6 p.

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Double Reduction of 4,4′-Bipyridine and Reductive Coupling of Pyridine by Two Thorium(III) Single-Electron Transfers

Formanuik, A., Ortu, F., Liu, J., Nodaraki, L., Tuna, F., Kerridge, A. & Mills, D., 16 Feb 2017, In: Chemistry: A European Journal. 23, 10, p. 2290-2293 4 p.

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Dual Functionalization of Liquid-Exfoliated Semiconducting 2H-MoS2 with Lanthanide Complexes Bearing Magnetic and Luminescence Properties

Mcadams, S., Lewis, E. A., Brent, J. R., Haigh, S., Thomas, A., O'Brien, P., Tuna, F. & Lewis, D., 8 Nov 2017, In: Advanced Functional Materials. 27, 42, 1703646.

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Evidence for Single Metal Two Electron Oxidative Addition and Reductive Elimination at Uranium

Gardner, B. M., Kefalidis, C. E., Lu, E., Patel, D., Mcinnes, E., Tuna, F., Wooles, A., Maron, L. & Liddle, S., 2017, In: Nature Communications. 8, 1898.

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Evidence of Spin-Canting, Metamagnetism, Negative Coercivity, and Slow Relaxation in a Two-dimensional Network of {Mn6} Cages

Dendrinou-Samara, C., Walsh, J., Muryn, C., Collison, D., Winpenny, R. & Tuna, F., 2017, In: European Journal of Inorganic Chemistry.

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Heterometallic Co^II-Co^III-M^II alkoxido-bridged heptanuclear motifs (M=Cu, Zn). Syntheses, crystal structures and magnetic properties

Martin, E., Tudor, V., Madalan, A. M., Maxim, C., Tuna, F., Lloret, F., Julve, M. & Andruh, M., 2017, In: Inorganica Chimica Acta.

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High magnetic relaxivity in a fluorescent CdSe/CdS/ZnS quantum dot functionalized with MRI contrast molecules

Mcadams, S., Lewis, D., Mcnaughter, P., Lewis, E., Haigh, S., O'Brien, P. & Tuna, F., 2017, In: Chemical Communications.

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In Situ Spectroelectrochemical Investigations of Ru^II Complexes with Bispyrazolyl Methane Triarylamine Ligands

Hua, C., Abrahams, B. F., Tuna, F., Collison, D. & D'Alessandro, D. M., 2017, In: Australian Journal of Chemistry. 70, 5, p. 546-555 10 p.

Research output: Contribution to journal › Article › peer-review

Modulating Supramolecular Binding of Carbon Dioxide in a Redox-Active Porous Metal-Organic Framework

Lu, Z., Godfrey, H., Da Silva, I., Cheng, Y., Savage, M., Tuna, F., Mcinnes, E., Teat, S. J., Gagnon, K. J., Frogley, M. D., Manuel, P., Rudić, S., J. Ramirez-Cuesta, A., Easun, T. L., Yang, S. & Schroder, M., 2017, In: Nature Communications. 8, 14212.

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Molecular single-ion magnets based on lanthanides and actinides: Design considerations and new advances in the context of quantum technologies

McAdams, S. G., Ariciu, A. M., Kostopoulos, A. K., Walsh, J. P. S. & Tuna, F., 1 Sept 2017, In: Coordination Chemistry Reviews. 346, p. 216-239 24 p.

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New synthesis route for obtaining carbon-free hexagonal RE manganites via novel simple individual precursors. The interplay between magnetic and thermodynamic properties of hexagonal RMnO3 (R=Ho–Yb, Y)

Gavrikov, A., Koroteev, P., Ilyukhin, A., Efimov, N., Kostopoulos, A. K., Baranchikov, A., Tyurin, A., Kirdyankin, D., Gavrichev, K., Tuna, F. & Dobrokhotova, Z., 28 Jan 2017, In: Polyhedron. 122, p. 184-193

Research output: Contribution to journal › Article › peer-review

Rare Earth- and Uranium-Mesoionic Carbenes: A New Class of f-Block Carbene Complex Derived from an N-Heterocyclic Olefin

Liddle, S., Seed, J., Gregson, M., Tuna, F., Chilton, N., Wooles, A. & Mcinnes, E., 2017, In: Angewandte Chemie - International Edition.

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Redox-state dependent spectroscopic properties of porous organic polymers containing furan, thiophene, and selenophene

Hua, C., Woo, S., Rawal, A., Tuna, F., Hook, J. M., Collison, D. & D'Alessandro, D. M., 2017, In: Australian Journal of Chemistry. 70, 11, p. 1227-1234 8 p.

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Redox state manipulation of a tris(p-tetrazolylphenyl)amine ligand and its Mn2+ coordination frameworks

Hua, C., Ge, J.-Y., Tuna, F., Collison, D., Zuo, J.-L. & D'Alessandro, D. M., 2017, In: Dalton Transactions. 46, 9, p. 2998-3007

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Spectroelectrochemical properties of a Ru(ii) complex with a thiazolo[5,4-d]thiazole triarylamine ligand

Hua, C., Rizzuto, F. J., Zhang, X., Tuna, F., Collison, D. & D'Alessandro, D. M., 2017, In: New Journal of Chemistry. 41, 1, p. 108-114 7 p.

Research output: Contribution to journal › Article › peer-review

Synthesis and SMM behaviour of trinuclear versus dinuclear 3d–5f uranyl(V)–cobalt(II) cation–cation complexes

Chatelain, L., Tuna, F., Pécaut, J. & Mazzanti, M., 17 Jan 2017, In: Dalton Transactions. 46, 17, p. 5498-5502

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Terminal Uranium(V/VI)-Nitride Activation of Carbon Dioxide and Disulfide: Factors Governing Diverse and Well-Defined Cleavage and Redox Reactions

Cleaves, P., Kefalidis, C. E., Gardner, B., Tuna, F., Mcinnes, E., Lewis, W., Maron, L. & Liddle, S., 2017, In: Chemistry: A European Journal. 23, 12

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The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

Gregson, M., Lu, E., Mills, D., Tuna, F., Mcinnes, E., Hennig, C., Scheinost, A. C., McMaster, J., Lewis, W., Blake, A. J., Kerridge, A. & Liddle, S., 2017, In: Nature Communications. 8, 14137.

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Thorium redox chemistry and a new way to measure actinide covalency by pulsed EPR spectroscopy

Mills, D., McInnes, E., Tuna, F., Kerridge, A., Maron, L., Formanuik, A., Ariciu, A.-M., Ortu, F., Liu, J., Beekmeyer, R. & Castro, L., 2 Apr 2017, In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 253

Research output: Contribution to journal › Meeting Abstract › peer-review

Floriana Tuna

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