Jordi Bures

Search results

• 2023

  Bismuth‐Catalyzed Amide Reduction

  Yang, X., Kuziola, J., Béland, V. A., Busch, J., Leutzsch, M., Burés, J. & Cornella, J., 7 Jun 2023, (E-pub ahead of print) In: Angewandte Chemie International Edition.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Carboxamide 100%
  • Amide 100%
  • % Inhibition 50%
  • Alkene 50%
  • Donor 50%
  61 Downloads (Pure)

• Organic reaction mechanism classification using machine learning

  Bures, J. & Larrosa, I., 26 Jan 2023, In: Nature.. 613, p. 689–695

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Learning System 100%
  • Artificial Intelligence 100%
  • Deep Neural Network 100%
  • Organic Reaction 100%
  • Kinetics Type 66%
  412 Downloads (Pure)
• 2022

  A computational tool to accurately and quickly predict 19F NMR chemical shifts of molecules with fluorine–carbon and fluorine–boron bonds

  Dumon, A. S., Rzepa, H. S., Alamillo-Ferrer, C., Bures, J., Procter, R., Sheppard, T. D. & Whiting, A., 9 Aug 2022, In: Physical Chemistry Chemical Physics.

  Research output: Contribution to journal › Article › peer-review

• Kinetic Rationalization of Nonlinear Effects in Asymmetric Catalytic Cascade Reactions Under Curtin-Hammett Conditions

  Ali, C., Blackmond, D. G. & Bures, J., 28 Mar 2022, (Accepted/In press) In: ACS Catalysis.

  Research output: Contribution to journal › Article › peer-review

  • Cascade Reaction 100%
  • Reaction Step 66%
  • Enantiopurity 66%
  • Primary Structure 33%
  • Enantiomer 33%

• Organocatalytic Enantioselective α-Bromination of Aldehydes with N-Bromosuccinimide

  Hutchinson, G., Alamillo-Ferrer, C., Fernández-Pascual, M. & Burés, J., 17 Jun 2022, In: The Journal of organic chemistry.

  Research output: Contribution to journal › Article › peer-review
• 2021

  Chirality-Induced Catalyst Aggregation: Insights into Catalyst Speciation and Activity Using Chiral Aluminum Catalysts in Cyclic Ester Ring-Opening Polymerization

  Gesslbauer, S., Hutchinson, G., White, A. J. P., Burés, J. & Romain, C., 17 Mar 2021, In: ACS Catalysis. p. 4084-4093

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Chirality 100%
  • Ring Opening Polymerisation 100%
  • Enantiomer 50%
  • Polymerization 25%
  • Enantiopurity 25%
  104 Downloads (Pure)

• Mechanistically Guided Design of an Efficient and Enantioselective Aminocatalytic α-Chlorination of Aldehydes

  Hutchinson, G., Alamillo-Ferrer, C. & Burés, J., 12 May 2021, In: Journal of the American Chemical Society. 143, 18, p. 6805-6809 5 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  • Enantioselectivity 100%

• Understanding the Diastereopreference of Intermediates in Aminocatalysis: Application to the Chiral Resolution of Lactols

  Alamillo-ferrer, C., Nielsen, C.D.-T., Salzano, A., Companyó, X., Di Sanza, R., Spivey, A. C., Rzepa, H. S. & Burés, J., 10 Feb 2021, In: The Journal of organic chemistry.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Lactol 100%
  • Chirality in Separations 100%
  • Flavouring Agent 50%
  102 Downloads (Pure)
• 2020

  Dual H-bond activation of NHC–Au(I)–Cl complexes with amide functionalized side-arms assisted by H-bond donor substrates or acid additives

  Seppänen, O., Aikonen, S., Muuronen, M., Alamillo-ferrer, C., Burés, J. & Helaja, J., 3 Nov 2020, (E-pub ahead of print) In: Chemical Communications. 56, 93, p. 14697-14700

  Research output: Contribution to journal › Article › peer-review

  Open Access

  • Donor 100%
  • Carboxamide 100%
  • Density Functional Theory 50%
  • Oxazoline 50%
  • Cycloisomerization 50%

• Use of Standard Addition to Quantify In Situ FTIR Reaction Data

  Hutchinson, G., Welsh, C. D. M. & Burés, J., 24 Dec 2020, (E-pub ahead of print) In: The Journal of organic chemistry.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Fourier Transform Infrared Spectroscopy 100%
  196 Downloads (Pure)
• 2019

  Hydroarylation of Alkenes by Protonation/Friedel−Crafts Trapping: HFIP-Mediated Access to Per-aryl Quaternary Stereocenters

  Bures, J., Nielsen, C.D.-T., White, A. J. P., Sale, D. & Spivey, A. C., 15 Nov 2019, In: The Journal of organic chemistry. p. 14965 14973 p.

  Research output: Contribution to journal › Article › peer-review

  • Alkene 100%
  • Hydroarylation 100%
  • Hydrothiolation 50%
  • Hydrogenation 50%
  • Sulfonic Acid 50%

• Kinetic Treatments for Catalyst Activation and Deactivation Processes based on Variable Time Normalization Analysis

  Martínez-carrión, A., Howlett, M. G., Alamillo-ferrer, C., Clayton, A. D., Bourne, R. A., Codina, A., Vidal-ferran, A., Adams, R. W. & Bures, J., 30 Apr 2019, In: Angewandte Chemie International Edition. 58, 30, p. 10189-10193

  Research output: Contribution to journal › Article › peer-review

  • Catalyst Activation 100%
  • Catalyst Deactivation 100%
  • Kinetic Method 50%
• 2018

  Gold(I)-catalyzed 1,3-O-transposition of ynones: Mechanism and catalytic acceleration with electron rich aldehydes

  Aikonen, S., Muuronen, M., Wirtanen, T., Heikkinen, S., Musgreave, J., Bures Amat, J. & Helaja, J., 2018, In: ACS Catalysis. 8, p. 960-967 8 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Ynone 100%
  • Nucleophilicity 100%
  • Mediator 100%
  • Acetal 40%
  • Kinetics Type 20%
  321 Downloads (Pure)

• Intermediacy of Ni–Ni Species in sp2 C–O Bond Cleavage of Aryl Esters: Relevance in Catalytic C–Si Bond Formation

  Somerville, R. J., Hale, L. V. A., Gomez-Bengoa, E., Bures Amat, J. & Martin, R., 18 Jul 2018, In: American Chemical Society. Journal . 140, 28, p. 8771-8780

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Oxidative Addition 100%
  • Disproportionation 50%
  • Pivalate 50%
  401 Downloads (Pure)

• Reversibility and reactivity in an acid catalyzed cyclocondensation to give furanochromanes – a reaction at the ‘oxonium-Prins’ vs.‘ ortho-quinone methide cycloaddition’ mechanistic nexus

  Nielsen, C.D.-T., Mooij, W. J., Sale, D., Rzepa, H. S., Burés, J. & Spivey, A. C., 19 Oct 2018, (E-pub ahead of print) In: Chemical Science.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  • Quinone 100%
  • Cyclocondensation Reaction 100%
  • Oxonium 100%
  • Isomerization 100%
  • Alkene 50%

• Visual kinetic analysis

  Nielsen, C.D.-T. & Burés, J., 13 Dec 2018, (E-pub ahead of print) In: Chemical Science.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  • Kinetic Method 100%
  • Mechanistic Study 33%
• 2017

  A bis(pyridyl)-N-alkylamine/Cu(I) catalyst system for aerobic alcohol oxidation

  Marais, L., Bures Amat, J., Jordaan, J. H. L., Mapolie, S. & Swarts, A. J., 2017, In: Organic and Biomolecular Chemistry. 15

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Alkylamine 100%
  • % Inhibition 50%
  • Oxidation Reaction 50%
  • Ambient Reaction Temperature 50%
  • Electrospray Ionization Mass Spectroscopy 50%
  116 Downloads (Pure)

• Distribution of Catalytic Species as an Indicator to Overcome Reproducibility Problems

  Companyo, X. & Bures Amat, J., 2017, In: Journal of the American Chemical Society.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Turnover Frequency 100%
  • Nucleophile 100%
  • Catalytic Reaction 100%
  • Catalysis 100%
  283 Downloads (Pure)

• Reaction monitoring reveals poisoning mechanism of Pd2(dba)3 and guides catalyst selection

  Colletto, C., Bures Amat, J. & Larrosa, I., 2017, In: Chemical Communications.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Arylation 100%
  • Ambient Reaction Temperature 66%
  • Thiophene 66%
  • Catalyst Deactivation 33%
  457 Downloads (Pure)

• What is the order of a reaction?

  Bures Amat, J., 2017, In: Topics in Catalysis.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  • Complex Reaction Mechanisms 100%
• 2016

  Ag(I)-Catalyzed C–H Activation: The Role of the Ag(I) Salt in Pd/Ag-Mediated C–H Arylation of Electron-Deficient Arenes

  Whitaker, D., Bures, J. & Larrosa, I., 15 Jun 2016, In: Journal of the American Chemical Society. 138, 27, p. 8384-8387 4 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Arylation 100%
  • Kinetic Study 50%
  • Fluorobenzene 50%
  • Halide 50%
  • Aromatic Compound 50%
  188 Downloads (Pure)

• A Simple Graphical Method to Determine the Order in Catalyst

  Bures, J., 2 Feb 2016, In: Angewandte Chemie - International Edition. 55, 6, p. 2028-2031 4 p.

  Research output: Contribution to journal › Article › peer-review

  • Catalyst 100%
  • Analytical Method 100%
  • Procedure 100%
  • Rate 66%
  • Concentration 66%

• Deciphering the roles of multiple additives in organocatalyzed Michael additions

  Gunler, Z. I., Companyo, X., Alfonso, I., Bures, J., Jimeno, C. & Pericas, M. A., 21 May 2016, In: Chemical Communications. 52, 41, p. 6821-6824 4 p.

  Research output: Contribution to journal › Article › peer-review

  • Michael Addition 100%
  • Acetic Acid 100%
  • Imine 50%
  • Primary Amine 50%
  • Thiourea 50%

• Explaining Anomalies in Enamine Catalysis: "Downstream Species" as a New Paradigm for Stereocontrol

  Burés, J., Armstrong, A. & Blackmond, D. G., 2016, In: Accounts of Chemical Research. 49, 2, p. 214-222 9 p.

  Research output: Contribution to journal › Article › peer-review

  • Enamine 100%
  • Enantioselectivity 100%
  • Electrophile 71%
  • Spectroscopy 33%
  • Organocatalysis 28%

• Variable Time Normalization Analysis: General Graphical Elucidation of Reaction Orders from Concentration Profiles

  Bures Amat, J., 25 Nov 2016, In: Angewandte Chemie - International Edition. 55, 52, p. 16084-16087

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Acquired Data 100%
  • Reaction Order 100%
  • Kinetics Analysis 100%
  • Monitoring Technique 100%
  • Concentration Profile 100%
  1820 Downloads (Pure)
• 2014

  Electrospray ionization mass spectra of the reactions of NaAuBr(4) and related aurates with nucleophiles: J Mass Spectrom

  Isart, C., Bures, J. & Vilarrasa, J., 2014, In: Journal of mass spectrometry . 49, p. 331-334 4 p.

  Research output: Contribution to journal › Article › peer-review

  File
  206 Downloads (Pure)

• Rationalization of an Unusual Solvent-Induced Inversion of Enantiomeric Excess in Organocatalytic Selenylation of Aldehydes

  Bures, J., Dingwall, P., Armstrong, A. & Blackmond, D. G., 2014, In: Angew. Chem., Int. Ed.. 53, p. 8700-8704 5 p.

  Research output: Contribution to journal › Article › peer-review

  • Enantiomer 100%
  • Organocatalysis 100%
  • Enantioselectivity 50%
  • Silyl Ether 50%
  • Enamine 50%
• 2013

  The interplay of thermodynamics and kinetics in dictating organocatalytic reactivity and selectivity

  Burés, J., Armstrong, A. & Blackmond, D. G., 2013, In: Pure and Applied Chemistry. 85

  Research output: Contribution to journal › Article › peer-review

  File
  234 Downloads (Pure)
• 2012

  Curtin–Hammett Paradigm for Stereocontrol in Organocatalysis by Diarylprolinol Ether Catalysts

  Burés, J., Armstrong, A. & Blackmond, D. G., 2012, In: Journal of the American Chemical Society. 134, p. 6741-6750 10 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • Transition State 100%
  • Organocatalysis 100%
  • Electrophile 100%
  • Enamine 100%
  • Catalysis 50%
  404 Downloads (Pure)

• Kinetic correlation between aldehyde/enamine stereoisomers in reactions between aldehydes with [small alpha]-stereocenters and chiral pyrrolidine-based catalysts

  Bures, J., Armstrong, A. & Blackmond, D. G., 2012, In: Chemical Science. 3, p. 1273-1277 5 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • Stereoisomer 100%
  • Pyrrolidine 100%
  • Enamine 100%
  • Electrophile 28%
  • Kinetic Study 14%
  332 Downloads (Pure)

• Relative Tendency of Carbonyl Compounds To Form Enamines

  Sánchez, D., Bastida, D., Burés, J., Isart, C., Pineda, O. & Vilarrasa, J., 2012, In: Organic Letters. 14, p. 536-539 4 p.

  Research output: Contribution to journal › Article › peer-review

  File
  369 Downloads (Pure)
• 2011

  Enamine Carboxylates as Stereodetermining Intermediates in Prolinate Catalysis

  Hein, J. E., Burés, J., Lam, Y.-H., Hughes, M., Houk, K. N., Armstrong, A. & Blackmond, D. G., 2011, In: Organic Letters. 13, p. 5644-5647 4 p.

  Research output: Contribution to journal › Article › peer-review

  File
  225 Downloads (Pure)

• Gold(III) Complexes Catalyze Deoximations/Transoximations at Neutral pH

  Isart, C., Bastida, D., Burés, J. & Vilarrasa, J., 2011, In: Angewandte Chemie International Edition. 50, p. 3275-3279 5 p.

  Research output: Contribution to journal › Article › peer-review

  File
  190 Downloads (Pure)

• Mechanistic rationalization of organocatalyzed conjugate addition of linear aldehydes to nitro-olefins

  Bures, J., Armstrong, A. & Blackmond, D. G., 2011, In: J Am Chem Soc. 133, p. 8822-8825 4 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • Kinetic Study 100%
  • Nitroolefin 100%
  • Propanal 100%
  • Stereoselectivity 100%
  • Cyclobutane 100%
  288 Downloads (Pure)
• 2010

  Reaction of Dess-Martin periodinane with 2-(alkylselenyl)pyridines. Dehydration of primary alcohols under extraordinarily mild conditions: Tetrahedron Letters

  Andreou, T., Bures, J. & Vilarrasa, J., 2010, In: Tetrahedron Letters. 51, p. 1863-1866 4 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • Dess-Martin Oxidation 100%
  • Primary Alcohols 100%
  • Alkene 50%
  706 Downloads (Pure)
• 2009

  AuBr3-Catalyzed Thiooxime-to-Carbonyl Conversion: From Chiral Aliphatic Nitro Compounds to Ketones without Racemization

  Bures, J., Isart, C. & Vilarrasa, J., 2009, In: Organic Letters. 11, p. 4414-4417 4 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • Nitro Compounds 100%
  • Ketones 100%
  • Ambient Reaction Temperature 50%
  • Neutral Condition 50%
  • Nitroalkane 50%
  243 Downloads (Pure)

• Catalytic Staudinger-Vilarrasa Reaction for the Direct Ligation of Carboxylic Acids and Azides: Journal of Organic Chemistry

  Bures, J., Martin, M., Urpi, F. & Vilarrasa, J., 2009, In: The Journal of organic chemistry. 74, p. 2203-2206 4 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • Azide 100%
  • Carboxylic Acid 100%
  • Ambient Reaction Temperature 50%
  • Diselenide 50%
  • Aza-Wittig Reaction 50%
  477 Downloads (Pure)
• 2008

  Catalytic, PMe3-mediated conversion of secondary nitroalkanes to ketones: a very mild Nef-type process

  Burés, J. & Vilarrasa, J., 2008, In: Tetrahedron Letters. 49, p. 441-444 4 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • Nitroalkane 100%
  • Ketones 100%
  • One Pot Reaction 50%
  • Trimethylphosphine 50%
  221 Downloads (Pure)

• Seebach's oxazolidinone is a good catalyst for aldol reactions: Tetrahedron Lett.

  Isart, C., Bures, J. & Vilarrasa, J., 2008, In: Tetrahedron Letters. 49, p. 5414-5418 5 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • Seebach Umpolung 100%
  • Oxazolidinones 100%
  • Aldol Reaction 100%
  • Proline 100%
  • Beta-Hydroxy Ketone 33%
  163 Downloads (Pure)
• 2007

  Efficient Preparation of N-Phenylsulfenyl Ketimines from Oximes or Nitro Compounds without Racemization of α-Stereocenters

  Burés, J., Isart, C. & Vilarrasa, J., 2007, In: Organic Letters. 9, p. 4635-4638 4 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • Imine 100%
  • Oxime 100%
  • Nitro Compounds 100%
  • Ketimine 100%
  • Oxaziridine 33%
  233 Downloads (Pure)