2,2′-Diazinodimethylidyne)di-o-phenyl-ene) dibenzoate

Basab Chattopadhyay, Sharmila Basu, Somnath Ghosh, Madeleine Helliwell, Monika Mukherjee

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The title compound, C28H20N2O4, was synthesized by the reaction of 2-(hydrazonometh-yl)phenyl benzoate with iodine. The mol-ecule possesses a crystallographically imposed center of symmetry at the mid-point of the hydrazine N - N bond. The substituents at the ends of the C=N bonds adopt an E,E configuration. Inter-molecular C - H⋯π(arene) hydrogen bonds and aromatic π-π stacking inter-actions [centroid-centroid distance 3.900 (1) Å] link the mol-ecules into (100) sheets. In addition, there is an inter-molecular C - H⋯O hydrogen-bond inter-action.
    Original languageEnglish
    Pages (from-to)o866
    JournalActa Crystallographica Section E: Structure Reports Online
    Volume64
    Issue number5
    DOIs
    Publication statusPublished - 30 Apr 2008

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