4-Arylamino-6-chloro-1,3,5-triazin-2(1H)-ones: Nucleophilic substitution of a model compound in acid medium to produce novel fibre reactive triazinyl derivatives

A. H M Renfrew; D. A S Phillips; I. Bates

doi:10.1016/S0143-7208(03)00084-6

4-Arylamino-6-chloro-1,3,5-triazin-2(1H)-ones: Nucleophilic substitution of a model compound in acid medium to produce novel fibre reactive triazinyl derivatives

A. H M Renfrew, D. A S Phillips, I. Bates

Research output: Contribution to journal › Article › peer-review

Abstract

A model 4-arylamino-6-chloro-1,3,5-triazin-2(1H)-one has been synthesised and reacted with a variety of nitrogen, oxygen and sulphur nucleophiles in an acidic medium. Unlike the parent compound, the products from reaction with pyridine, nicotinic acid and p-aminobenzene-β-sulphatoethylsulphone are capable of reaction with cellulose in an alkaline medium. © 2003 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	99-106
Number of pages	7
Journal	Dyes and pigments
Volume	59
Issue number	1
DOIs	https://doi.org/10.1016/S0143-7208(03)00084-6
Publication status	Published - Oct 2003

Keywords

4-Arylamino-6-chloro-1,3,5-triazin-2(1H)-one
Acid catalysis
Betaine
Nicotinic acid
Reactive group
Triazine-2-oxide

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title = "4-Arylamino-6-chloro-1,3,5-triazin-2(1H)-ones: Nucleophilic substitution of a model compound in acid medium to produce novel fibre reactive triazinyl derivatives",

abstract = "A model 4-arylamino-6-chloro-1,3,5-triazin-2(1H)-one has been synthesised and reacted with a variety of nitrogen, oxygen and sulphur nucleophiles in an acidic medium. Unlike the parent compound, the products from reaction with pyridine, nicotinic acid and p-aminobenzene-β-sulphatoethylsulphone are capable of reaction with cellulose in an alkaline medium. {\textcopyright} 2003 Elsevier Ltd. All rights reserved.",

keywords = "4-Arylamino-6-chloro-1,3,5-triazin-2(1H)-one, Acid catalysis, Betaine, Nicotinic acid, Reactive group, Triazine-2-oxide",

author = "Renfrew, {A. H M} and Phillips, {D. A S} and I. Bates",

year = "2003",

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language = "English",

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T1 - 4-Arylamino-6-chloro-1,3,5-triazin-2(1H)-ones: Nucleophilic substitution of a model compound in acid medium to produce novel fibre reactive triazinyl derivatives

AU - Renfrew, A. H M

AU - Phillips, D. A S

AU - Bates, I.

PY - 2003/10

Y1 - 2003/10

N2 - A model 4-arylamino-6-chloro-1,3,5-triazin-2(1H)-one has been synthesised and reacted with a variety of nitrogen, oxygen and sulphur nucleophiles in an acidic medium. Unlike the parent compound, the products from reaction with pyridine, nicotinic acid and p-aminobenzene-β-sulphatoethylsulphone are capable of reaction with cellulose in an alkaline medium. © 2003 Elsevier Ltd. All rights reserved.

AB - A model 4-arylamino-6-chloro-1,3,5-triazin-2(1H)-one has been synthesised and reacted with a variety of nitrogen, oxygen and sulphur nucleophiles in an acidic medium. Unlike the parent compound, the products from reaction with pyridine, nicotinic acid and p-aminobenzene-β-sulphatoethylsulphone are capable of reaction with cellulose in an alkaline medium. © 2003 Elsevier Ltd. All rights reserved.

KW - 4-Arylamino-6-chloro-1,3,5-triazin-2(1H)-one

KW - Acid catalysis

KW - Betaine

KW - Nicotinic acid

KW - Reactive group

KW - Triazine-2-oxide

U2 - 10.1016/S0143-7208(03)00084-6

DO - 10.1016/S0143-7208(03)00084-6

M3 - Article

SN - 0143-7208

VL - 59

SP - 99

EP - 106

JO - Dyes and pigments

JF - Dyes and pigments

IS - 1

ER -

4-Arylamino-6-chloro-1,3,5-triazin-2(1H)-ones: Nucleophilic substitution of a model compound in acid medium to produce novel fibre reactive triazinyl derivatives

Abstract

Keywords

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