A centred, elongated ‘ferric tetrahedron’ with an S = 15/2 spin ground state

James Tabernor; Leigh F. Jones; Sarah L. Heath; Chris Muryn; Guillem Aromí; Joan Ribas; Euan K. Brechin; David Collison

doi:10.1039/b403041a

A centred, elongated ‘ferric tetrahedron’ with an S = 15/2 spin ground state

James Tabernor, Leigh F. Jones, Sarah L. Heath, Chris Muryn, Guillem Aromí, Joan Ribas, Euan K. Brechin^*, David Collison

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of anhydrous FeCl₃with 1H-benzotriazole-1-methanol (Bta-CH₂OH) in MeOH produces the pentanuclear complex [Fe₅O₂(OMe)₂(Bta)₄(BtaH)(MeOH)₅Cl₅], containing a distorted tetrahedron of four Fe ions centred on a fifth. The central Fe is antiferromagnetically coupled to the peripheral Fe ions resulting in an S = 15/2 spin ground state.

Original language	English
Pages (from-to)	975-976
Number of pages	2
Journal	Journal of the Chemical Society. Dalton Transactions
Volume	4
Issue number	7
DOIs	https://doi.org/10.1039/b403041a
Publication status	Published - 19 Mar 2004

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10.1039/b403041a

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title = "A centred, elongated {\textquoteleft}ferric tetrahedron{\textquoteright} with an S = 15/2 spin ground state",

abstract = "The reaction of anhydrous FeCl3with 1H-benzotriazole-1-methanol (Bta-CH2OH) in MeOH produces the pentanuclear complex [Fe5O2(OMe)2(Bta)4(BtaH)(MeOH)5Cl5], containing a distorted tetrahedron of four Fe ions centred on a fifth. The central Fe is antiferromagnetically coupled to the peripheral Fe ions resulting in an S = 15/2 spin ground state.",

author = "James Tabernor and Jones, {Leigh F.} and Heath, {Sarah L.} and Chris Muryn and Guillem Arom{\'i} and Joan Ribas and Brechin, {Euan K.} and David Collison",

year = "2004",

month = mar,

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doi = "10.1039/b403041a",

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journal = "Journal of the Chemical Society. Dalton Transactions",

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T1 - A centred, elongated ‘ferric tetrahedron’ with an S = 15/2 spin ground state

AU - Tabernor, James

AU - Jones, Leigh F.

AU - Heath, Sarah L.

AU - Muryn, Chris

AU - Aromí, Guillem

AU - Ribas, Joan

AU - Brechin, Euan K.

AU - Collison, David

PY - 2004/3/19

Y1 - 2004/3/19

N2 - The reaction of anhydrous FeCl3with 1H-benzotriazole-1-methanol (Bta-CH2OH) in MeOH produces the pentanuclear complex [Fe5O2(OMe)2(Bta)4(BtaH)(MeOH)5Cl5], containing a distorted tetrahedron of four Fe ions centred on a fifth. The central Fe is antiferromagnetically coupled to the peripheral Fe ions resulting in an S = 15/2 spin ground state.

AB - The reaction of anhydrous FeCl3with 1H-benzotriazole-1-methanol (Bta-CH2OH) in MeOH produces the pentanuclear complex [Fe5O2(OMe)2(Bta)4(BtaH)(MeOH)5Cl5], containing a distorted tetrahedron of four Fe ions centred on a fifth. The central Fe is antiferromagnetically coupled to the peripheral Fe ions resulting in an S = 15/2 spin ground state.

UR - http://www.scopus.com/inward/record.url?scp=85034350528&partnerID=8YFLogxK

U2 - 10.1039/b403041a

DO - 10.1039/b403041a

M3 - Article

AN - SCOPUS:85034350528

SN - 1477-9226

VL - 4

SP - 975

EP - 976

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 7

ER -

A centred, elongated ‘ferric tetrahedron’ with an S = 15/2 spin ground state

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