A centrosymmetrical Di-thiolato-bridged dinuclear nickel(II) compound; Bis-μ-S-(7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiolato)dinickel(II) perchlorate

Neil F Curtis; Olga P Gladhikh; Sarah L Heath; Keith R Morgan

doi:10.1071/C97005

A centrosymmetrical Di-thiolato-bridged dinuclear nickel(II) compound; Bis-μ-S-(7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiolato)dinickel(II) perchlorate

Neil F Curtis, Olga P Gladhikh, Sarah L Heath, Keith R Morgan

Research output: Contribution to journal › Article › peer-review

Abstract

[Ni2(μ-L)2](ClO4)2 (HL = 7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiol), formed by reaction of 4-mercapto-4-methylpentan-2-one with bis(ethane-1,2-diamine)nickel(II) perchlorate, has a centrosym. dinuclear cation. Each singlet ground-state Ni(II) ion is in tetrahedrally twisted square-planar coordination by the primary amine and imine N atoms and the thiolato S atom of one mol. of 7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiolate (adet-), and the S atom of another mol., with the S atoms of two ligands forming a planar Ni2S2 bridging group. Crystal data: [Ni2-μ-(adet)2](ClO4)2, C16H34Cl2N4Ni2O8S2, Mr 662.9, monoclinic, P 21/c, a 8.267(1), b 9.952(1), c 16.234(2) Å, β 103.010(2)°, R1 0.033 for 2531 reflections. [on SciFinder(R)]

Original language	English
Pages (from-to)	49-53
Number of pages	5
Journal	Aust. J. Chem.
Volume	51
Issue number	1
DOIs	https://doi.org/10.1071/C97005
Publication status	Published - 1998

Keywords

crystal structure nickel aminodimethylazaheptenethiol dinuclear
nickel aminodimethylazaheptenethiol dinuclear prepn structure

Access to Document

10.1071/C97005

Cite this

@article{01bd08383e45477e80b1d73c8893fde6,

title = "A centrosymmetrical Di-thiolato-bridged dinuclear nickel(II) compound; Bis-μ-S-(7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiolato)dinickel(II) perchlorate",

abstract = "[Ni2(μ-L)2](ClO4)2 (HL = 7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiol), formed by reaction of 4-mercapto-4-methylpentan-2-one with bis(ethane-1,2-diamine)nickel(II) perchlorate, has a centrosym. dinuclear cation. Each singlet ground-state Ni(II) ion is in tetrahedrally twisted square-planar coordination by the primary amine and imine N atoms and the thiolato S atom of one mol. of 7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiolate (adet-), and the S atom of another mol., with the S atoms of two ligands forming a planar Ni2S2 bridging group. Crystal data: [Ni2-μ-(adet)2](ClO4)2, C16H34Cl2N4Ni2O8S2, Mr 662.9, monoclinic, P 21/c, a 8.267(1), b 9.952(1), c 16.234(2) {\AA}, β 103.010(2)°, R1 0.033 for 2531 reflections. [on SciFinder(R)]",

keywords = "crystal structure nickel aminodimethylazaheptenethiol dinuclear, nickel aminodimethylazaheptenethiol dinuclear prepn structure",

author = "Curtis, {Neil F} and Gladhikh, {Olga P} and Heath, {Sarah L} and Morgan, {Keith R}",

note = "CAPLUS AN 1998:200969(Journal)",

year = "1998",

doi = "10.1071/C97005",

language = "English",

volume = "51",

pages = "49--53",

journal = "Aust. J. Chem.",

issn = "0004-9425",

publisher = "CSIRO Publishing ",

number = "1",

}

TY - JOUR

T1 - A centrosymmetrical Di-thiolato-bridged dinuclear nickel(II) compound; Bis-μ-S-(7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiolato)dinickel(II) perchlorate

AU - Curtis, Neil F

AU - Gladhikh, Olga P

AU - Heath, Sarah L

AU - Morgan, Keith R

N1 - CAPLUS AN 1998:200969(Journal)

PY - 1998

Y1 - 1998

N2 - [Ni2(μ-L)2](ClO4)2 (HL = 7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiol), formed by reaction of 4-mercapto-4-methylpentan-2-one with bis(ethane-1,2-diamine)nickel(II) perchlorate, has a centrosym. dinuclear cation. Each singlet ground-state Ni(II) ion is in tetrahedrally twisted square-planar coordination by the primary amine and imine N atoms and the thiolato S atom of one mol. of 7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiolate (adet-), and the S atom of another mol., with the S atoms of two ligands forming a planar Ni2S2 bridging group. Crystal data: [Ni2-μ-(adet)2](ClO4)2, C16H34Cl2N4Ni2O8S2, Mr 662.9, monoclinic, P 21/c, a 8.267(1), b 9.952(1), c 16.234(2) Å, β 103.010(2)°, R1 0.033 for 2531 reflections. [on SciFinder(R)]

AB - [Ni2(μ-L)2](ClO4)2 (HL = 7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiol), formed by reaction of 4-mercapto-4-methylpentan-2-one with bis(ethane-1,2-diamine)nickel(II) perchlorate, has a centrosym. dinuclear cation. Each singlet ground-state Ni(II) ion is in tetrahedrally twisted square-planar coordination by the primary amine and imine N atoms and the thiolato S atom of one mol. of 7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiolate (adet-), and the S atom of another mol., with the S atoms of two ligands forming a planar Ni2S2 bridging group. Crystal data: [Ni2-μ-(adet)2](ClO4)2, C16H34Cl2N4Ni2O8S2, Mr 662.9, monoclinic, P 21/c, a 8.267(1), b 9.952(1), c 16.234(2) Å, β 103.010(2)°, R1 0.033 for 2531 reflections. [on SciFinder(R)]

KW - crystal structure nickel aminodimethylazaheptenethiol dinuclear

KW - nickel aminodimethylazaheptenethiol dinuclear prepn structure

U2 - 10.1071/C97005

DO - 10.1071/C97005

M3 - Article

SN - 0004-9425

VL - 51

SP - 49

EP - 53

JO - Aust. J. Chem.

JF - Aust. J. Chem.

IS - 1

ER -

A centrosymmetrical Di-thiolato-bridged dinuclear nickel(II) compound; Bis-μ-S-(7-amino-2,4-dimethyl-5-azahept-4-ene-2-thiolato)dinickel(II) perchlorate

Abstract

Keywords

Access to Document

Fingerprint

Cite this