A comparison of the pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics

B. J. Coe; J. A. Harris; K. Clays; A. Persoons; K. Wostyn; B. S. Brunschwig

doi:10.1039/b103543f

A comparison of the pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics

B. J. Coe
, J. A. Harris
, K. Clays
, A. Persoons
, K. Wostyn
, B. S. Brunschwig

Research output: Contribution to journal › Article › peer-review

Abstract

Hyper-Rayleigh scattering and Stark spectroscopic studies show that the complex salts [1-4]PF6 have larger static first hyperpolarizabilities β0 than [5-8]PF6, because the higher HOMO energy of a {RuII(NH3)5}2+ centre more than offsets the superior π-orbital overlap in the purely organic chromophores.

Original language	English
Pages (from-to)	1548-1549
Number of pages	1
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/b103543f
Publication status	Published - 7 Sept 2001

Keywords

Nonlinear optical properties (of pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics); Oxidation potential; Reduction potential; UV and visible spectra (of pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenylpyridinium groups)

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10.1039/b103543f

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title = "A comparison of the pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics",

abstract = "Hyper-Rayleigh scattering and Stark spectroscopic studies show that the complex salts [1-4]PF6 have larger static first hyperpolarizabilities β0 than [5-8]PF6, because the higher HOMO energy of a \{RuII(NH3)5\}2+ centre more than offsets the superior π-orbital overlap in the purely organic chromophores.",

keywords = "Nonlinear optical properties (of pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics); Oxidation potential; Reduction potential; UV and visible spectra (of pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenylpyridinium groups)",

author = "Coe, \{B. J.\} and Harris, \{J. A.\} and K. Clays and A. Persoons and K. Wostyn and Brunschwig, \{B. S.\}",

year = "2001",

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day = "7",

doi = "10.1039/b103543f",

language = "English",

pages = "1548--1549",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - A comparison of the pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics

AU - Coe, B. J.

AU - Harris, J. A.

AU - Clays, K.

AU - Persoons, A.

AU - Wostyn, K.

AU - Brunschwig, B. S.

PY - 2001/9/7

Y1 - 2001/9/7

N2 - Hyper-Rayleigh scattering and Stark spectroscopic studies show that the complex salts [1-4]PF6 have larger static first hyperpolarizabilities β0 than [5-8]PF6, because the higher HOMO energy of a {RuII(NH3)5}2+ centre more than offsets the superior π-orbital overlap in the purely organic chromophores.

AB - Hyper-Rayleigh scattering and Stark spectroscopic studies show that the complex salts [1-4]PF6 have larger static first hyperpolarizabilities β0 than [5-8]PF6, because the higher HOMO energy of a {RuII(NH3)5}2+ centre more than offsets the superior π-orbital overlap in the purely organic chromophores.

KW - Nonlinear optical properties (of pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics); Oxidation potential; Reduction potential; UV and visible spectra (of pentaammine(pyridyl)ruthenium(I

U2 - 10.1039/b103543f

DO - 10.1039/b103543f

M3 - Article

SN - 1359-7345

SP - 1548

EP - 1549

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

A comparison of the pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics

Abstract

Keywords

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