A Cryptand Metal-Organic Framework as a Platform for the Selective Uptake and Detection of Group 1 Metal Cations

Sergey A. Sapchenko, Pavel A. Demakov, Denis G. Samsonenko, Danil. N. Dybtsev, Martin Schroder, Vladimir P. Fedin

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    Abstract

    The metal–organic framework (MOF) complex (H3O)2[Zn4(ur)(Hfdc)2(fdc)4] (1, ur=urotropine, H2fdc=furan-2,5-dicarboxylic acid) incorporates cryptand-like cavities, which can be used to separate and detect Rb+ and Cs+ optically. This is the first example of the effective employment of a MOF material for optical detection of these cations.
    Original languageEnglish
    Pages (from-to)2286–2289
    Number of pages4
    JournalChemistry: A European Journal
    Volume23
    Issue number10
    Early online date20 Jan 2017
    DOIs
    Publication statusPublished - 16 Feb 2017

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