A dramatic shift from multiple to simple exchange in the cyclopentane/D2 probe reaction on palladium catalysts

Gerard Fitzsimons; Christopher Hardacre; William R. Patterson; John J. Rooney; John K A Clarke; Michael R. Smith; R. Mark Ormerod

A dramatic shift from multiple to simple exchange in the cyclopentane/D2 probe reaction on palladium catalysts

Gerard Fitzsimons, Christopher Hardacre, William R. Patterson, John J. Rooney, John K A Clarke, Michael R. Smith, R. Mark Ormerod

Research output: Contribution to journal › Article › peer-review

Abstract

Electron deficient active sites in Pd catalysts, either as films or on supports, are deliberately generated by calcining in O₂ at high temperature followed by the mildest possible reduction (with the reaction mixture itself), and are manifested by a marked shift from multiple to simple exchange in the cyclopentane/D₂ probe reaction.

Original language	English
Pages (from-to)	187-191
Number of pages	5
Journal	Catalysis Letters
Volume	45
Issue number	1-2
Publication status	Published - 1997

Keywords

Cyclopentane/D exchange
Falling initial distributions of deuterioisomers
Novel supports and pretreatments
Pd catalysts

Cite this

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title = "A dramatic shift from multiple to simple exchange in the cyclopentane/D2 probe reaction on palladium catalysts",

abstract = "Electron deficient active sites in Pd catalysts, either as films or on supports, are deliberately generated by calcining in O2 at high temperature followed by the mildest possible reduction (with the reaction mixture itself), and are manifested by a marked shift from multiple to simple exchange in the cyclopentane/D2 probe reaction.",

keywords = "Cyclopentane/D exchange, Falling initial distributions of deuterioisomers, Novel supports and pretreatments, Pd catalysts",

author = "Gerard Fitzsimons and Christopher Hardacre and Patterson, {William R.} and Rooney, {John J.} and Clarke, {John K A} and Smith, {Michael R.} and {Mark Ormerod}, R.",

year = "1997",

language = "English",

volume = "45",

pages = "187--191",

journal = "Catalysis Letters",

issn = "1011-372X",

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T1 - A dramatic shift from multiple to simple exchange in the cyclopentane/D2 probe reaction on palladium catalysts

AU - Fitzsimons, Gerard

AU - Hardacre, Christopher

AU - Patterson, William R.

AU - Rooney, John J.

AU - Clarke, John K A

AU - Smith, Michael R.

AU - Mark Ormerod, R.

PY - 1997

Y1 - 1997

N2 - Electron deficient active sites in Pd catalysts, either as films or on supports, are deliberately generated by calcining in O2 at high temperature followed by the mildest possible reduction (with the reaction mixture itself), and are manifested by a marked shift from multiple to simple exchange in the cyclopentane/D2 probe reaction.

AB - Electron deficient active sites in Pd catalysts, either as films or on supports, are deliberately generated by calcining in O2 at high temperature followed by the mildest possible reduction (with the reaction mixture itself), and are manifested by a marked shift from multiple to simple exchange in the cyclopentane/D2 probe reaction.

KW - Cyclopentane/D exchange

KW - Falling initial distributions of deuterioisomers

KW - Novel supports and pretreatments

KW - Pd catalysts

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M3 - Article

VL - 45

SP - 187

EP - 191

JO - Catalysis Letters

JF - Catalysis Letters

SN - 1011-372X

IS - 1-2

ER -

A dramatic shift from multiple to simple exchange in the cyclopentane/D2 probe reaction on palladium catalysts

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Keywords

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