A family of mononuclear CoIII/2-pyridyloximate complexes and their conversion to trinuclear, mixed-valence linear CoII/III3 clusters

Theocharis C. Stamatatos; Eugenia Katsoulakou; Aris Terzis; Catherine P. Raptopoulou; Richard E P Winpenny; Spyros P. Perlepes

doi:10.1016/j.poly.2008.10.040

A family of mononuclear CoIII/2-pyridyloximate complexes and their conversion to trinuclear, mixed-valence linear CoII/III3 clusters

Theocharis C. Stamatatos, Eugenia Katsoulakou, Aris Terzis, Catherine P. Raptopoulou, Richard E P Winpenny, Spyros P. Perlepes

Research output: Contribution to journal › Article › peer-review

Abstract

The use of the 2-pyridyl oxime ligands (LH) 2-pyridinealdoxime, methyl 2-pyridyl ketone oxime and phenyl 2-pyridyl ketone oxime in Co chemistry has been investigated and led to two families of compounds. The first family includes the mononuclear octahedral, low-spin complexes [CoIII(L)3], while the second family consists of the trinuclear, mixed-valent linear clusters [CoIII2CoII(L)6]X2 (X = ClO4-, PF6-). The latter are prepared by the reactions of the former with an appropriate CoII source. The structural, physical and spectroscopic properties of the complexes are described. © 2008 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	1638-1645
Number of pages	7
Journal	Polyhedron
Volume	28
Issue number	9-10
DOIs	https://doi.org/10.1016/j.poly.2008.10.040
Publication status	Published - 22 Jun 2009

Keywords

2-Pyridyloxime ligands
Cobalt(III) complexes
Complexes as ligands strategy
Crystal structures
Mixed-valence cobalt(II/III) complexes
Trinuclear cobalt clusters

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10.1016/j.poly.2008.10.040

CCDC 264166: Experimental Crystal Structure Determination
Stamatatos, T. C. (Contributor), Bell, A. (Contributor), Cooper, P. (Contributor), Terzis, A. (Contributor), Raptopoulou, C. P. (Contributor), Heath, S. L. (Contributor), Winpenny, R. (Contributor) & Perlepes, S. P. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2005
DOI: 10.5517/cc8vwhg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8vwhg&sid=DataCite
Dataset
CCDC 264168: Experimental Crystal Structure Determination
Stamatatos, T. C. (Contributor), Bell, A. (Contributor), Cooper, P. (Contributor), Terzis, A. (Contributor), Raptopoulou, C. P. (Contributor), Heath, S. (Contributor), Winpenny, R. (Contributor) & Perlepes, S. P. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2005
DOI: 10.5517/cc8vwkj, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8vwkj&sid=DataCite
Dataset
CCDC 264167: Experimental Crystal Structure Determination
Stamatatos, T. C. (Contributor), Bell, A. (Contributor), Cooper, P. (Contributor), Terzis, A. (Contributor), Raptopoulou, C. P. (Contributor), Heath, S. (Contributor), Winpenny, R. (Contributor) & Perlepes, S. P. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2005
DOI: 10.5517/cc8vwjh, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8vwjh&sid=DataCite
Dataset

Cite this

@article{931a750af65a43b3ae87af20a22d8738,

title = "A family of mononuclear CoIII/2-pyridyloximate complexes and their conversion to trinuclear, mixed-valence linear CoII/III3 clusters",

abstract = "The use of the 2-pyridyl oxime ligands (LH) 2-pyridinealdoxime, methyl 2-pyridyl ketone oxime and phenyl 2-pyridyl ketone oxime in Co chemistry has been investigated and led to two families of compounds. The first family includes the mononuclear octahedral, low-spin complexes [CoIII(L)3], while the second family consists of the trinuclear, mixed-valent linear clusters [CoIII2CoII(L)6]X2 (X = ClO4-, PF6-). The latter are prepared by the reactions of the former with an appropriate CoII source. The structural, physical and spectroscopic properties of the complexes are described. {\textcopyright} 2008 Elsevier Ltd. All rights reserved.",

keywords = "2-Pyridyloxime ligands, Cobalt(III) complexes, Complexes as ligands strategy, Crystal structures, Mixed-valence cobalt(II/III) complexes, Trinuclear cobalt clusters",

author = "Stamatatos, {Theocharis C.} and Eugenia Katsoulakou and Aris Terzis and Raptopoulou, {Catherine P.} and Winpenny, {Richard E P} and Perlepes, {Spyros P.}",

year = "2009",

month = jun,

day = "22",

doi = "10.1016/j.poly.2008.10.040",

language = "English",

volume = "28",

pages = "1638--1645",

journal = "Polyhedron",

publisher = "Elsevier BV",

number = "9-10",

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TY - JOUR

T1 - A family of mononuclear CoIII/2-pyridyloximate complexes and their conversion to trinuclear, mixed-valence linear CoII/III3 clusters

AU - Stamatatos, Theocharis C.

AU - Katsoulakou, Eugenia

AU - Terzis, Aris

AU - Raptopoulou, Catherine P.

AU - Winpenny, Richard E P

AU - Perlepes, Spyros P.

PY - 2009/6/22

Y1 - 2009/6/22

N2 - The use of the 2-pyridyl oxime ligands (LH) 2-pyridinealdoxime, methyl 2-pyridyl ketone oxime and phenyl 2-pyridyl ketone oxime in Co chemistry has been investigated and led to two families of compounds. The first family includes the mononuclear octahedral, low-spin complexes [CoIII(L)3], while the second family consists of the trinuclear, mixed-valent linear clusters [CoIII2CoII(L)6]X2 (X = ClO4-, PF6-). The latter are prepared by the reactions of the former with an appropriate CoII source. The structural, physical and spectroscopic properties of the complexes are described. © 2008 Elsevier Ltd. All rights reserved.

AB - The use of the 2-pyridyl oxime ligands (LH) 2-pyridinealdoxime, methyl 2-pyridyl ketone oxime and phenyl 2-pyridyl ketone oxime in Co chemistry has been investigated and led to two families of compounds. The first family includes the mononuclear octahedral, low-spin complexes [CoIII(L)3], while the second family consists of the trinuclear, mixed-valent linear clusters [CoIII2CoII(L)6]X2 (X = ClO4-, PF6-). The latter are prepared by the reactions of the former with an appropriate CoII source. The structural, physical and spectroscopic properties of the complexes are described. © 2008 Elsevier Ltd. All rights reserved.

KW - 2-Pyridyloxime ligands

KW - Cobalt(III) complexes

KW - Complexes as ligands strategy

KW - Crystal structures

KW - Mixed-valence cobalt(II/III) complexes

KW - Trinuclear cobalt clusters

U2 - 10.1016/j.poly.2008.10.040

DO - 10.1016/j.poly.2008.10.040

M3 - Article

VL - 28

SP - 1638

EP - 1645

JO - Polyhedron

JF - Polyhedron

IS - 9-10

ER -

A family of mononuclear CoIII/2-pyridyloximate complexes and their conversion to trinuclear, mixed-valence linear CoII/III3 clusters

Abstract

Keywords

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Datasets

CCDC 264166: Experimental Crystal Structure Determination

CCDC 264168: Experimental Crystal Structure Determination

CCDC 264167: Experimental Crystal Structure Determination

Cite this