A Heterobimetallic Gallyl Complex Containing an Unsupported Ga-Y Bond

Stephen T. Liddle, David P. Mills, Benedict M. Gardner, Jonathan McMaster, Cameron Jones, William D. Woodul

Research output: Contribution to journalArticlepeer-review

Abstract

The synthesis and characterization of the first unsupported Ga-Y bond in [Y{Ga(NArCH)2}{C(PPh2NSiMe3)2}(THF) 2] (Ar = 2,6-diiso-propylphenyl) is described; structural and computational analyses are consistent with a highly polarized covalent Ga-Y bond. © 2009 American Chemical Society.
Original languageEnglish
Pages (from-to)3520-3522
Number of pages2
JournalInorganic Chemistry: including bioinorganic chemistry
Volume48
Issue number8
DOIs
Publication statusPublished - 20 Apr 2009

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