A highly efficient synthetic procedure for deuteriating imidazoles and imidazolium salts

C. Hardacre; J. D. Holbrey; S. E J McMath

A highly efficient synthetic procedure for deuteriating imidazoles and imidazolium salts

C. Hardacre^*
, J. D. Holbrey
, S. E J McMath

^*Corresponding author for this work

Queen's University Belfast

Research output: Contribution to journal › Article › peer-review

Abstract

Both substituted imidazoles and 1,3-dialkylimidazolium salts can be fully deuteriated on the heterocyclic ring using D₂O over heterogeneous Pd catalysts: deuteriated 1-alkyl-3-methylimidazolium chloride and hexafluorophosphate ionic liquids can also be prepared in good yields utilising readily available and relatively low cost sources of deuterium.

Original language	English
Pages (from-to)	367-368
Number of pages	2
Journal	Chemical Communications
Issue number	4
Publication status	Published - 21 Feb 2001

Cite this

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title = "A highly efficient synthetic procedure for deuteriating imidazoles and imidazolium salts",

abstract = "Both substituted imidazoles and 1,3-dialkylimidazolium salts can be fully deuteriated on the heterocyclic ring using D2O over heterogeneous Pd catalysts: deuteriated 1-alkyl-3-methylimidazolium chloride and hexafluorophosphate ionic liquids can also be prepared in good yields utilising readily available and relatively low cost sources of deuterium.",

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AU - Hardacre, C.

AU - Holbrey, J. D.

AU - McMath, S. E J

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N2 - Both substituted imidazoles and 1,3-dialkylimidazolium salts can be fully deuteriated on the heterocyclic ring using D2O over heterogeneous Pd catalysts: deuteriated 1-alkyl-3-methylimidazolium chloride and hexafluorophosphate ionic liquids can also be prepared in good yields utilising readily available and relatively low cost sources of deuterium.

AB - Both substituted imidazoles and 1,3-dialkylimidazolium salts can be fully deuteriated on the heterocyclic ring using D2O over heterogeneous Pd catalysts: deuteriated 1-alkyl-3-methylimidazolium chloride and hexafluorophosphate ionic liquids can also be prepared in good yields utilising readily available and relatively low cost sources of deuterium.

UR - https://www.scopus.com/pages/publications/0035925151

M3 - Article

AN - SCOPUS:0035925151

SN - 1359-7345

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EP - 368

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

A highly efficient synthetic procedure for deuteriating imidazoles and imidazolium salts

Abstract

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