A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

Manuel Souto; Andrea Santiago-Portillo; Miguel Palomino; Iñigo J. Vitórica-Yrezábal; Bruno J.C. Vieira; João C. Waerenborgh; Susana Valencia; Sergio Navalón; Fernando Rey; Hermenegildo García; Guillermo Mínguez Espallargas

doi:10.1039/c7sc04829g

A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

Manuel Souto, Andrea Santiago-Portillo, Miguel Palomino, Iñigo J. Vitórica-Yrezábal, Bruno J.C. Vieira, João C. Waerenborgh, Susana Valencia, Sergio Navalón, Fernando Rey, Hermenegildo García, Guillermo Mínguez Espallargas^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe₃(μ₃-O)(COO)₆] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.

Original language	English
Pages (from-to)	2413-2418
Number of pages	6
Journal	Chemical Science
Volume	9
Issue number	9
Early online date	24 Jan 2018
DOIs	https://doi.org/10.1039/c7sc04829g
Publication status	Published - 7 Mar 2018

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10.1039/c7sc04829gLicence: CC BY

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Souto, M., Santiago-Portillo, A., Palomino, M., Vitórica-Yrezábal, I. J., Vieira, B. J. C., Waerenborgh, J. C., Valencia, S., Navalón, S., Rey, F., García, H., & Mínguez Espallargas, G. (2018). A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst. Chemical Science, 9(9), 2413-2418. https://doi.org/10.1039/c7sc04829g

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title = "A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst",

abstract = "Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.",

author = "Manuel Souto and Andrea Santiago-Portillo and Miguel Palomino and Vit{\'o}rica-Yrez{\'a}bal, {I{\~n}igo J.} and Vieira, {Bruno J.C.} and Waerenborgh, {Jo{\~a}o C.} and Susana Valencia and Sergio Naval{\'o}n and Fernando Rey and Hermenegildo Garc{\'i}a and {M{\'i}nguez Espallargas}, Guillermo",

year = "2018",

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doi = "10.1039/c7sc04829g",

language = "English",

volume = "9",

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journal = "Chemical Science",

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Souto, M, Santiago-Portillo, A, Palomino, M, Vitórica-Yrezábal, IJ, Vieira, BJC, Waerenborgh, JC, Valencia, S, Navalón, S, Rey, F, García, H & Mínguez Espallargas, G 2018, 'A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst', Chemical Science, vol. 9, no. 9, pp. 2413-2418. https://doi.org/10.1039/c7sc04829g

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T1 - A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

AU - Souto, Manuel

AU - Santiago-Portillo, Andrea

AU - Palomino, Miguel

AU - Vitórica-Yrezábal, Iñigo J.

AU - Vieira, Bruno J.C.

AU - Waerenborgh, João C.

AU - Valencia, Susana

AU - Navalón, Sergio

AU - Rey, Fernando

AU - García, Hermenegildo

AU - Mínguez Espallargas, Guillermo

PY - 2018/3/7

Y1 - 2018/3/7

N2 - Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.

AB - Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.

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UR - http://www.mendeley.com/research/highly-stable-hierarchical-tetrathiafulvalenebased-metalorganic-framework-improved-performance-solid

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DO - 10.1039/c7sc04829g

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SN - 2041-6520

VL - 9

SP - 2413

EP - 2418

JO - Chemical Science

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ER -

A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

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CCDC 1579606: Experimental Crystal Structure Determination

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A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

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CCDC 1579606: Experimental Crystal Structure Determination

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