A lanthanide-gallium complex stabilized by the N-heterocyclic carbene group

Polly L. Arnold; Stephen T. Liddle; Jonathan McMaster; Cameron Jones; David P. Mills

doi:10.1021/ja0710858

A lanthanide-gallium complex stabilized by the N-heterocyclic carbene group

Polly L. Arnold, Stephen T. Liddle, Jonathan McMaster, Cameron Jones, David P. Mills

The University of Manchester

Research output: Contribution to journal › Article › peer-review

Abstract

The complex [Nd(L′){Ga(NArCH)2}(N″)(THF)], which exhibits the first f-element-gallium bond, is formed from the reaction between the N-heterocyclic carbene-supported neodymium complex [Nd(L′)(N″)(I)] (L′ = ButNCH2CH2{C(NCSiMe3 CHNBut)}; N″ = N(SiMe3)2) and the anionic gallium(I) heterocycle [Ga(NArCH)2][K(tmeda)] (Ar = 2,6-Pri2C6H3). The Nd-Ga bond energy is calculated to be 386 kJ mol-1. Copyright © 2007 American Chemical Society.

Original language	English
Pages (from-to)	5360-5361
Number of pages	1
Journal	Journal of the American Chemical Society
Volume	129
Issue number	17
DOIs	https://doi.org/10.1021/ja0710858
Publication status	Published - 2 May 2007

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10.1021/ja0710858

CCDC 829336: Experimental Crystal Structure Determination
Arnold, P. L. (Contributor), Liddle, S. (Contributor), McMaster, J. (Contributor), Jones, C. (Contributor) & Mills, D. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccwtzsf, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwtzsf&sid=DataCite
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Cite this

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title = "A lanthanide-gallium complex stabilized by the N-heterocyclic carbene group",

abstract = "The complex [Nd(L′){Ga(NArCH)2}(N″)(THF)], which exhibits the first f-element-gallium bond, is formed from the reaction between the N-heterocyclic carbene-supported neodymium complex [Nd(L′)(N″)(I)] (L′ = ButNCH2CH2{C(NCSiMe3 CHNBut)}; N″ = N(SiMe3)2) and the anionic gallium(I) heterocycle [Ga(NArCH)2][K(tmeda)] (Ar = 2,6-Pri2C6H3). The Nd-Ga bond energy is calculated to be 386 kJ mol-1. Copyright {\textcopyright} 2007 American Chemical Society.",

author = "Arnold, {Polly L.} and Liddle, {Stephen T.} and Jonathan McMaster and Cameron Jones and Mills, {David P.}",

note = "doi: 10.1021/ja0710858",

year = "2007",

month = may,

day = "2",

doi = "10.1021/ja0710858",

language = "English",

volume = "129",

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journal = "Journal of the American Chemical Society",

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TY - JOUR

T1 - A lanthanide-gallium complex stabilized by the N-heterocyclic carbene group

AU - Arnold, Polly L.

AU - Liddle, Stephen T.

AU - McMaster, Jonathan

AU - Jones, Cameron

AU - Mills, David P.

N1 - doi: 10.1021/ja0710858

PY - 2007/5/2

Y1 - 2007/5/2

N2 - The complex [Nd(L′){Ga(NArCH)2}(N″)(THF)], which exhibits the first f-element-gallium bond, is formed from the reaction between the N-heterocyclic carbene-supported neodymium complex [Nd(L′)(N″)(I)] (L′ = ButNCH2CH2{C(NCSiMe3 CHNBut)}; N″ = N(SiMe3)2) and the anionic gallium(I) heterocycle [Ga(NArCH)2][K(tmeda)] (Ar = 2,6-Pri2C6H3). The Nd-Ga bond energy is calculated to be 386 kJ mol-1. Copyright © 2007 American Chemical Society.

AB - The complex [Nd(L′){Ga(NArCH)2}(N″)(THF)], which exhibits the first f-element-gallium bond, is formed from the reaction between the N-heterocyclic carbene-supported neodymium complex [Nd(L′)(N″)(I)] (L′ = ButNCH2CH2{C(NCSiMe3 CHNBut)}; N″ = N(SiMe3)2) and the anionic gallium(I) heterocycle [Ga(NArCH)2][K(tmeda)] (Ar = 2,6-Pri2C6H3). The Nd-Ga bond energy is calculated to be 386 kJ mol-1. Copyright © 2007 American Chemical Society.

U2 - 10.1021/ja0710858

DO - 10.1021/ja0710858

M3 - Article

SN - 0002-7863

VL - 129

SP - 5360

EP - 5361

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 17

ER -

A lanthanide-gallium complex stabilized by the N-heterocyclic carbene group

Abstract

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CCDC 829336: Experimental Crystal Structure Determination

Cite this