A magnesium-bis(diaryldiketiminate) complex

Alan R. Kennedy; Francis S. Mair

doi:10.1107/S010827010302376X

A magnesium-bis(diaryldiketiminate) complex

Alan R. Kennedy
, Francis S. Mair

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal structure of magnesium-bis(diaryldiketiminate) Mg(II) 2 complex, first reported group 2 complex containing ligand(II) was studied. Mg(II)2 is isomorphous, isostructural and isotypic with its zinc analogue. The coordination geometry about the Mg atom is dostorted tetrahedral with the metal lying out of the ligand plane. The ligands adopted a locak and approximate non-crystallographic Cs symmetry.

Original language	English
Pages (from-to)	m549-m551
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	59
Issue number	12
DOIs	https://doi.org/10.1107/S010827010302376X
Publication status	Published - Dec 2003

Keywords

Crystal structure; Molecular structure (of magnesium bis(isopropylphenyl)pentanediiminato complex)

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10.1107/S010827010302376X

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title = "A magnesium-bis(diaryldiketiminate) complex",

abstract = "The crystal structure of magnesium-bis(diaryldiketiminate) Mg(II) 2 complex, first reported group 2 complex containing ligand(II) was studied. Mg(II)2 is isomorphous, isostructural and isotypic with its zinc analogue. The coordination geometry about the Mg atom is dostorted tetrahedral with the metal lying out of the ligand plane. The ligands adopted a locak and approximate non-crystallographic Cs symmetry.",

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AU - Mair, Francis S.

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AB - The crystal structure of magnesium-bis(diaryldiketiminate) Mg(II) 2 complex, first reported group 2 complex containing ligand(II) was studied. Mg(II)2 is isomorphous, isostructural and isotypic with its zinc analogue. The coordination geometry about the Mg atom is dostorted tetrahedral with the metal lying out of the ligand plane. The ligands adopted a locak and approximate non-crystallographic Cs symmetry.

KW - Crystal structure; Molecular structure (of magnesium bis(isopropylphenyl)pentanediiminato complex)

U2 - 10.1107/S010827010302376X

DO - 10.1107/S010827010302376X

M3 - Article

SN - 0108-2701

VL - 59

SP - m549-m551

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 12

ER -

A magnesium-bis(diaryldiketiminate) complex

Abstract

Keywords

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