A manganese(II) allyl complex: Synthesis, structure, and magnetic properties of [Li(thf)4] [Mn{η3-(Me 3Si)2C3H3}{η1- (Me3Si)2C3H3}2]

Richard A. Layfield; Simon M. Humphrey

doi:10.1002/anie.200454008

A manganese(II) allyl complex: Synthesis, structure, and magnetic properties of [Li(thf)4] [Mn{η3-(Me 3Si)2C3H3}{η1- (Me3Si)2C3H3}2]

Richard A. Layfield, Simon M. Humphrey

Research output: Contribution to journal › Article › peer-review

Abstract

Lucky thirteen: The first example of a manganese(II) allyl complex, [Li(thf)4] [Mn{η3(Me3Si)2C 3H3}{η1-(Me3Si) 2C3H3}2], contains a tris(allyl)-manganate monoanion (depicted). The structure of the anion was determined and shown to contain both π- and σ-allyl ligands, resulting in an unusually low valence-electron count of thirteen.

Original language	English
Pages (from-to)	3067-3069
Number of pages	2
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	23
DOIs	https://doi.org/10.1002/anie.200454008
Publication status	Published - 7 Jun 2004

Keywords

Allyl ligands
Magnetic properties
Manganese
Structure elucidation

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title = "A manganese(II) allyl complex: Synthesis, structure, and magnetic properties of [Li(thf)4] [Mn{η3-(Me 3Si)2C3H3}{η1- (Me3Si)2C3H3}2]",

abstract = "Lucky thirteen: The first example of a manganese(II) allyl complex, [Li(thf)4] [Mn{η3(Me3Si)2C 3H3}{η1-(Me3Si) 2C3H3}2], contains a tris(allyl)-manganate monoanion (depicted). The structure of the anion was determined and shown to contain both π- and σ-allyl ligands, resulting in an unusually low valence-electron count of thirteen.",

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T1 - A manganese(II) allyl complex: Synthesis, structure, and magnetic properties of [Li(thf)4] [Mn{η3-(Me 3Si)2C3H3}{η1- (Me3Si)2C3H3}2]

AU - Layfield, Richard A.

AU - Humphrey, Simon M.

PY - 2004/6/7

Y1 - 2004/6/7

N2 - Lucky thirteen: The first example of a manganese(II) allyl complex, [Li(thf)4] [Mn{η3(Me3Si)2C 3H3}{η1-(Me3Si) 2C3H3}2], contains a tris(allyl)-manganate monoanion (depicted). The structure of the anion was determined and shown to contain both π- and σ-allyl ligands, resulting in an unusually low valence-electron count of thirteen.

AB - Lucky thirteen: The first example of a manganese(II) allyl complex, [Li(thf)4] [Mn{η3(Me3Si)2C 3H3}{η1-(Me3Si) 2C3H3}2], contains a tris(allyl)-manganate monoanion (depicted). The structure of the anion was determined and shown to contain both π- and σ-allyl ligands, resulting in an unusually low valence-electron count of thirteen.

KW - Allyl ligands

KW - Magnetic properties

KW - Manganese

KW - Structure elucidation

UR - https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.5517/cc7rkfy&sid=DataCite

U2 - 10.1002/anie.200454008

DO - 10.1002/anie.200454008

M3 - Article

SN - 1433-7851

VL - 43

SP - 3067

EP - 3069

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 23

ER -

A manganese(II) allyl complex: Synthesis, structure, and magnetic properties of [Li(thf)4] [Mn{η3-(Me 3Si)2C3H3}{η1- (Me3Si)2C3H3}2]

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