TY - JOUR
T1 - A mechanistic change in the alkaline hydrolysis of esters of fluorene-9-carboxylic acid
AU - Alborz, Manoochehr
AU - Douglas, Kenneth T.
PY - 1980
Y1 - 1980
N2 - The Brønsted leaving group (β1g) plot for the alkaline hydrolysis of fluorene-9-carboxylate esters in the pH region corresponding to the existence of the ester anion shows a minimum flanked by a region of high negative β1g (-1 01), corresponding to an E1cb pathway and, for esters of pK1g > 9 5, a region of positive β1g (+0.11).
AB - The Brønsted leaving group (β1g) plot for the alkaline hydrolysis of fluorene-9-carboxylate esters in the pH region corresponding to the existence of the ester anion shows a minimum flanked by a region of high negative β1g (-1 01), corresponding to an E1cb pathway and, for esters of pK1g > 9 5, a region of positive β1g (+0.11).
UR - http://www.scopus.com/inward/record.url?scp=37049112606&partnerID=8YFLogxK
U2 - 10.1039/c39800000728
DO - 10.1039/c39800000728
M3 - Article
AN - SCOPUS:37049112606
SN - 0022-4936
SP - 728
EP - 730
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 15
ER -