TY - JOUR
T1 - A nickel(II) compound with a tetradentate diamine-diimine ligand, (2,4,6,9,11-pentamethyl-5,8-diazadodeca-4,8-diene-2,11-diamine)nickel(II) tetrachlorozincate
AU - Gladkikh, Olga P
AU - Curtis, Neil F
AU - Heath, Sarah L
N1 - CAPLUS AN 1998:29084(Journal)
PY - 1997
Y1 - 1997
N2 - The title compd. is monoclinic, space group P21/c, with a 9.3718(14), b 17.085(3), c 14.351(2) Å, and β 95.121(4)°; Z = 4, dc = 1.551; R = 0.047, Rw(F2) = 0.109 for 5241 reflections. The compd. has a tetradentate diamine-diimine ligand in a tetrahedrally twisted square-planar coordination to singlet ground-state Ni(II), with a mean Ni-N distance of 1.909(3) Å. The cation has approx. mirror symmetry, apart from the axially oriented C6 Me-substituent. [on SciFinder(R)]
AB - The title compd. is monoclinic, space group P21/c, with a 9.3718(14), b 17.085(3), c 14.351(2) Å, and β 95.121(4)°; Z = 4, dc = 1.551; R = 0.047, Rw(F2) = 0.109 for 5241 reflections. The compd. has a tetradentate diamine-diimine ligand in a tetrahedrally twisted square-planar coordination to singlet ground-state Ni(II), with a mean Ni-N distance of 1.909(3) Å. The cation has approx. mirror symmetry, apart from the axially oriented C6 Me-substituent. [on SciFinder(R)]
KW - mol structure nickel methyldiazadodecadienediamine chlorozincate
UR - https://www.scopus.com/pages/publications/5844328011
U2 - 10.1107/S0108270197009840
DO - 10.1107/S0108270197009840
M3 - Article
SN - 0108-2701
VL - C53
SP - 1770
EP - 1772
JO - Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
JF - Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
IS - 12
ER -