A novel magnetically coupled nonamanganese(II) 3 × 3 portcullis-like grid involving just oxygen bridges, generated by strict self assembly of the metal cation and a single heptadentate ligand

Liang Zhao; Craig J Matthews; Laurence K Thompson; Sarah L Heath

doi:10.1039/a909180g

A novel magnetically coupled nonamanganese(II) 3 × 3 portcullis-like grid involving just oxygen bridges, generated by strict self assembly of the metal cation and a single heptadentate ligand

Liang Zhao, Craig J Matthews, Laurence K Thompson, Sarah L Heath

Research output: Contribution to journal › Article › peer-review

Abstract

The heptadentate ligand 2POAP (I) combines two bridging alkoxide oxygen donors with diazine and pyridine terminal nitrogen donors in a linear array with the binding sites positioned critically to accommodate three metal centers, but on reaction with Mn(ClO4)2·6H2O a strict self assembly process occurs, producing a unique homoleptic nonamanganese 'square' grid complex, involving six ligands. The crystal structure of [Mn9(2POAP-2H)6](ClO4)6·3.57MeCN·11H2O was detd. Electrochem. studies show that the complex undergoes a 4 electron oxidn. process followed by four more addnl. 1 electron oxidn. steps. Variable temp. magnetic susceptibility measurements reveal the presence of antiferromagnetic exchange as well as a very weak ferromagnetic interaction at

Original language	English
Pages (from-to)	265-266
Number of pages	2
Journal	Chem. Commun. (Cambridge)
Issue number	4
DOIs	https://doi.org/10.1039/a909180g
Publication status	Published - 2000

Keywords

manganese heptadentate diazine nonanuclear self assembly
pyridinedicarboxylic dihydrazide heptadentate manganese self assembly
crystal structure manganese heptadentate diazine nonanuclear
magnetism manganese heptadentate diazine nonanuclear complex
electrochem oxidn manganese heptadentate diazine nonanuclear

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10.1039/a909180g

http://pubs.rsc.org/en/content/articlepdf/2000/cc/a909180g

CCDC 141507: Experimental Crystal Structure Determination
Zhao, L. (Contributor), Matthews, C. J. (Contributor), Thompson, L. K. (Contributor) & Heath, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2000
DOI: 10.5517/cc4r7rv, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc4r7rv&sid=DataCite
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title = "A novel magnetically coupled nonamanganese(II) 3 × 3 portcullis-like grid involving just oxygen bridges, generated by strict self assembly of the metal cation and a single heptadentate ligand",

abstract = "The heptadentate ligand 2POAP (I) combines two bridging alkoxide oxygen donors with diazine and pyridine terminal nitrogen donors in a linear array with the binding sites positioned critically to accommodate three metal centers, but on reaction with Mn(ClO4)2·6H2O a strict self assembly process occurs, producing a unique homoleptic nonamanganese 'square' grid complex, involving six ligands. The crystal structure of [Mn9(2POAP-2H)6](ClO4)6·3.57MeCN·11H2O was detd. Electrochem. studies show that the complex undergoes a 4 electron oxidn. process followed by four more addnl. 1 electron oxidn. steps. Variable temp. magnetic susceptibility measurements reveal the presence of antiferromagnetic exchange as well as a very weak ferromagnetic interaction at",

keywords = "manganese heptadentate diazine nonanuclear self assembly, pyridinedicarboxylic dihydrazide heptadentate manganese self assembly, crystal structure manganese heptadentate diazine nonanuclear, magnetism manganese heptadentate diazine nonanuclear complex, electrochem oxidn manganese heptadentate diazine nonanuclear",

author = "Liang Zhao and Matthews, {Craig J} and Thompson, {Laurence K} and Heath, {Sarah L}",

note = "CAPLUS AN 2000:104475(Journal)",

year = "2000",

doi = "10.1039/a909180g",

language = "English",

pages = "265--266",

journal = "Chem. Commun. (Cambridge)",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "4",

}

A novel magnetically coupled nonamanganese(II) 3 × 3 portcullis-like grid involving just oxygen bridges, generated by strict self assembly of the metal cation and a single heptadentate ligand. / Zhao, Liang; Matthews, Craig J; Thompson, Laurence K et al.
In: Chem. Commun. (Cambridge), No. 4, 2000, p. 265-266.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A novel magnetically coupled nonamanganese(II) 3 × 3 portcullis-like grid involving just oxygen bridges, generated by strict self assembly of the metal cation and a single heptadentate ligand

AU - Zhao, Liang

AU - Matthews, Craig J

AU - Thompson, Laurence K

AU - Heath, Sarah L

N1 - CAPLUS AN 2000:104475(Journal)

PY - 2000

Y1 - 2000

N2 - The heptadentate ligand 2POAP (I) combines two bridging alkoxide oxygen donors with diazine and pyridine terminal nitrogen donors in a linear array with the binding sites positioned critically to accommodate three metal centers, but on reaction with Mn(ClO4)2·6H2O a strict self assembly process occurs, producing a unique homoleptic nonamanganese 'square' grid complex, involving six ligands. The crystal structure of [Mn9(2POAP-2H)6](ClO4)6·3.57MeCN·11H2O was detd. Electrochem. studies show that the complex undergoes a 4 electron oxidn. process followed by four more addnl. 1 electron oxidn. steps. Variable temp. magnetic susceptibility measurements reveal the presence of antiferromagnetic exchange as well as a very weak ferromagnetic interaction at

AB - The heptadentate ligand 2POAP (I) combines two bridging alkoxide oxygen donors with diazine and pyridine terminal nitrogen donors in a linear array with the binding sites positioned critically to accommodate three metal centers, but on reaction with Mn(ClO4)2·6H2O a strict self assembly process occurs, producing a unique homoleptic nonamanganese 'square' grid complex, involving six ligands. The crystal structure of [Mn9(2POAP-2H)6](ClO4)6·3.57MeCN·11H2O was detd. Electrochem. studies show that the complex undergoes a 4 electron oxidn. process followed by four more addnl. 1 electron oxidn. steps. Variable temp. magnetic susceptibility measurements reveal the presence of antiferromagnetic exchange as well as a very weak ferromagnetic interaction at

KW - manganese heptadentate diazine nonanuclear self assembly

KW - pyridinedicarboxylic dihydrazide heptadentate manganese self assembly

KW - crystal structure manganese heptadentate diazine nonanuclear

KW - magnetism manganese heptadentate diazine nonanuclear complex

KW - electrochem oxidn manganese heptadentate diazine nonanuclear

U2 - 10.1039/a909180g

DO - 10.1039/a909180g

M3 - Article

SN - 1359-7345

SP - 265

EP - 266

JO - Chem. Commun. (Cambridge)

JF - Chem. Commun. (Cambridge)

IS - 4

ER -

A novel magnetically coupled nonamanganese(II) 3 × 3 portcullis-like grid involving just oxygen bridges, generated by strict self assembly of the metal cation and a single heptadentate ligand

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CCDC 141507: Experimental Crystal Structure Determination

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