A novel open-box shaped pentamer of vertically linked porphyrins that selectively recognizes S-bonded Me2SO complexes

Enzo Alessio; Michela Macchi; Sarah Heath; Luigi G Marzilli

doi:10.1039/cc9960001411

A novel open-box shaped pentamer of vertically linked porphyrins that selectively recognizes S-bonded Me2SO complexes

Enzo Alessio, Michela Macchi, Sarah Heath, Luigi G Marzilli

Research output: Contribution to journal › Article › peer-review

Abstract

A new stable open-box shaped pentamer of vertically linked porphyrins, is formed quant. by treatment of tetra-4-pyridylporphyrin (TPyP) with [Ru(TPP)CO(EtOH)], (TPP = tetraphenylporphyrin) to give (TPyP)[Ru(TPP)CO]4 1. (Trans-DPyDP)[Ru(TPP)CO]2 2, (cis-DPyDP)[Ru(TPP)CO]2 3 and [Ru(TPP)(CO)(MPyTP)] 4, were similarly synthesized (trans-DPyDP = 5,15-di-4-pyridyl-10,20-diphenylporphyrin, cis-DPyDP = 5,10-di-4-pyridyl-15,20-diphenylporphyrin, MPyTP = 5,(4-pyridyl)-10,15,20-triphenylporphyrin). The Zn derivs. Zn1, Zn3 and Zn4 were synthesized by treatment of 1,3 and 4 with zinc acetate. Zn1 adds S-bonded RuII-Me2SO complexes which can enter the box to form adducts contg. the rare bridging Me2SO. [on SciFinder(R)]

Original language	English
Pages (from-to)	1411-1412
Number of pages	2
Journal	Chem. Commun. (Cambridge)
Issue number	12
DOIs	https://doi.org/10.1039/cc9960001411
Publication status	Published - 1996

Keywords

ruthenium zinc porphyrin oligomer prepn
DMSO selectivity ruthenium zinc porphyrin pentamer

Access to Document

10.1039/cc9960001411

Cite this

@article{54794b56b65a4cb794c6958db6e0dc9c,

title = "A novel open-box shaped pentamer of vertically linked porphyrins that selectively recognizes S-bonded Me2SO complexes",

abstract = "A new stable open-box shaped pentamer of vertically linked porphyrins, is formed quant. by treatment of tetra-4-pyridylporphyrin (TPyP) with [Ru(TPP)CO(EtOH)], (TPP = tetraphenylporphyrin) to give (TPyP)[Ru(TPP)CO]4 1. (Trans-DPyDP)[Ru(TPP)CO]2 2, (cis-DPyDP)[Ru(TPP)CO]2 3 and [Ru(TPP)(CO)(MPyTP)] 4, were similarly synthesized (trans-DPyDP = 5,15-di-4-pyridyl-10,20-diphenylporphyrin, cis-DPyDP = 5,10-di-4-pyridyl-15,20-diphenylporphyrin, MPyTP = 5,(4-pyridyl)-10,15,20-triphenylporphyrin). The Zn derivs. Zn1, Zn3 and Zn4 were synthesized by treatment of 1,3 and 4 with zinc acetate. Zn1 adds S-bonded RuII-Me2SO complexes which can enter the box to form adducts contg. the rare bridging Me2SO. [on SciFinder(R)]",

keywords = "ruthenium zinc porphyrin oligomer prepn, DMSO selectivity ruthenium zinc porphyrin pentamer",

author = "Enzo Alessio and Michela Macchi and Sarah Heath and Marzilli, {Luigi G}",

note = "CAPLUS AN 1996:402970(Journal)",

year = "1996",

doi = "10.1039/cc9960001411",

language = "English",

pages = "1411--1412",

journal = "Chem. Commun. (Cambridge)",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "12",

}

TY - JOUR

T1 - A novel open-box shaped pentamer of vertically linked porphyrins that selectively recognizes S-bonded Me2SO complexes

AU - Alessio, Enzo

AU - Macchi, Michela

AU - Heath, Sarah

AU - Marzilli, Luigi G

N1 - CAPLUS AN 1996:402970(Journal)

PY - 1996

Y1 - 1996

N2 - A new stable open-box shaped pentamer of vertically linked porphyrins, is formed quant. by treatment of tetra-4-pyridylporphyrin (TPyP) with [Ru(TPP)CO(EtOH)], (TPP = tetraphenylporphyrin) to give (TPyP)[Ru(TPP)CO]4 1. (Trans-DPyDP)[Ru(TPP)CO]2 2, (cis-DPyDP)[Ru(TPP)CO]2 3 and [Ru(TPP)(CO)(MPyTP)] 4, were similarly synthesized (trans-DPyDP = 5,15-di-4-pyridyl-10,20-diphenylporphyrin, cis-DPyDP = 5,10-di-4-pyridyl-15,20-diphenylporphyrin, MPyTP = 5,(4-pyridyl)-10,15,20-triphenylporphyrin). The Zn derivs. Zn1, Zn3 and Zn4 were synthesized by treatment of 1,3 and 4 with zinc acetate. Zn1 adds S-bonded RuII-Me2SO complexes which can enter the box to form adducts contg. the rare bridging Me2SO. [on SciFinder(R)]

AB - A new stable open-box shaped pentamer of vertically linked porphyrins, is formed quant. by treatment of tetra-4-pyridylporphyrin (TPyP) with [Ru(TPP)CO(EtOH)], (TPP = tetraphenylporphyrin) to give (TPyP)[Ru(TPP)CO]4 1. (Trans-DPyDP)[Ru(TPP)CO]2 2, (cis-DPyDP)[Ru(TPP)CO]2 3 and [Ru(TPP)(CO)(MPyTP)] 4, were similarly synthesized (trans-DPyDP = 5,15-di-4-pyridyl-10,20-diphenylporphyrin, cis-DPyDP = 5,10-di-4-pyridyl-15,20-diphenylporphyrin, MPyTP = 5,(4-pyridyl)-10,15,20-triphenylporphyrin). The Zn derivs. Zn1, Zn3 and Zn4 were synthesized by treatment of 1,3 and 4 with zinc acetate. Zn1 adds S-bonded RuII-Me2SO complexes which can enter the box to form adducts contg. the rare bridging Me2SO. [on SciFinder(R)]

KW - ruthenium zinc porphyrin oligomer prepn

KW - DMSO selectivity ruthenium zinc porphyrin pentamer

U2 - 10.1039/cc9960001411

DO - 10.1039/cc9960001411

M3 - Article

SN - 1359-7345

SP - 1411

EP - 1412

JO - Chem. Commun. (Cambridge)

JF - Chem. Commun. (Cambridge)

IS - 12

ER -

A novel open-box shaped pentamer of vertically linked porphyrins that selectively recognizes S-bonded Me2SO complexes

Abstract

Keywords

Access to Document

Fingerprint

Cite this