A novel scandium ortho-methoxynitrosobenzene-dimer complex: Mechanistic implications for the nitroso-Diels-Alder reaction

Andrew P. Lightfoot; Robin G. Pritchard; Hayley Wan; John E. Warren; Andrew Whiting

doi:10.1039/b206366b

A novel scandium ortho-methoxynitrosobenzene-dimer complex: Mechanistic implications for the nitroso-Diels-Alder reaction

Andrew P. Lightfoot, Robin G. Pritchard, Hayley Wan, John E. Warren, Andrew Whiting

Research output: Contribution to journal › Article › peer-review

Abstract

Arylnitroso dienophiles exist in equilibrium with their dimeric counterparts, which in turn form stable bidentate complexes with scandium(III) triflate and react with cyclohexadiene to give the corresponding Diels-Alder adduct at the same rate as the normal thermal process.

Original language	English
Pages (from-to)	2072-2073
Number of pages	1
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/b206366b
Publication status	Published - 2002

Keywords

ACID
C-NITROSOBENZENES
CYCLOADDITIONS
{CYCLOADDITIONS
CYCLOPENTADIENE
{CYCLOPENTADIENE
OXIDATION
{INVESTIGATIONS
IRON
IRON} {SALTS
{OXIDATION
{SALTS
STRUCTURAL
STRUCTURAL} {INVESTIGATIONS
{STRUCTURAL} {INVESTIGATIONS
IRON SALTS

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10.1039/b206366b

CCDC 176704: Experimental Crystal Structure Determination
Lightfoot, A. P. (Contributor), Pritchard, R. (Contributor), Wan, H. (Contributor), Warren, J. (Contributor) & Whiting, A. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2002
DOI: 10.5517/cc5xw42, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc5xw42&sid=DataCite
Dataset
CCDC 177523: Experimental Crystal Structure Determination
Lightfoot, A. P. (Contributor), Pritchard, R. (Contributor), Wan, H. (Contributor), Warren, J. (Contributor) & Whiting, A. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2002
DOI: 10.5517/cc5yqkc, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc5yqkc&sid=DataCite
Dataset

Cite this

@article{0a92e81748e84a60b71570ac2202fe11,

title = "A novel scandium ortho-methoxynitrosobenzene-dimer complex: Mechanistic implications for the nitroso-Diels-Alder reaction",

abstract = "Arylnitroso dienophiles exist in equilibrium with their dimeric counterparts, which in turn form stable bidentate complexes with scandium(III) triflate and react with cyclohexadiene to give the corresponding Diels-Alder adduct at the same rate as the normal thermal process.",

keywords = "ACID, C-NITROSOBENZENES, CYCLOADDITIONS, {CYCLOADDITIONS, CYCLOPENTADIENE, {CYCLOPENTADIENE, OXIDATION, {INVESTIGATIONS, IRON, IRON} {SALTS, {OXIDATION, {SALTS, STRUCTURAL, STRUCTURAL} {INVESTIGATIONS, {STRUCTURAL} {INVESTIGATIONS, IRON SALTS",

author = "Lightfoot, {Andrew P.} and Pritchard, {Robin G.} and Hayley Wan and Warren, {John E.} and Andrew Whiting",

note = "18",

year = "2002",

doi = "10.1039/b206366b",

language = "English",

pages = "2072--2073",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "18",

}

TY - JOUR

T1 - A novel scandium ortho-methoxynitrosobenzene-dimer complex: Mechanistic implications for the nitroso-Diels-Alder reaction

AU - Lightfoot, Andrew P.

AU - Pritchard, Robin G.

AU - Wan, Hayley

AU - Warren, John E.

AU - Whiting, Andrew

N1 - 18

PY - 2002

Y1 - 2002

N2 - Arylnitroso dienophiles exist in equilibrium with their dimeric counterparts, which in turn form stable bidentate complexes with scandium(III) triflate and react with cyclohexadiene to give the corresponding Diels-Alder adduct at the same rate as the normal thermal process.

AB - Arylnitroso dienophiles exist in equilibrium with their dimeric counterparts, which in turn form stable bidentate complexes with scandium(III) triflate and react with cyclohexadiene to give the corresponding Diels-Alder adduct at the same rate as the normal thermal process.

KW - ACID

KW - C-NITROSOBENZENES

KW - CYCLOADDITIONS

KW - {CYCLOADDITIONS

KW - CYCLOPENTADIENE

KW - {CYCLOPENTADIENE

KW - OXIDATION

KW - {INVESTIGATIONS

KW - IRON

KW - IRON} {SALTS

KW - {OXIDATION

KW - {SALTS

KW - STRUCTURAL

KW - STRUCTURAL} {INVESTIGATIONS

KW - {STRUCTURAL} {INVESTIGATIONS

KW - IRON SALTS

U2 - 10.1039/b206366b

DO - 10.1039/b206366b

M3 - Article

SN - 1359-7345

SP - 2072

EP - 2073

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

A novel scandium ortho-methoxynitrosobenzene-dimer complex: Mechanistic implications for the nitroso-Diels-Alder reaction

Abstract

Keywords

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Datasets

CCDC 176704: Experimental Crystal Structure Determination

CCDC 177523: Experimental Crystal Structure Determination

Cite this