Abstract
PbS nanocrystal (nc-PbS) - C60 photovoltaic devices are demonstrated, in which nc-PbS function as electron donors, showing infrared photosensitivity up to 1600 nm. Annealing nc-PbS is proved to remove capping oleic acid ligands, studied using x-ray photoelectron spectroscopy, significantly improving the short circuit current, open circuit voltage, and fill factor. The device performance is rationalized by quantum confinement in nc-PbS and energy level alignment at the heterojunction based on direct measurements of nc-PbS ionization potential using ultraviolet photoelectron spectroscopy.
Original language | English |
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Article number | 133506 |
Journal | Applied Physics Letters |
Volume | 91 |
Issue number | 13 |
DOIs | |
Publication status | Published - 2007 |