A PbS nanocrystal- C60 photovoltaic device for infrared light harvesting

D. M N M Dissanayake, Ross A. Hatton, Thierry Lutz, Cristina E. Giusca, Richard J. Curry, S. R P Silva

    Research output: Contribution to journalArticlepeer-review

    Abstract

    PbS nanocrystal (nc-PbS) - C60 photovoltaic devices are demonstrated, in which nc-PbS function as electron donors, showing infrared photosensitivity up to 1600 nm. Annealing nc-PbS is proved to remove capping oleic acid ligands, studied using x-ray photoelectron spectroscopy, significantly improving the short circuit current, open circuit voltage, and fill factor. The device performance is rationalized by quantum confinement in nc-PbS and energy level alignment at the heterojunction based on direct measurements of nc-PbS ionization potential using ultraviolet photoelectron spectroscopy.

    Original languageEnglish
    Article number133506
    JournalApplied Physics Letters
    Volume91
    Issue number13
    DOIs
    Publication statusPublished - 2007

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