A phthalocyanine clathrate of cubic symmetry containing interconnected solvent-filled voids of nanometer dimensions

Neil B. McKeown; Saad Makhseed; Kadhum J. Msayib; Li Ling Ooi; Madeleine Helliwell; John E. Warren

doi:10.1002/anie.200502668

A phthalocyanine clathrate of cubic symmetry containing interconnected solvent-filled voids of nanometer dimensions

Neil B. McKeown, Saad Makhseed, Kadhum J. Msayib, Li Ling Ooi, Madeleine Helliwell, John E. Warren

Research output: Contribution to journal › Article › peer-review

Abstract

(Figure Presented) A void apart! A clathrate based on zinc octa(2,6-diisopropylphenoxy)phthalocyanine contains solvent-filled voids of exceptionally large volume (> 8 nm3; see picture for the packing arrangement). Each nanovoid is enclosed by a cubic assembly of six phthalocyanine molecules and contains 18 molecules of water and an estimated 65 molecules of acetone, which may be exchanged for methanol or water molecules without loss of order. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	7546-7549
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	46
DOIs	https://doi.org/10.1002/anie.200502668
Publication status	Published - 25 Nov 2005

Keywords

Clathrates
Crystal engineering
Microporous materials
Nanostructures
Phthalocyanines

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10.1002/anie.200502668

http://www3.interscience.wiley.com/cgi-bin/fulltext/112099507/HTMLSTART

CCDC 279644: Experimental Crystal Structure Determination
Mckeown, N. B. (Contributor), Makhseed, S. (Contributor), Msayib, K. J. (Contributor), Ooi, L. L. (Contributor), Helliwell, M. (Contributor) & Warren, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2006
DOI: 10.5517/cc9czsd, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc9czsd&sid=DataCite
Dataset

Cite this

@article{142ca77d35034245b42625690b555400,

title = "A phthalocyanine clathrate of cubic symmetry containing interconnected solvent-filled voids of nanometer dimensions",

abstract = "(Figure Presented) A void apart! A clathrate based on zinc octa(2,6-diisopropylphenoxy)phthalocyanine contains solvent-filled voids of exceptionally large volume (> 8 nm3; see picture for the packing arrangement). Each nanovoid is enclosed by a cubic assembly of six phthalocyanine molecules and contains 18 molecules of water and an estimated 65 molecules of acetone, which may be exchanged for methanol or water molecules without loss of order. {\textcopyright} 2005 Wiley-VCH Verlag GmbH & Co. KGaA.",

keywords = "Clathrates, Crystal engineering, Microporous materials, Nanostructures, Phthalocyanines",

author = "McKeown, {Neil B.} and Saad Makhseed and Msayib, {Kadhum J.} and Ooi, {Li Ling} and Madeleine Helliwell and Warren, {John E.}",

year = "2005",

month = nov,

day = "25",

doi = "10.1002/anie.200502668",

language = "English",

volume = "44",

pages = "7546--7549",

journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley & Sons Ltd",

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TY - JOUR

T1 - A phthalocyanine clathrate of cubic symmetry containing interconnected solvent-filled voids of nanometer dimensions

AU - McKeown, Neil B.

AU - Makhseed, Saad

AU - Msayib, Kadhum J.

AU - Ooi, Li Ling

AU - Helliwell, Madeleine

AU - Warren, John E.

PY - 2005/11/25

Y1 - 2005/11/25

N2 - (Figure Presented) A void apart! A clathrate based on zinc octa(2,6-diisopropylphenoxy)phthalocyanine contains solvent-filled voids of exceptionally large volume (> 8 nm3; see picture for the packing arrangement). Each nanovoid is enclosed by a cubic assembly of six phthalocyanine molecules and contains 18 molecules of water and an estimated 65 molecules of acetone, which may be exchanged for methanol or water molecules without loss of order. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - (Figure Presented) A void apart! A clathrate based on zinc octa(2,6-diisopropylphenoxy)phthalocyanine contains solvent-filled voids of exceptionally large volume (> 8 nm3; see picture for the packing arrangement). Each nanovoid is enclosed by a cubic assembly of six phthalocyanine molecules and contains 18 molecules of water and an estimated 65 molecules of acetone, which may be exchanged for methanol or water molecules without loss of order. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Clathrates

KW - Crystal engineering

KW - Microporous materials

KW - Nanostructures

KW - Phthalocyanines

U2 - 10.1002/anie.200502668

DO - 10.1002/anie.200502668

M3 - Article

SN - 1433-7851

VL - 44

SP - 7546

EP - 7549

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 46

ER -

A phthalocyanine clathrate of cubic symmetry containing interconnected solvent-filled voids of nanometer dimensions

Abstract

Keywords

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Datasets

CCDC 279644: Experimental Crystal Structure Determination

Cite this