A pseudo-icosahedral cage {Gd12} based on aminomethylphosphonate

Zemin Zhang; Karzan Zangana; Andreas Kostopoulos; Ming-Liang  Tong; Richard Winpenny

doi:10.1039/C6DT00876C

A pseudo-icosahedral cage {Gd12} based on aminomethylphosphonate

Zemin Zhang, Karzan Zangana, Andreas Kostopoulos, Ming-Liang Tong, Richard Winpenny

Sun Yat-sen University

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Abstract

Reaction of (aminomethyl)phosphonic acid (ampH2) with a mixture of gadolinium and cobalt pivalates under solvothermal conditions, led to a pseudo-icosahedral cage {Gd12}, which shows a large magnetocaloric effect (MCE).

Original language	English
Pages (from-to)	9041-9044
Journal	Dalton Transactions
Volume	45
Issue number	22
Early online date	10 May 2016
DOIs	https://doi.org/10.1039/C6DT00876C
Publication status	Published - 14 Jun 2016

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title = "A pseudo-icosahedral cage {Gd12} based on aminomethylphosphonate",

abstract = "Reaction of (aminomethyl)phosphonic acid (ampH2) with a mixture of gadolinium and cobalt pivalates under solvothermal conditions, led to a pseudo-icosahedral cage {Gd12}, which shows a large magnetocaloric effect (MCE).",

author = "Zemin Zhang and Karzan Zangana and Andreas Kostopoulos and Ming-Liang Tong and Richard Winpenny",

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AU - Zhang, Zemin

AU - Zangana, Karzan

AU - Kostopoulos, Andreas

AU - Tong, Ming-Liang

AU - Winpenny, Richard

PY - 2016/6/14

Y1 - 2016/6/14

N2 - Reaction of (aminomethyl)phosphonic acid (ampH2) with a mixture of gadolinium and cobalt pivalates under solvothermal conditions, led to a pseudo-icosahedral cage {Gd12}, which shows a large magnetocaloric effect (MCE).

AB - Reaction of (aminomethyl)phosphonic acid (ampH2) with a mixture of gadolinium and cobalt pivalates under solvothermal conditions, led to a pseudo-icosahedral cage {Gd12}, which shows a large magnetocaloric effect (MCE).

U2 - 10.1039/C6DT00876C

DO - 10.1039/C6DT00876C

M3 - Article

SN - 1477-9226

VL - 45

SP - 9041

EP - 9044

JO - Dalton Transactions

JF - Dalton Transactions

IS - 22

ER -

A pseudo-icosahedral cage {Gd12} based on aminomethylphosphonate

Abstract

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