A remarkably simple and efficient benzannulation reaction

James A. Bull; Michael G. Hutchings; Peter Quayle

doi:10.1002/anie.200603416

A remarkably simple and efficient benzannulation reaction

James A. Bull, Michael G. Hutchings, Peter Quayle

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Abstract

(Chemical Equation Presented) On a short fuse: Although fused aromatic rings are common structural motifs in natural products, there are relatively few direct methods for the preparation of such systems from acyclic precursors. An atom-transfer radical cyclization carried out under microwave (MW) irradiation has now been developed which gives rapid access to functionalized aromatic compounds from readily available starting materials (see scheme). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	1869-1872
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	11
DOIs	https://doi.org/10.1002/anie.200603416
Publication status	Published - 2007

Keywords

Cyclization
Fused-ring systems
Microwave irradiation
Radical reactions
Synthetic methods

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POST-PEER-REVIEW-PUBLISHERS-DOCUMENT.PDFFinal published version, 126 KB

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AB - (Chemical Equation Presented) On a short fuse: Although fused aromatic rings are common structural motifs in natural products, there are relatively few direct methods for the preparation of such systems from acyclic precursors. An atom-transfer radical cyclization carried out under microwave (MW) irradiation has now been developed which gives rapid access to functionalized aromatic compounds from readily available starting materials (see scheme). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Cyclization

KW - Fused-ring systems

KW - Microwave irradiation

KW - Radical reactions

KW - Synthetic methods

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JF - Angewandte Chemie - International Edition

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ER -

A remarkably simple and efficient benzannulation reaction

Abstract

Keywords

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