TY - JOUR
T1 - A structural and magnetic study of organolanthanide(III) amides
AU - Layfield, Richard A.
AU - Bashall, Alan
AU - McPartlin, Mary
AU - Rawson, Jeremy M.
AU - Wright, Dominic S.
PY - 2006
Y1 - 2006
N2 - The syntheses, structures and magnetic properties of the series of dimeric organolanthanide(iii) amides [Cp2Ln{2-NH-4,6-Me2pm}] 2 [Ln = Nd (1), Gd (2), Dy (3), Yb (4) and pm = pyrimidine], which are formed from the deprotonation of 2-amino-4,6-dimethylpyrimidine by the corresponding lanthanide tris-cyclopentadienide, are reported. The synthesis and structure of [{Cp2Yb(2-NH-4-MeO-6-MeOpm)2( 3-O)(YbCp)] (5), formed in a similar deprotonation reaction but in the presence of adventitious water, is also reported. © The Royal Society of Chemistry 2006.
AB - The syntheses, structures and magnetic properties of the series of dimeric organolanthanide(iii) amides [Cp2Ln{2-NH-4,6-Me2pm}] 2 [Ln = Nd (1), Gd (2), Dy (3), Yb (4) and pm = pyrimidine], which are formed from the deprotonation of 2-amino-4,6-dimethylpyrimidine by the corresponding lanthanide tris-cyclopentadienide, are reported. The synthesis and structure of [{Cp2Yb(2-NH-4-MeO-6-MeOpm)2( 3-O)(YbCp)] (5), formed in a similar deprotonation reaction but in the presence of adventitious water, is also reported. © The Royal Society of Chemistry 2006.
UR - https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.5517/cc9lxd5&sid=DataCite
UR - https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.5517/cc9lxc4&sid=DataCite
UR - https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.5517/cc9lxh8&sid=DataCite
UR - https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.5517/cc9lxf6&sid=DataCite
UR - https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.5517/cc9lxg7&sid=DataCite
U2 - 10.1039/b514470a
DO - 10.1039/b514470a
M3 - Article
SN - 1477-9234
VL - 6
SP - 1660
EP - 1666
JO - Dalton Transactions
JF - Dalton Transactions
IS - 13
ER -