A sulfonyl-substituted aziridine

William Clegg; Sarah L Heath; Lynne Horsburgh; Richard F W Jackson; Anthony Wood

doi:10.1107/S0108270196010153

A sulfonyl-substituted aziridine

William Clegg, Sarah L Heath, Lynne Horsburgh, Richard F W Jackson, Anthony Wood

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compd., 1-p-toluenesulfonylaziridine-(2S)-carboxylic acid tert-Bu ester, C14H19NO4S, the p-toluenesulfonyl substituent on the N atom and the ester substituent on one C atom of the aziridine ring are mutually trans, minimizing steric interactions. The two N-C ring bond lengths [1.479(2) and 1.484(2) Å] are insignificantly different, consistent with the lack of regioselectivity in reactions with C nucleophiles. Crystallog. data and at. coordinates are given. [on SciFinder(R)]

Original language	English
Pages (from-to)	2779-2781
Number of pages	3
Journal	Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
Volume	C52
Issue number	11
DOIs	https://doi.org/10.1107/S0108270196010153
Publication status	Published - 1996

Keywords

mol structure butyl toluenesulfonyl aziridinecarboxylate

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10.1107/S0108270196010153

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@article{4ed64d9daa9b4ef896d1958bfab9ba5a,

title = "A sulfonyl-substituted aziridine",

abstract = "In the title compd., 1-p-toluenesulfonylaziridine-(2S)-carboxylic acid tert-Bu ester, C14H19NO4S, the p-toluenesulfonyl substituent on the N atom and the ester substituent on one C atom of the aziridine ring are mutually trans, minimizing steric interactions. The two N-C ring bond lengths [1.479(2) and 1.484(2) {\AA}] are insignificantly different, consistent with the lack of regioselectivity in reactions with C nucleophiles. Crystallog. data and at. coordinates are given. [on SciFinder(R)]",

keywords = "mol structure butyl toluenesulfonyl aziridinecarboxylate",

author = "William Clegg and Heath, {Sarah L} and Lynne Horsburgh and Jackson, {Richard F W} and Anthony Wood",

note = "CAPLUS AN 1996:738758(Journal)",

year = "1996",

doi = "10.1107/S0108270196010153",

language = "English",

volume = "C52",

pages = "2779--2781",

journal = "Acta Crystallogr., Sect. C: Cryst. Struct. Commun.",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - A sulfonyl-substituted aziridine

AU - Clegg, William

AU - Heath, Sarah L

AU - Horsburgh, Lynne

AU - Jackson, Richard F W

AU - Wood, Anthony

N1 - CAPLUS AN 1996:738758(Journal)

PY - 1996

Y1 - 1996

N2 - In the title compd., 1-p-toluenesulfonylaziridine-(2S)-carboxylic acid tert-Bu ester, C14H19NO4S, the p-toluenesulfonyl substituent on the N atom and the ester substituent on one C atom of the aziridine ring are mutually trans, minimizing steric interactions. The two N-C ring bond lengths [1.479(2) and 1.484(2) Å] are insignificantly different, consistent with the lack of regioselectivity in reactions with C nucleophiles. Crystallog. data and at. coordinates are given. [on SciFinder(R)]

AB - In the title compd., 1-p-toluenesulfonylaziridine-(2S)-carboxylic acid tert-Bu ester, C14H19NO4S, the p-toluenesulfonyl substituent on the N atom and the ester substituent on one C atom of the aziridine ring are mutually trans, minimizing steric interactions. The two N-C ring bond lengths [1.479(2) and 1.484(2) Å] are insignificantly different, consistent with the lack of regioselectivity in reactions with C nucleophiles. Crystallog. data and at. coordinates are given. [on SciFinder(R)]

KW - mol structure butyl toluenesulfonyl aziridinecarboxylate

U2 - 10.1107/S0108270196010153

DO - 10.1107/S0108270196010153

M3 - Article

SN - 0108-2701

VL - C52

SP - 2779

EP - 2781

JO - Acta Crystallogr., Sect. C: Cryst. Struct. Commun.

JF - Acta Crystallogr., Sect. C: Cryst. Struct. Commun.

IS - 11

ER -

A sulfonyl-substituted aziridine

Abstract

Keywords

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