TY - JOUR
T1 - A sulfonyl-substituted aziridine
AU - Clegg, William
AU - Heath, Sarah L
AU - Horsburgh, Lynne
AU - Jackson, Richard F W
AU - Wood, Anthony
N1 - CAPLUS AN 1996:738758(Journal)
PY - 1996
Y1 - 1996
N2 - In the title compd., 1-p-toluenesulfonylaziridine-(2S)-carboxylic acid tert-Bu ester, C14H19NO4S, the p-toluenesulfonyl substituent on the N atom and the ester substituent on one C atom of the aziridine ring are mutually trans, minimizing steric interactions. The two N-C ring bond lengths [1.479(2) and 1.484(2) Å] are insignificantly different, consistent with the lack of regioselectivity in reactions with C nucleophiles. Crystallog. data and at. coordinates are given. [on SciFinder(R)]
AB - In the title compd., 1-p-toluenesulfonylaziridine-(2S)-carboxylic acid tert-Bu ester, C14H19NO4S, the p-toluenesulfonyl substituent on the N atom and the ester substituent on one C atom of the aziridine ring are mutually trans, minimizing steric interactions. The two N-C ring bond lengths [1.479(2) and 1.484(2) Å] are insignificantly different, consistent with the lack of regioselectivity in reactions with C nucleophiles. Crystallog. data and at. coordinates are given. [on SciFinder(R)]
KW - mol structure butyl toluenesulfonyl aziridinecarboxylate
UR - https://www.scopus.com/pages/publications/0030291560
U2 - 10.1107/S0108270196010153
DO - 10.1107/S0108270196010153
M3 - Article
SN - 0108-2701
VL - C52
SP - 2779
EP - 2781
JO - Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
JF - Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
IS - 11
ER -