A supramolecular porous material comprising Fe(ii) mesocates

Benjamin H. Wilson; Hayley S. Scott; Omid T. Qazvini; Shane G. Telfer; Corine Mathonière; Rodolphe Clérac; Paul E. Kruger

doi:10.1039/c8cc07227b

A supramolecular porous material comprising Fe(ii) mesocates

Benjamin H. Wilson, Hayley S. Scott, Omid T. Qazvini, Shane G. Telfer, Corine Mathonière, Rodolphe Clérac, Paul E. Kruger

Research output: Contribution to journal › Article › peer-review

Abstract

The dinuclear mesocate [Fe2L3](BF4)4, 1, is a supramolecular building block for a microporous material. Structural analysis reveals that extensive noncovalent interactions in the solid state generate a 3D framework with microporous channels. These channels are permanently accessible to incoming guest molecules and adsorption isotherms demonstrate that the material has a high selectivity for CO2 over N2.

Original language	English
Journal	Chemical Communications
Early online date	7 Nov 2018
DOIs	https://doi.org/10.1039/c8cc07227b
Publication status	Published - 2018

Access to Document

10.1039/c8cc07227bLicence: CC BY-NC

Cite this

@article{cece161ef94f4f08acec8c11e5f56fd9,

title = "A supramolecular porous material comprising Fe(ii) mesocates",

abstract = "The dinuclear mesocate [Fe2L3](BF4)4, 1, is a supramolecular building block for a microporous material. Structural analysis reveals that extensive noncovalent interactions in the solid state generate a 3D framework with microporous channels. These channels are permanently accessible to incoming guest molecules and adsorption isotherms demonstrate that the material has a high selectivity for CO2 over N2.",

author = "Wilson, \{Benjamin H.\} and Scott, \{Hayley S.\} and Qazvini, \{Omid T.\} and Telfer, \{Shane G.\} and Corine Mathoni{\`e}re and Rodolphe Cl{\'e}rac and Kruger, \{Paul E.\}",

year = "2018",

doi = "10.1039/c8cc07227b",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - A supramolecular porous material comprising Fe(ii) mesocates

AU - Wilson, Benjamin H.

AU - Scott, Hayley S.

AU - Qazvini, Omid T.

AU - Telfer, Shane G.

AU - Mathonière, Corine

AU - Clérac, Rodolphe

AU - Kruger, Paul E.

PY - 2018

Y1 - 2018

N2 - The dinuclear mesocate [Fe2L3](BF4)4, 1, is a supramolecular building block for a microporous material. Structural analysis reveals that extensive noncovalent interactions in the solid state generate a 3D framework with microporous channels. These channels are permanently accessible to incoming guest molecules and adsorption isotherms demonstrate that the material has a high selectivity for CO2 over N2.

AB - The dinuclear mesocate [Fe2L3](BF4)4, 1, is a supramolecular building block for a microporous material. Structural analysis reveals that extensive noncovalent interactions in the solid state generate a 3D framework with microporous channels. These channels are permanently accessible to incoming guest molecules and adsorption isotherms demonstrate that the material has a high selectivity for CO2 over N2.

U2 - 10.1039/c8cc07227b

DO - 10.1039/c8cc07227b

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

A supramolecular porous material comprising Fe(ii) mesocates

Abstract

Access to Document

Fingerprint

Cite this