A time-resolved infrared vibrational spectroscopic study of the photo-dynamics of crystalline materials

Mike Towrie; Anthony W. Parker; Kate L. Ronayne; Katharine F. Bowes; Jacqueline M. Cole; Paul R. Raithby; John E. Warren

doi:10.1366/000370209787169902

A time-resolved infrared vibrational spectroscopic study of the photo-dynamics of crystalline materials

Mike Towrie, Anthony W. Parker, Kate L. Ronayne, Katharine F. Bowes, Jacqueline M. Cole, Paul R. Raithby, John E. Warren

Research output: Contribution to journal › Article › peer-review

Abstract

Time-resolved infrared vibrational spectroscopy is a structurally sensitive probe of the excited-state properties of matter. The technique has found many applications in the study of molecules in dilute solution phase but has rarely been applied to crystalline samples. We report on the use of a sensitive pump-probe time-resolved infrared spectrometer and sample handling techniques for studies of the ultrafast excited-state dynamics of crystalline materials. The charge transfer excited states of crystalline metal carbonyls and the proton transfer of dihydroxyquinones are presented and compared with the solution phase. © 2009 Society for Applied Spectroscopy.

Original language	English
Pages (from-to)	57-65
Number of pages	8
Journal	Applied Spectroscopy
Volume	63
Issue number	1
DOIs	https://doi.org/10.1366/000370209787169902
Publication status	Published - Jan 2009

Keywords

Crystal
Infrared spectroscopy
IR spectroscopy
Nanosecond measurement
Picosecond measurement
Solids
Time-resolved spectroscopy
Transient
TRIR spectroscopy
Ultrafast measurement
Vibrational

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title = "A time-resolved infrared vibrational spectroscopic study of the photo-dynamics of crystalline materials",

abstract = "Time-resolved infrared vibrational spectroscopy is a structurally sensitive probe of the excited-state properties of matter. The technique has found many applications in the study of molecules in dilute solution phase but has rarely been applied to crystalline samples. We report on the use of a sensitive pump-probe time-resolved infrared spectrometer and sample handling techniques for studies of the ultrafast excited-state dynamics of crystalline materials. The charge transfer excited states of crystalline metal carbonyls and the proton transfer of dihydroxyquinones are presented and compared with the solution phase. {\textcopyright} 2009 Society for Applied Spectroscopy.",

keywords = "Crystal, Infrared spectroscopy, IR spectroscopy, Nanosecond measurement, Picosecond measurement, Solids, Time-resolved spectroscopy, Transient, TRIR spectroscopy, Ultrafast measurement, Vibrational",

author = "Mike Towrie and Parker, {Anthony W.} and Ronayne, {Kate L.} and Bowes, {Katharine F.} and Cole, {Jacqueline M.} and Raithby, {Paul R.} and Warren, {John E.}",

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AU - Towrie, Mike

AU - Parker, Anthony W.

AU - Ronayne, Kate L.

AU - Bowes, Katharine F.

AU - Cole, Jacqueline M.

AU - Raithby, Paul R.

AU - Warren, John E.

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PY - 2009/1

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N2 - Time-resolved infrared vibrational spectroscopy is a structurally sensitive probe of the excited-state properties of matter. The technique has found many applications in the study of molecules in dilute solution phase but has rarely been applied to crystalline samples. We report on the use of a sensitive pump-probe time-resolved infrared spectrometer and sample handling techniques for studies of the ultrafast excited-state dynamics of crystalline materials. The charge transfer excited states of crystalline metal carbonyls and the proton transfer of dihydroxyquinones are presented and compared with the solution phase. © 2009 Society for Applied Spectroscopy.

AB - Time-resolved infrared vibrational spectroscopy is a structurally sensitive probe of the excited-state properties of matter. The technique has found many applications in the study of molecules in dilute solution phase but has rarely been applied to crystalline samples. We report on the use of a sensitive pump-probe time-resolved infrared spectrometer and sample handling techniques for studies of the ultrafast excited-state dynamics of crystalline materials. The charge transfer excited states of crystalline metal carbonyls and the proton transfer of dihydroxyquinones are presented and compared with the solution phase. © 2009 Society for Applied Spectroscopy.

KW - Crystal

KW - Infrared spectroscopy

KW - IR spectroscopy

KW - Nanosecond measurement

KW - Picosecond measurement

KW - Solids

KW - Time-resolved spectroscopy

KW - Transient

KW - TRIR spectroscopy

KW - Ultrafast measurement

KW - Vibrational

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DO - 10.1366/000370209787169902

M3 - Article

SN - 0003-7028

VL - 63

SP - 57

EP - 65

JO - Applied Spectroscopy

JF - Applied Spectroscopy

IS - 1

ER -

A time-resolved infrared vibrational spectroscopic study of the photo-dynamics of crystalline materials

Abstract

Keywords

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