A uranium-based UO2+-Mn2+ single-chain magnet assembled trough cation-cation interactions

Victor Mougel; Lucile Chatelain; Johannes Hermle; Roberto Caciuffo; Eric Colineau; Floriana Tuna; Nicola Magnani; Arnaud De Geyer; Jacques Pécaut; Marinella Mazzanti

doi:10.1002/anie.201307366

A uranium-based UO2+-Mn2+ single-chain magnet assembled trough cation-cation interactions

Victor Mougel, Lucile Chatelain, Johannes Hermle, Roberto Caciuffo, Eric Colineau, Floriana Tuna, Nicola Magnani, Arnaud De Geyer, Jacques Pécaut, Marinella Mazzanti

Research output: Contribution to journal › Article › peer-review

Abstract

Single-chain magnets (SCMs) are materials composed of magnetically isolated one-dimensional (1D) units exhibiting slow relaxation of magnetization. The occurrence of SCM behavior requires the fulfillment of stringent conditions for exchange and anisotropy interactions. Herein, we report the synthesis, the structure, and the magnetic characterization of the first actinide-containing SCM. The 5f-3d heterometallic 1D chains [{[UO2(salen)(py)][M(py) 4](NO3)}]n, (M=Cd (1) and M=Mn (2); py=pyridine) are assembled trough cation-cation interaction from the reaction of the uranyl(V) complex [UO2(salen)py][Cp*2Co] (Cp*=pentamethylcyclopentadienyl) with Cd(NO3)2 or Mn(NO3)2 in pyridine. The infinite UMn chain displays a high relaxation barrier of 134±0.8 K (93±0.5 cm-1), probably as a result of strong intra-chain magnetic interactions combined with the high Ising anisotropy of the uranyl(V) dioxo group. It also exhibits an open magnetic hysteresis loop at T

Original language	English
Pages (from-to)	819-823
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	53
Issue number	3
DOIs	https://doi.org/10.1002/anie.201307366
Publication status	Published - 2014

Keywords

actinides
cations
polymetallic complexes
single-chain magnets
uranium

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10.1002/anie.201307366

CCDC 956785: Experimental Crystal Structure Determination
Mougel, V. (Contributor), Chatelain, L. (Contributor), Hermie, J. (Contributor), Caciuffo, R. (Contributor), Colineau, E. (Contributor), Tuna, F. (Contributor), Magnani, N. (Contributor), De Geyer, A. (Contributor), Pécaut, J. (Contributor) & Mazzanti, M. (Contributor), Cambridge Crystallographic Data Centre, 21 Aug 2013
DOI: 10.5517/cc113m1t, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc113m1t&sid=DataCite
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title = "A uranium-based UO2+-Mn2+ single-chain magnet assembled trough cation-cation interactions",

abstract = "Single-chain magnets (SCMs) are materials composed of magnetically isolated one-dimensional (1D) units exhibiting slow relaxation of magnetization. The occurrence of SCM behavior requires the fulfillment of stringent conditions for exchange and anisotropy interactions. Herein, we report the synthesis, the structure, and the magnetic characterization of the first actinide-containing SCM. The 5f-3d heterometallic 1D chains [{[UO2(salen)(py)][M(py) 4](NO3)}]n, (M=Cd (1) and M=Mn (2); py=pyridine) are assembled trough cation-cation interaction from the reaction of the uranyl(V) complex [UO2(salen)py][Cp*2Co] (Cp*=pentamethylcyclopentadienyl) with Cd(NO3)2 or Mn(NO3)2 in pyridine. The infinite UMn chain displays a high relaxation barrier of 134±0.8 K (93±0.5 cm-1), probably as a result of strong intra-chain magnetic interactions combined with the high Ising anisotropy of the uranyl(V) dioxo group. It also exhibits an open magnetic hysteresis loop at T",

keywords = "actinides, cations, polymetallic complexes, single-chain magnets, uranium",

author = "Victor Mougel and Lucile Chatelain and Johannes Hermle and Roberto Caciuffo and Eric Colineau and Floriana Tuna and Nicola Magnani and {De Geyer}, Arnaud and Jacques P{\'e}caut and Marinella Mazzanti",

year = "2014",

doi = "10.1002/anie.201307366",

language = "English",

volume = "53",

pages = "819--823",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley & Sons Ltd",

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TY - JOUR

T1 - A uranium-based UO2+-Mn2+ single-chain magnet assembled trough cation-cation interactions

AU - Mougel, Victor

AU - Chatelain, Lucile

AU - Hermle, Johannes

AU - Caciuffo, Roberto

AU - Colineau, Eric

AU - Tuna, Floriana

AU - Magnani, Nicola

AU - De Geyer, Arnaud

AU - Pécaut, Jacques

AU - Mazzanti, Marinella

PY - 2014

Y1 - 2014

N2 - Single-chain magnets (SCMs) are materials composed of magnetically isolated one-dimensional (1D) units exhibiting slow relaxation of magnetization. The occurrence of SCM behavior requires the fulfillment of stringent conditions for exchange and anisotropy interactions. Herein, we report the synthesis, the structure, and the magnetic characterization of the first actinide-containing SCM. The 5f-3d heterometallic 1D chains [{[UO2(salen)(py)][M(py) 4](NO3)}]n, (M=Cd (1) and M=Mn (2); py=pyridine) are assembled trough cation-cation interaction from the reaction of the uranyl(V) complex [UO2(salen)py][Cp*2Co] (Cp*=pentamethylcyclopentadienyl) with Cd(NO3)2 or Mn(NO3)2 in pyridine. The infinite UMn chain displays a high relaxation barrier of 134±0.8 K (93±0.5 cm-1), probably as a result of strong intra-chain magnetic interactions combined with the high Ising anisotropy of the uranyl(V) dioxo group. It also exhibits an open magnetic hysteresis loop at T

AB - Single-chain magnets (SCMs) are materials composed of magnetically isolated one-dimensional (1D) units exhibiting slow relaxation of magnetization. The occurrence of SCM behavior requires the fulfillment of stringent conditions for exchange and anisotropy interactions. Herein, we report the synthesis, the structure, and the magnetic characterization of the first actinide-containing SCM. The 5f-3d heterometallic 1D chains [{[UO2(salen)(py)][M(py) 4](NO3)}]n, (M=Cd (1) and M=Mn (2); py=pyridine) are assembled trough cation-cation interaction from the reaction of the uranyl(V) complex [UO2(salen)py][Cp*2Co] (Cp*=pentamethylcyclopentadienyl) with Cd(NO3)2 or Mn(NO3)2 in pyridine. The infinite UMn chain displays a high relaxation barrier of 134±0.8 K (93±0.5 cm-1), probably as a result of strong intra-chain magnetic interactions combined with the high Ising anisotropy of the uranyl(V) dioxo group. It also exhibits an open magnetic hysteresis loop at T

KW - actinides

KW - cations

KW - polymetallic complexes

KW - single-chain magnets

KW - uranium

U2 - 10.1002/anie.201307366

DO - 10.1002/anie.201307366

M3 - Article

SN - 1433-7851

VL - 53

SP - 819

EP - 823

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 3

ER -

A uranium-based UO2+-Mn2+ single-chain magnet assembled trough cation-cation interactions

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CCDC 956785: Experimental Crystal Structure Determination

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