A XAS study of the structural changes undergone by amorphous copper sulfides when precipitated from solution

J. F W Mosselmans; J. M. Charnock; C. D. Garner; R. A D Pattrick; D. J. Vaughan

doi:10.1016/0921-4526(94)00879-z

A XAS study of the structural changes undergone by amorphous copper sulfides when precipitated from solution

J. F W Mosselmans, J. M. Charnock, C. D. Garner, R. A D Pattrick, D. J. Vaughan

Research output: Contribution to journal › Article › peer-review

Abstract

Amorphous copper sulfide precipitates, synthesised from Cu(NO3)2 solution and H2S/Na2S, have been studied by XAS. They all contain Cu(I) and age to covellite, but their initial form depends on the concentration of the Cu(II) solution. Low concentration solutions give rise to a brown sol, which contains trigonally coordinated Cu(I), while more concentrated solutions produce a black floc, which has a close CuCu interaction of 2.66 Å similar to that in anilite, Cu7S4 and low chalcocite, Cu2S. © 1995.

Original language	English
Pages (from-to)	609-610
Number of pages	1
Journal	Physica B: Condensed Matter
Volume	208-209
Issue number	C
DOIs	https://doi.org/10.1016/0921-4526(94)00879-z
Publication status	Published - 1 Mar 1995

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title = "A XAS study of the structural changes undergone by amorphous copper sulfides when precipitated from solution",

abstract = "Amorphous copper sulfide precipitates, synthesised from Cu(NO3)2 solution and H2S/Na2S, have been studied by XAS. They all contain Cu(I) and age to covellite, but their initial form depends on the concentration of the Cu(II) solution. Low concentration solutions give rise to a brown sol, which contains trigonally coordinated Cu(I), while more concentrated solutions produce a black floc, which has a close CuCu interaction of 2.66 {\AA} similar to that in anilite, Cu7S4 and low chalcocite, Cu2S. {\textcopyright} 1995.",

author = "Mosselmans, {J. F W} and Charnock, {J. M.} and Garner, {C. D.} and Pattrick, {R. A D} and Vaughan, {D. J.}",

note = "Times Cited: 1 8th International Conference on X-Ray Absorption Fine Structure (XAFS VIII) Aug 28-sep 01, 1994 Freie univ berlin, berlin, germany Bessy; fritz haber inst; hahn meitner inst berlin",

year = "1995",

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doi = "10.1016/0921-4526(94)00879-z",

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journal = "Physica B: Condensed Matter",

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T1 - A XAS study of the structural changes undergone by amorphous copper sulfides when precipitated from solution

AU - Mosselmans, J. F W

AU - Charnock, J. M.

AU - Garner, C. D.

AU - Pattrick, R. A D

AU - Vaughan, D. J.

N1 - Times Cited: 1 8th International Conference on X-Ray Absorption Fine Structure (XAFS VIII) Aug 28-sep 01, 1994 Freie univ berlin, berlin, germany Bessy; fritz haber inst; hahn meitner inst berlin

PY - 1995/3/1

Y1 - 1995/3/1

N2 - Amorphous copper sulfide precipitates, synthesised from Cu(NO3)2 solution and H2S/Na2S, have been studied by XAS. They all contain Cu(I) and age to covellite, but their initial form depends on the concentration of the Cu(II) solution. Low concentration solutions give rise to a brown sol, which contains trigonally coordinated Cu(I), while more concentrated solutions produce a black floc, which has a close CuCu interaction of 2.66 Å similar to that in anilite, Cu7S4 and low chalcocite, Cu2S. © 1995.

AB - Amorphous copper sulfide precipitates, synthesised from Cu(NO3)2 solution and H2S/Na2S, have been studied by XAS. They all contain Cu(I) and age to covellite, but their initial form depends on the concentration of the Cu(II) solution. Low concentration solutions give rise to a brown sol, which contains trigonally coordinated Cu(I), while more concentrated solutions produce a black floc, which has a close CuCu interaction of 2.66 Å similar to that in anilite, Cu7S4 and low chalcocite, Cu2S. © 1995.

U2 - 10.1016/0921-4526(94)00879-z

DO - 10.1016/0921-4526(94)00879-z

M3 - Article

SN - 2469-9969

VL - 208-209

SP - 609

EP - 610

JO - Physica B: Condensed Matter

JF - Physica B: Condensed Matter

IS - C

ER -

A XAS study of the structural changes undergone by amorphous copper sulfides when precipitated from solution

Abstract

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