Adsorption studies of a microporous phthalocyanine network polymer

A. Verena Maffei; Peter M. Budd; Neil B. McKeown

doi:10.1021/la060091z

Adsorption studies of a microporous phthalocyanine network polymer

A. Verena Maffei, Peter M. Budd, Neil B. McKeown

Research output: Contribution to journal › Article › peer-review

Abstract

The adsorption/desorption of N2 at 77 K and the adsorption from aqueous solution at 298 K of four organic probe molecules of different sizes (phenol, 4-nitrophenol, orange II, naphthol green B) were studied for a phthalocyanine network polymer of intrinsic microporosity (PIM) and for an activated carbon (Darco 20-40 mesh). N2 sorption analysis gave similar surface areas for the PIM and the carbon (610 and 545 m2 g-1, respectively) but showed differences in pore size distribution, the PIM being essentially microporous (pore size <2 nm), with a high proportion of ultramicropores (

Original language	English
Pages (from-to)	4225-4229
Number of pages	4
Journal	Langmuir
Volume	22
Issue number	9
DOIs	https://doi.org/10.1021/la060091z
Publication status	Published - 25 Apr 2006

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abstract = "The adsorption/desorption of N2 at 77 K and the adsorption from aqueous solution at 298 K of four organic probe molecules of different sizes (phenol, 4-nitrophenol, orange II, naphthol green B) were studied for a phthalocyanine network polymer of intrinsic microporosity (PIM) and for an activated carbon (Darco 20-40 mesh). N2 sorption analysis gave similar surface areas for the PIM and the carbon (610 and 545 m2 g-1, respectively) but showed differences in pore size distribution, the PIM being essentially microporous (pore size <2 nm), with a high proportion of ultramicropores (",

author = "Maffei, {A. Verena} and Budd, {Peter M.} and McKeown, {Neil B.}",

year = "2006",

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AU - Maffei, A. Verena

AU - Budd, Peter M.

AU - McKeown, Neil B.

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Y1 - 2006/4/25

N2 - The adsorption/desorption of N2 at 77 K and the adsorption from aqueous solution at 298 K of four organic probe molecules of different sizes (phenol, 4-nitrophenol, orange II, naphthol green B) were studied for a phthalocyanine network polymer of intrinsic microporosity (PIM) and for an activated carbon (Darco 20-40 mesh). N2 sorption analysis gave similar surface areas for the PIM and the carbon (610 and 545 m2 g-1, respectively) but showed differences in pore size distribution, the PIM being essentially microporous (pore size <2 nm), with a high proportion of ultramicropores (

AB - The adsorption/desorption of N2 at 77 K and the adsorption from aqueous solution at 298 K of four organic probe molecules of different sizes (phenol, 4-nitrophenol, orange II, naphthol green B) were studied for a phthalocyanine network polymer of intrinsic microporosity (PIM) and for an activated carbon (Darco 20-40 mesh). N2 sorption analysis gave similar surface areas for the PIM and the carbon (610 and 545 m2 g-1, respectively) but showed differences in pore size distribution, the PIM being essentially microporous (pore size <2 nm), with a high proportion of ultramicropores (

U2 - 10.1021/la060091z

DO - 10.1021/la060091z

M3 - Article

SN - 1520-5827

VL - 22

SP - 4225

EP - 4229

JO - Langmuir

JF - Langmuir

IS - 9

ER -

Adsorption studies of a microporous phthalocyanine network polymer

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