Alkali metal templated assembly of an iron trigonal prism

Jeremy C Goodwin; Daniel J Price; Annie K Powell; Sarah L Heath

doi:10.1002/1099-0682(200007)2000:7<1407::AID-EJIC1407>3.0.CO;2-P

Alkali metal templated assembly of an iron trigonal prism

Jeremy C Goodwin, Daniel J Price, Annie K Powell, Sarah L Heath

Research output: Contribution to journal › Article › peer-review

Abstract

A novel hexanuclear Fe(III) complex [Fe6(Hpida)6(μ2-O)3Na][NO3]·18H2O (1; H3pida = N-(2-hydroxypropyl)iminodiacetic acid) was prepd. by reaction of equimolar amts. of N-(2-hydroxypropyl)iminodiacetic acid with iron(III) nitrate and was shown by x-ray crystallog. to possess a prismatic structure contg. a Na ion in the core. Magnetic studies showed 1 to have very strong antiferromagnetic character. [on SciFinder(R)]

Original language	English
Pages (from-to)	1407-1410
Number of pages	4
Journal	Eur. J. Inorg. Chem.
Issue number	7
DOIs	https://doi.org/10.1002/1099-0682(200007)2000:7<1407::AID-EJIC1407>3.0.CO;2-P
Publication status	Published - 2000

Keywords

crystal structure iron hydroxypropyliminodiacetate hexanuclear complex
iron hydroxypropyliminodiacetate hexanuclear complex structure prepn
antiferromagnetism iron hydroxypropyliminodiacetate hexanuclear complex
iminodiacetate hydroxypropyl iron hexanuclear complex structure prepn

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10.1002/1099-0682(200007)2000:7<1407::AID-EJIC1407>3.0.CO;2-P

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Cite this

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title = "Alkali metal templated assembly of an iron trigonal prism",

abstract = "A novel hexanuclear Fe(III) complex [Fe6(Hpida)6(μ2-O)3Na][NO3]·18H2O (1; H3pida = N-(2-hydroxypropyl)iminodiacetic acid) was prepd. by reaction of equimolar amts. of N-(2-hydroxypropyl)iminodiacetic acid with iron(III) nitrate and was shown by x-ray crystallog. to possess a prismatic structure contg. a Na ion in the core. Magnetic studies showed 1 to have very strong antiferromagnetic character. [on SciFinder(R)]",

keywords = "crystal structure iron hydroxypropyliminodiacetate hexanuclear complex, iron hydroxypropyliminodiacetate hexanuclear complex structure prepn, antiferromagnetism iron hydroxypropyliminodiacetate hexanuclear complex, iminodiacetate hydroxypropyl iron hexanuclear complex structure prepn",

author = "Goodwin, {Jeremy C} and Price, {Daniel J} and Powell, {Annie K} and Heath, {Sarah L}",

note = "CAPLUS AN 2000:491190(Journal)",

year = "2000",

doi = "10.1002/1099-0682(200007)2000:7<1407::AID-EJIC1407>3.0.CO;2-P",

language = "English",

pages = "1407--1410",

journal = "Eur. J. Inorg. Chem.",

issn = "1434-1948",

publisher = "John Wiley & Sons Ltd",

number = "7",

}

TY - JOUR

T1 - Alkali metal templated assembly of an iron trigonal prism

AU - Goodwin, Jeremy C

AU - Price, Daniel J

AU - Powell, Annie K

AU - Heath, Sarah L

N1 - CAPLUS AN 2000:491190(Journal)

PY - 2000

Y1 - 2000

N2 - A novel hexanuclear Fe(III) complex [Fe6(Hpida)6(μ2-O)3Na][NO3]·18H2O (1; H3pida = N-(2-hydroxypropyl)iminodiacetic acid) was prepd. by reaction of equimolar amts. of N-(2-hydroxypropyl)iminodiacetic acid with iron(III) nitrate and was shown by x-ray crystallog. to possess a prismatic structure contg. a Na ion in the core. Magnetic studies showed 1 to have very strong antiferromagnetic character. [on SciFinder(R)]

AB - A novel hexanuclear Fe(III) complex [Fe6(Hpida)6(μ2-O)3Na][NO3]·18H2O (1; H3pida = N-(2-hydroxypropyl)iminodiacetic acid) was prepd. by reaction of equimolar amts. of N-(2-hydroxypropyl)iminodiacetic acid with iron(III) nitrate and was shown by x-ray crystallog. to possess a prismatic structure contg. a Na ion in the core. Magnetic studies showed 1 to have very strong antiferromagnetic character. [on SciFinder(R)]

KW - crystal structure iron hydroxypropyliminodiacetate hexanuclear complex

KW - iron hydroxypropyliminodiacetate hexanuclear complex structure prepn

KW - antiferromagnetism iron hydroxypropyliminodiacetate hexanuclear complex

KW - iminodiacetate hydroxypropyl iron hexanuclear complex structure prepn

U2 - 10.1002/1099-0682(200007)2000:7<1407::AID-EJIC1407>3.0.CO;2-P

DO - 10.1002/1099-0682(200007)2000:7<1407::AID-EJIC1407>3.0.CO;2-P

M3 - Article

SN - 1434-1948

SP - 1407

EP - 1410

JO - Eur. J. Inorg. Chem.

JF - Eur. J. Inorg. Chem.

IS - 7

ER -

Alkali metal templated assembly of an iron trigonal prism

Abstract

Keywords

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