Alkali metal templated assembly of an iron trigonal prism

Jeremy C Goodwin, Daniel J Price, Annie K Powell, Sarah L Heath

    Research output: Contribution to journalArticlepeer-review


    A novel hexanuclear Fe(III) complex [Fe6(Hpida)6(μ2-O)3Na][NO3]·18H2O (1; H3pida = N-(2-hydroxypropyl)iminodiacetic acid) was prepd. by reaction of equimolar amts. of N-(2-hydroxypropyl)iminodiacetic acid with iron(III) nitrate and was shown by x-ray crystallog. to possess a prismatic structure contg. a Na ion in the core. Magnetic studies showed 1 to have very strong antiferromagnetic character. [on SciFinder(R)]
    Original languageEnglish
    Pages (from-to)1407-1410
    Number of pages4
    JournalEur. J. Inorg. Chem.
    Issue number7
    Publication statusPublished - 2000


    • crystal structure iron hydroxypropyliminodiacetate hexanuclear complex
    • iron hydroxypropyliminodiacetate hexanuclear complex structure prepn
    • antiferromagnetism iron hydroxypropyliminodiacetate hexanuclear complex
    • iminodiacetate hydroxypropyl iron hexanuclear complex structure prepn


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