Alkaline earth diazapentadienyl compounds: Structure of [Ba2{(C6H11)NC(Me)CHC(Me)-N(C6H11)}3{(SiMe3)2N}]

William Clegg, Simon J. Coles, Elaine K. Cope, Francis S. Mair

    Research output: Contribution to journalArticlepeer-review


    Three different bonding modes in one molecule! The diazapentadienyl ligands in the title compound 1 adopt η1,η1-N,N-chelating plus η5-terminal, η1η1-N,N chelating plus η5-bridging, and novel η1-N plus η3-1-aza-allyl bonding modes. R = cyclohexyl.
    Original languageEnglish
    Pages (from-to)796-798
    Number of pages2
    JournalAngewandte Chemie - International Edition
    Issue number6
    Publication statusPublished - 3 Apr 1998


    • Barium
    • Bridging ligands
    • Chemical vapor deposition
    • Coordination modes
    • N ligands


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