Alkaline earth diazapentadienyl compounds: Structure of [Ba2{(C6H11)NC(Me)CHC(Me)-N(C6H11)}3{(SiMe3)2N}]

William Clegg; Simon J. Coles; Elaine K. Cope; Francis S. Mair

doi:10.1002/(SICI)1521-3773(19980403)37:6<796::AID-ANIE796>3.0.CO;2-B

Alkaline earth diazapentadienyl compounds: Structure of [Ba2{(C6H11)NC(Me)CHC(Me)-N(C6H11)}3{(SiMe3)2N}]

William Clegg
, Simon J. Coles
, Elaine K. Cope
, Francis S. Mair

Research output: Contribution to journal › Article › peer-review

Abstract

Three different bonding modes in one molecule! The diazapentadienyl ligands in the title compound 1 adopt η1,η1-N,N-chelating plus η5-terminal, η1η1-N,N chelating plus η5-bridging, and novel η1-N plus η3-1-aza-allyl bonding modes. R = cyclohexyl.

Original language	English
Pages (from-to)	796-798
Number of pages	2
Journal	Angewandte Chemie - International Edition
Volume	37
Issue number	6
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19980403)37:6<796::AID-ANIE796>3.0.CO;2-B
Publication status	Published - 3 Apr 1998

Keywords

Barium
Bridging ligands
Chemical vapor deposition
Coordination modes
N ligands

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10.1002/(SICI)1521-3773(19980403)37:6<796::AID-ANIE796>3.0.CO;2-B

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title = "Alkaline earth diazapentadienyl compounds: Structure of [Ba2\{(C6H11)NC(Me)CHC(Me)-N(C6H11)\}3\{(SiMe3)2N\}]",

abstract = "Three different bonding modes in one molecule! The diazapentadienyl ligands in the title compound 1 adopt η1,η1-N,N-chelating plus η5-terminal, η1η1-N,N chelating plus η5-bridging, and novel η1-N plus η3-1-aza-allyl bonding modes. R = cyclohexyl.",

keywords = "Barium, Bridging ligands, Chemical vapor deposition, Coordination modes, N ligands",

author = "William Clegg and Coles, \{Simon J.\} and Cope, \{Elaine K.\} and Mair, \{Francis S.\}",

year = "1998",

month = apr,

day = "3",

doi = "10.1002/(SICI)1521-3773(19980403)37:6<796::AID-ANIE796>3.0.CO;2-B",

language = "English",

volume = "37",

pages = "796--798",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley \& Sons Ltd",

number = "6",

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TY - JOUR

T1 - Alkaline earth diazapentadienyl compounds: Structure of [Ba2{(C6H11)NC(Me)CHC(Me)-N(C6H11)}3{(SiMe3)2N}]

AU - Clegg, William

AU - Coles, Simon J.

AU - Cope, Elaine K.

AU - Mair, Francis S.

PY - 1998/4/3

Y1 - 1998/4/3

N2 - Three different bonding modes in one molecule! The diazapentadienyl ligands in the title compound 1 adopt η1,η1-N,N-chelating plus η5-terminal, η1η1-N,N chelating plus η5-bridging, and novel η1-N plus η3-1-aza-allyl bonding modes. R = cyclohexyl.

AB - Three different bonding modes in one molecule! The diazapentadienyl ligands in the title compound 1 adopt η1,η1-N,N-chelating plus η5-terminal, η1η1-N,N chelating plus η5-bridging, and novel η1-N plus η3-1-aza-allyl bonding modes. R = cyclohexyl.

KW - Barium

KW - Bridging ligands

KW - Chemical vapor deposition

KW - Coordination modes

KW - N ligands

U2 - 10.1002/(SICI)1521-3773(19980403)37:6<796::AID-ANIE796>3.0.CO;2-B

DO - 10.1002/(SICI)1521-3773(19980403)37:6<796::AID-ANIE796>3.0.CO;2-B

M3 - Article

SN - 1433-7851

VL - 37

SP - 796

EP - 798

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 6

ER -

Alkaline earth diazapentadienyl compounds: Structure of [Ba2{(C6H11)NC(Me)CHC(Me)-N(C6H11)}3{(SiMe3)2N}]

Abstract

Keywords

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