Amine-bis(phenolate) Iron(III)-Catalyzed Formal Hydroamination of Olefins

Kailong Zhu; Michael P. Shaver; Stephen Thomas

doi:10.1002/asia.201501098

Amine-bis(phenolate) Iron(III)-Catalyzed Formal Hydroamination of Olefins

Kailong Zhu, Michael P. Shaver^*, Stephen Thomas

^*Corresponding author for this work

University of Edinburgh

Research output: Contribution to journal › Article › peer-review

Abstract

A practical synthesis of highly functionalized amines by the formal hydroamination reaction of alkenes with nitroarenes catalyzed by an air stable amine-bis(phenolate) iron(III) complex is reported. The reaction uses an easily handled silane, low catalyst loadings, and mild reaction conditions. A wide range of substrates are transformed with synthetically useful yields (21 examples).

Original language	English
Pages (from-to)	977-980
Number of pages	4
Journal	Chemistry: An Asian Journal
Volume	11
Issue number	7
DOIs	https://doi.org/10.1002/asia.201501098
Publication status	Published - 5 Apr 2016

Keywords

amine-bis(phenolate)
hydroamination
iron
radicals
silanes

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10.1002/asia.201501098

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title = "Amine-bis(phenolate) Iron(III)-Catalyzed Formal Hydroamination of Olefins",

abstract = "A practical synthesis of highly functionalized amines by the formal hydroamination reaction of alkenes with nitroarenes catalyzed by an air stable amine-bis(phenolate) iron(III) complex is reported. The reaction uses an easily handled silane, low catalyst loadings, and mild reaction conditions. A wide range of substrates are transformed with synthetically useful yields (21 examples).",

keywords = "amine-bis(phenolate), hydroamination, iron, radicals, silanes",

author = "Kailong Zhu and Shaver, {Michael P.} and Stephen Thomas",

year = "2016",

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doi = "10.1002/asia.201501098",

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AU - Zhu, Kailong

AU - Shaver, Michael P.

AU - Thomas, Stephen

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Y1 - 2016/4/5

N2 - A practical synthesis of highly functionalized amines by the formal hydroamination reaction of alkenes with nitroarenes catalyzed by an air stable amine-bis(phenolate) iron(III) complex is reported. The reaction uses an easily handled silane, low catalyst loadings, and mild reaction conditions. A wide range of substrates are transformed with synthetically useful yields (21 examples).

AB - A practical synthesis of highly functionalized amines by the formal hydroamination reaction of alkenes with nitroarenes catalyzed by an air stable amine-bis(phenolate) iron(III) complex is reported. The reaction uses an easily handled silane, low catalyst loadings, and mild reaction conditions. A wide range of substrates are transformed with synthetically useful yields (21 examples).

KW - amine-bis(phenolate)

KW - hydroamination

KW - iron

KW - radicals

KW - silanes

U2 - 10.1002/asia.201501098

DO - 10.1002/asia.201501098

M3 - Article

C2 - 26864731

AN - SCOPUS:84977871252

SN - 1861-4728

VL - 11

SP - 977

EP - 980

JO - Chemistry: An Asian Journal

JF - Chemistry: An Asian Journal

IS - 7

ER -

Amine-bis(phenolate) Iron(III)-Catalyzed Formal Hydroamination of Olefins

Abstract

Keywords

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