Amine-bis(phenolate) Iron(III)-Catalyzed Formal Hydroamination of Olefins

Kailong Zhu, Michael P. Shaver, Stephen Thomas

    Research output: Contribution to journalArticlepeer-review

    Abstract

    A practical synthesis of highly functionalized amines by the formal hydroamination reaction of alkenes with nitroarenes catalyzed by an air stable amine-bis(phenolate) iron(III) complex is reported. The reaction uses an easily handled silane, low catalyst loadings, and mild reaction conditions. A wide range of substrates are transformed with synthetically useful yields (21 examples).

    Original languageEnglish
    Pages (from-to)977-980
    Number of pages4
    JournalChemistry: An Asian Journal
    Volume11
    Issue number7
    DOIs
    Publication statusPublished - 5 Apr 2016

    Keywords

    • amine-bis(phenolate)
    • hydroamination
    • iron
    • radicals
    • silanes

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