Aminoarylation of Alkynes using Diarylanilines

Michael Greaney; Zi Liu

doi:10.1039/D4CC01935K

Aminoarylation of Alkynes using Diarylanilines

Michael Greaney, Zi Liu

Organic Chemistry Group

Research output: Contribution to journal › Article › peer-review

Abstract

Intermolecular aminoarylation of alkynes is described, via addition of diarylanilines to alkynes and Smiles-Truce rearrangement. The transformation manipulates the C-N bond of anilines directly, with no requirement for organometallic reagents or transition metal catalysis. The enaminoate products are versatile building blocks for different classes of heterocycles.

Original language	English
Journal	Chemical Communications
Early online date	22 May 2024
DOIs	https://doi.org/10.1039/D4CC01935K
Publication status	E-pub ahead of print - 22 May 2024

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10.1039/D4CC01935KLicence: CC BY

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title = "Aminoarylation of Alkynes using Diarylanilines",

abstract = "Intermolecular aminoarylation of alkynes is described, via addition of diarylanilines to alkynes and Smiles-Truce rearrangement. The transformation manipulates the C-N bond of anilines directly, with no requirement for organometallic reagents or transition metal catalysis. The enaminoate products are versatile building blocks for different classes of heterocycles.",

author = "Michael Greaney and Zi Liu",

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month = may,

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doi = "10.1039/D4CC01935K",

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AU - Liu, Zi

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N2 - Intermolecular aminoarylation of alkynes is described, via addition of diarylanilines to alkynes and Smiles-Truce rearrangement. The transformation manipulates the C-N bond of anilines directly, with no requirement for organometallic reagents or transition metal catalysis. The enaminoate products are versatile building blocks for different classes of heterocycles.

AB - Intermolecular aminoarylation of alkynes is described, via addition of diarylanilines to alkynes and Smiles-Truce rearrangement. The transformation manipulates the C-N bond of anilines directly, with no requirement for organometallic reagents or transition metal catalysis. The enaminoate products are versatile building blocks for different classes of heterocycles.

U2 - 10.1039/D4CC01935K

DO - 10.1039/D4CC01935K

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Aminoarylation of Alkynes using Diarylanilines

Abstract

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