An Actinide Zintl Cluster: A Tris(triamidouranium)μ3-η2:η2:η2-Heptaphosphanortricyclane and Its Diverse Synthetic Utility

Dipti Patel; Floriana Tuna; Eric J L McInnes; William Lewis; Alexander J. Blake; Stephen T. Liddle

doi:10.1002/anie.201306492

An Actinide Zintl Cluster: A Tris(triamidouranium)μ3-η2:η2:η2-Heptaphosphanortricyclane and Its Diverse Synthetic Utility

Dipti Patel, Floriana Tuna, Eric J L McInnes, William Lewis, Alexander J. Blake, Stephen T. Liddle

The University of Manchester

Research output: Contribution to journal › Article › peer-review

Abstract

A diuranium(V) arene complex reductively cleaves P4 to give a triuranium heptaphosphanortricyclane cluster (see picture; Ugreen, Ppurple, Nblue, Siorange). This cluster is the first example of a molecular actinide [P7] Zintl complex and the first example of uranium-promoted catenation of P4. This complex undergoes a wide range of reactions under mild conditions to afford liberated P7R3 phosphanortricyclanes. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	13334-13337
Number of pages	3
Journal	Angewandte Chemie (International Edition)
Volume	52
Issue number	50
DOIs	https://doi.org/10.1002/anie.201306492
Publication status	Published - 9 Dec 2013

Keywords

actinides
reduction
uranium
white phosphorus
Zintl phases

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10.1002/anie.201306492

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CCDC 952235: Experimental Crystal Structure Determination
Patel, D. (Contributor), Tuna, F. (Contributor), Mcinnes, E. (Contributor), Lewis, W. (Contributor), Blake, A. J. (Contributor) & Liddle, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cc10yw83, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10yw83&sid=DataCite
Dataset

Cite this

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title = "An Actinide Zintl Cluster: A Tris(triamidouranium)μ3-η2:η2:η2-Heptaphosphanortricyclane and Its Diverse Synthetic Utility",

abstract = "A diuranium(V) arene complex reductively cleaves P4 to give a triuranium heptaphosphanortricyclane cluster (see picture; Ugreen, Ppurple, Nblue, Siorange). This cluster is the first example of a molecular actinide [P7] Zintl complex and the first example of uranium-promoted catenation of P4. This complex undergoes a wide range of reactions under mild conditions to afford liberated P7R3 phosphanortricyclanes. {\textcopyright} 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

keywords = "actinides, reduction, uranium, white phosphorus, Zintl phases",

author = "Dipti Patel and Floriana Tuna and McInnes, {Eric J L} and William Lewis and Blake, {Alexander J.} and Liddle, {Stephen T.}",

note = "Times Cited: 2",

year = "2013",

month = dec,

day = "9",

doi = "10.1002/anie.201306492",

language = "English",

volume = "52",

pages = "13334--13337",

journal = "Angewandte Chemie (International Edition)",

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publisher = "John Wiley & Sons Ltd",

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TY - JOUR

T1 - An Actinide Zintl Cluster: A Tris(triamidouranium)μ3-η2:η2:η2-Heptaphosphanortricyclane and Its Diverse Synthetic Utility

AU - Patel, Dipti

AU - Tuna, Floriana

AU - McInnes, Eric J L

AU - Lewis, William

AU - Blake, Alexander J.

AU - Liddle, Stephen T.

N1 - Times Cited: 2

PY - 2013/12/9

Y1 - 2013/12/9

N2 - A diuranium(V) arene complex reductively cleaves P4 to give a triuranium heptaphosphanortricyclane cluster (see picture; Ugreen, Ppurple, Nblue, Siorange). This cluster is the first example of a molecular actinide [P7] Zintl complex and the first example of uranium-promoted catenation of P4. This complex undergoes a wide range of reactions under mild conditions to afford liberated P7R3 phosphanortricyclanes. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - A diuranium(V) arene complex reductively cleaves P4 to give a triuranium heptaphosphanortricyclane cluster (see picture; Ugreen, Ppurple, Nblue, Siorange). This cluster is the first example of a molecular actinide [P7] Zintl complex and the first example of uranium-promoted catenation of P4. This complex undergoes a wide range of reactions under mild conditions to afford liberated P7R3 phosphanortricyclanes. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - actinides

KW - reduction

KW - uranium

KW - white phosphorus

KW - Zintl phases

U2 - 10.1002/anie.201306492

DO - 10.1002/anie.201306492

M3 - Article

SN - 1433-7851

VL - 52

SP - 13334

EP - 13337

JO - Angewandte Chemie (International Edition)

JF - Angewandte Chemie (International Edition)

IS - 50

ER -

An Actinide Zintl Cluster: A Tris(triamidouranium)μ3-η2:η2:η2-Heptaphosphanortricyclane and Its Diverse Synthetic Utility

Abstract

Keywords

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Datasets

CCDC 952235: Experimental Crystal Structure Determination

Cite this