An aerosol chamber investigation of the heterogeneous ice nucleating potential of refractory nanoparticles

R. W. Saunders, O. Möhler, M. Schnaiter, S. Benz, R. Wagner, H. Saathoff, P. J. Connolly, R. Burgess, B. J. Murray, M. Gallagher, R. Wills, J. M C Plane

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Nanoparticles of iron oxide (crystalline and amorphous), silicon oxide and magnesium oxide were investigated for their propensity to nucleate ice over the temperature range 180-250 K, using the AIDA chamber in Karlsruhe, Germany. All samples were observed to initiate ice formation via the deposition mode at threshold ice super-saturations (RHithresh) ranging from 105% to 140% for temperatures below 220 K. Approximately 10% of amorphous Fe 2O3 particles (modal diameter Combining double low line 30 nm) generated in situ from a photochemical aerosol reactor, led to ice nucleation at RHithresh Combining double low line 140% at an initial chamber temperature of 182 K. Quantitative analysis using a singular hypothesis treatment provided a fitted function [ns(190 K)Combining double low line10(3.33×sice)+8.16] for the variation in ice-active surface site density (ns:m-2) with ice saturation (sice) for Fe2O3 nanoparticles. This was implemented in an aerosol-cloud model to determine a predicted deposition (mass accommodation) coefficient for water vapour on ice of 0.1 at temperatures appropriate for the upper atmosphere. Classical nucleation theory was used to determine representative contact angles (θ) for the different particle compositions. For the in situ generated Fe2O3 particles, a slight inverse temperature dependence was observed with θ Combining double low line 10.5° at 182 K, decreasing to 9.0° at 200 K (compared with 10.2° and 11.4° respectively for the SiO 2 and MgO particle samples at the higher temperature). These observations indicate that such refractory nanoparticles are relatively efficient materials for the nucleation of ice under the conditions studied in the chamber which correspond to cirrus cloud formation in the upper troposphere. The results also show that Fe2O3 particles do not act as ice nuclei under conditions pertinent for tropospheric mixed phase clouds, which necessarily form above ∼233 K. At the lower temperatures (
    Original languageEnglish
    Pages (from-to)1227-1247
    Number of pages21
    JournalAtmospheric Chemistry and Physics
    Volume10
    Issue number3
    DOIs
    Publication statusPublished - 4 Feb 2010

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