An antiferromagnetically coupled dimeric Ni(II) complex anion and its counter cationic monomeric Ni(II) complex, and some other mononuclear transition metal compounds using some neutral ligands

Bhaskar Biswas; Abhijit Pal; G. Rama Krishna; C. Malla Reddy; Floriana Tuna; Rajarshi Ghosh

doi:10.1016/j.poly.2011.05.007

An antiferromagnetically coupled dimeric Ni(II) complex anion and its counter cationic monomeric Ni(II) complex, and some other mononuclear transition metal compounds using some neutral ligands

Bhaskar Biswas, Abhijit Pal, G. Rama Krishna, C. Malla Reddy, Floriana Tuna, Rajarshi Ghosh

Research output: Contribution to journal › Article › peer-review

Abstract

Synthesis and single crystal X-ray diffraction studies of four transition metal complexes [Mn(L1)](ClO4)2 (1), [Cu(L 1)](ClO4)2 (2), [Ni2(L 2)(NCS)6][Ni(L1)] (3) and [Mn(bzpy)(NCS) 2] (4) with neutral ligands [L1 = N-(1-pyridin- 2-yl-phenylidene)-N′-[2-({2-[(1-pyridin-2-yl phenylidene)amino]ethyl} amino)ethyl]ethane-1,2diamine, L2 = N-(1-pyridin-2-yl-phenylidene)- N′-[2-({2-[(1-pyridin-2-ylphenylidene)amino]ethyl}piperazine-1yl)ethyl] amine, bzpy = 2-benzoylpyridine] are reported. The trinuclear nickel(II) complex 3 is made of a dinuclear anion and a mononuclear cation. Variable-temperature magnetic susceptibility and variable-field magnetisation studies performed on 3 suggest weak antiferromagnetic coupling (J = -0.7 cm-1) between the twometals of the dinuclear entity, but no magnetic interaction between the anionic and cationic counterparts. © 2011 Elsevier Ltd.

Original language	English
Pages (from-to)	2032-2037
Number of pages	5
Journal	Polyhedron
Volume	30
Issue number	12
DOIs	https://doi.org/10.1016/j.poly.2011.05.007
Publication status	Published - 2 Aug 2011

Keywords

Magnetism
Schiff bases
Transition metal ions
X-ray structure

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10.1016/j.poly.2011.05.007

CCDC 808347: Experimental Crystal Structure Determination
Biswas, B. (Contributor), Pal, A. (Contributor), Krishna, G. R. (Contributor), Reddy, C. M. (Contributor), Tuna, F. (Contributor) & Ghosh, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccw44qv, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw44qv&sid=DataCite
Dataset
CCDC 808345: Experimental Crystal Structure Determination
Biswas, B. (Contributor), Pal, A. (Contributor), Krishna, G. R. (Contributor), Reddy, C. M. (Contributor), Tuna, F. (Contributor) & Ghosh, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccw44ns, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw44ns&sid=DataCite
Dataset
CCDC 808346: Experimental Crystal Structure Determination
Biswas, B. (Contributor), Pal, A. (Contributor), Krishna, G. R. (Contributor), Reddy, C. M. (Contributor), Tuna, F. (Contributor) & Ghosh, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccw44pt, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw44pt&sid=DataCite
Dataset

Cite this

@article{a8fa8e0649f24ad3b317f4bde23a8d17,

title = "An antiferromagnetically coupled dimeric Ni(II) complex anion and its counter cationic monomeric Ni(II) complex, and some other mononuclear transition metal compounds using some neutral ligands",

abstract = "Synthesis and single crystal X-ray diffraction studies of four transition metal complexes [Mn(L1)](ClO4)2 (1), [Cu(L 1)](ClO4)2 (2), [Ni2(L 2)(NCS)6][Ni(L1)] (3) and [Mn(bzpy)(NCS) 2] (4) with neutral ligands [L1 = N-(1-pyridin- 2-yl-phenylidene)-N′-[2-({2-[(1-pyridin-2-yl phenylidene)amino]ethyl} amino)ethyl]ethane-1,2diamine, L2 = N-(1-pyridin-2-yl-phenylidene)- N′-[2-({2-[(1-pyridin-2-ylphenylidene)amino]ethyl}piperazine-1yl)ethyl] amine, bzpy = 2-benzoylpyridine] are reported. The trinuclear nickel(II) complex 3 is made of a dinuclear anion and a mononuclear cation. Variable-temperature magnetic susceptibility and variable-field magnetisation studies performed on 3 suggest weak antiferromagnetic coupling (J = -0.7 cm-1) between the twometals of the dinuclear entity, but no magnetic interaction between the anionic and cationic counterparts. {\textcopyright} 2011 Elsevier Ltd.",

keywords = "Magnetism, Schiff bases, Transition metal ions, X-ray structure",

author = "Bhaskar Biswas and Abhijit Pal and Krishna, {G. Rama} and Reddy, {C. Malla} and Floriana Tuna and Rajarshi Ghosh",

year = "2011",

month = aug,

day = "2",

doi = "10.1016/j.poly.2011.05.007",

language = "English",

volume = "30",

pages = "2032--2037",

journal = "Polyhedron",

publisher = "Elsevier BV",

number = "12",

}

An antiferromagnetically coupled dimeric Ni(II) complex anion and its counter cationic monomeric Ni(II) complex, and some other mononuclear transition metal compounds using some neutral ligands. / Biswas, Bhaskar; Pal, Abhijit; Krishna, G. Rama et al.
In: Polyhedron, Vol. 30, No. 12, 02.08.2011, p. 2032-2037.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - An antiferromagnetically coupled dimeric Ni(II) complex anion and its counter cationic monomeric Ni(II) complex, and some other mononuclear transition metal compounds using some neutral ligands

AU - Biswas, Bhaskar

AU - Pal, Abhijit

AU - Krishna, G. Rama

AU - Reddy, C. Malla

AU - Tuna, Floriana

AU - Ghosh, Rajarshi

PY - 2011/8/2

Y1 - 2011/8/2

N2 - Synthesis and single crystal X-ray diffraction studies of four transition metal complexes [Mn(L1)](ClO4)2 (1), [Cu(L 1)](ClO4)2 (2), [Ni2(L 2)(NCS)6][Ni(L1)] (3) and [Mn(bzpy)(NCS) 2] (4) with neutral ligands [L1 = N-(1-pyridin- 2-yl-phenylidene)-N′-[2-({2-[(1-pyridin-2-yl phenylidene)amino]ethyl} amino)ethyl]ethane-1,2diamine, L2 = N-(1-pyridin-2-yl-phenylidene)- N′-[2-({2-[(1-pyridin-2-ylphenylidene)amino]ethyl}piperazine-1yl)ethyl] amine, bzpy = 2-benzoylpyridine] are reported. The trinuclear nickel(II) complex 3 is made of a dinuclear anion and a mononuclear cation. Variable-temperature magnetic susceptibility and variable-field magnetisation studies performed on 3 suggest weak antiferromagnetic coupling (J = -0.7 cm-1) between the twometals of the dinuclear entity, but no magnetic interaction between the anionic and cationic counterparts. © 2011 Elsevier Ltd.

AB - Synthesis and single crystal X-ray diffraction studies of four transition metal complexes [Mn(L1)](ClO4)2 (1), [Cu(L 1)](ClO4)2 (2), [Ni2(L 2)(NCS)6][Ni(L1)] (3) and [Mn(bzpy)(NCS) 2] (4) with neutral ligands [L1 = N-(1-pyridin- 2-yl-phenylidene)-N′-[2-({2-[(1-pyridin-2-yl phenylidene)amino]ethyl} amino)ethyl]ethane-1,2diamine, L2 = N-(1-pyridin-2-yl-phenylidene)- N′-[2-({2-[(1-pyridin-2-ylphenylidene)amino]ethyl}piperazine-1yl)ethyl] amine, bzpy = 2-benzoylpyridine] are reported. The trinuclear nickel(II) complex 3 is made of a dinuclear anion and a mononuclear cation. Variable-temperature magnetic susceptibility and variable-field magnetisation studies performed on 3 suggest weak antiferromagnetic coupling (J = -0.7 cm-1) between the twometals of the dinuclear entity, but no magnetic interaction between the anionic and cationic counterparts. © 2011 Elsevier Ltd.

KW - Magnetism

KW - Schiff bases

KW - Transition metal ions

KW - X-ray structure

U2 - 10.1016/j.poly.2011.05.007

DO - 10.1016/j.poly.2011.05.007

M3 - Article

VL - 30

SP - 2032

EP - 2037

JO - Polyhedron

JF - Polyhedron

IS - 12

ER -

An antiferromagnetically coupled dimeric Ni(II) complex anion and its counter cationic monomeric Ni(II) complex, and some other mononuclear transition metal compounds using some neutral ligands

Abstract

Keywords

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Datasets

CCDC 808347: Experimental Crystal Structure Determination

CCDC 808345: Experimental Crystal Structure Determination

CCDC 808346: Experimental Crystal Structure Determination

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