A linear cation-decorated polymeric support with tuneable surface properties and microstructure has been prepared by ring-opening metathesis polymerisation (ROMP) of a pyrrolidinium-functionalised norbornene-based monomer with cyclooctene. The derived peroxophosphotungstate-based polymer-immobilised ionic liquid phase (PIILP) catalyst is an efficient and recyclable system for the epoxidation of allylic alcohols and alkenes, with only a minor reduction in performance on successive cycles.
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Doherty, S. (Contributor), Knight, J. G. (Contributor), Ellison, J. R. (Contributor), Weekes, D. (Contributor), Harrington, R. W. (Contributor), Hardacre, C. (Contributor) & Manyar, H. G. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012