Abstract
A nanoscopic {Fe60} coordination cage (approximately 3 nm) was prepared by the self assembly of a partially blocked tricyanidoferrate(III) complex and tris(alkoxo)-based iron(III) coordination motifs. This cage is a rare example of a mixed cyanido/alkoxo-bridged high nuclearity complex and it exemplifies the great potential of this new synthetic route to generate uncommon molecular architectures using cyanometallates as metalloligands versus alkoxo-based polynuclear entities.
Original language | English |
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Pages (from-to) | 17610-17615 |
Journal | Dalton Transactions |
Volume | 45 |
Issue number | 44 |
Early online date | 11 Aug 2016 |
DOIs | |
Publication status | Published - 28 Nov 2016 |
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CCDC 1409712: Experimental Crystal Structure Determination
Jiménez, J.-R. (Creator), Mondal, A. (Creator), Chamoreau, L.-M. (Creator), Fertey, P. (Creator), Tuna, F. (Creator), Julve, M. (Creator), Bousseksou, A. (Creator), Lescouëzec, R. (Creator) & Lisnard, L. (Creator), Cambridge Crystallographic Data Centre, 10 Feb 2016
DOI: 10.5517/ccdc.csd.cc1j9xlb
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