Analysis of fountain solutions for anionic components, including alkylbenzenesulfonates, carboxylates and polyphosphates, by a combination of ion-exchange and ion-exclusion chromatography and inductively coupled plasma atomic emission spectrometry

A. D. Bewsher; D. A. Polya; P. R. Lythgoe; I. M. Bruckshaw; D. A C Manning

doi:10.1016/S0021-9673(01)00553-2

Analysis of fountain solutions for anionic components, including alkylbenzenesulfonates, carboxylates and polyphosphates, by a combination of ion-exchange and ion-exclusion chromatography and inductively coupled plasma atomic emission spectrometry

A. D. Bewsher, D. A. Polya, P. R. Lythgoe, I. M. Bruckshaw, D. A C Manning

Research output: Contribution to journal › Article › peer-review

Abstract

A method for the quantitative determination of the major anionic constituents of fountain solutions, typically mono-, di- and hydroxycarboxylates, alkylbenzenesulfonates, and inorganic anions, including orthophosphate and polyphosphates, is presented here for the first time. The analytical problems arising from extensive co-elution of many of these analytes on an ion-exchange column have been resolved through a combination of (i) careful selection of the concentration gradient of the sodium hydroxide eluent; (ii) parallel analysis by ion-exclusion chromatography; and (iii) determination of total phosphorus by inductively coupled plasma atomic emission spectrometry. © 2001 Elsevier Science B.V.

Original language	English
Pages (from-to)	247-253
Number of pages	6
Journal	Journal of Chromatography A
Volume	920
Issue number	1-2
DOIs	https://doi.org/10.1016/S0021-9673(01)00553-2
Publication status	Published - 27 Jun 2001

Keywords

Alkylbenzenesulfonates
Carboxylic acids
Fountain solutions
Inorganic anions
Organosulfur compounds
Polyphosphates

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10.1016/S0021-9673(01)00553-2

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Bewsher, A. D., Polya, D. A., Lythgoe, P. R., Bruckshaw, I. M., & Manning, D. A. C. (2001). Analysis of fountain solutions for anionic components, including alkylbenzenesulfonates, carboxylates and polyphosphates, by a combination of ion-exchange and ion-exclusion chromatography and inductively coupled plasma atomic emission spectrometry. Journal of Chromatography A, 920(1-2), 247-253. https://doi.org/10.1016/S0021-9673(01)00553-2

Bewsher, A. D. ; Polya, D. A. ; Lythgoe, P. R. et al. / Analysis of fountain solutions for anionic components, including alkylbenzenesulfonates, carboxylates and polyphosphates, by a combination of ion-exchange and ion-exclusion chromatography and inductively coupled plasma atomic emission spectrometry. In: Journal of Chromatography A. 2001 ; Vol. 920, No. 1-2. pp. 247-253.

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title = "Analysis of fountain solutions for anionic components, including alkylbenzenesulfonates, carboxylates and polyphosphates, by a combination of ion-exchange and ion-exclusion chromatography and inductively coupled plasma atomic emission spectrometry",

abstract = "A method for the quantitative determination of the major anionic constituents of fountain solutions, typically mono-, di- and hydroxycarboxylates, alkylbenzenesulfonates, and inorganic anions, including orthophosphate and polyphosphates, is presented here for the first time. The analytical problems arising from extensive co-elution of many of these analytes on an ion-exchange column have been resolved through a combination of (i) careful selection of the concentration gradient of the sodium hydroxide eluent; (ii) parallel analysis by ion-exclusion chromatography; and (iii) determination of total phosphorus by inductively coupled plasma atomic emission spectrometry. {\textcopyright} 2001 Elsevier Science B.V.",

keywords = "Alkylbenzenesulfonates, Carboxylic acids, Fountain solutions, Inorganic anions, Organosulfur compounds, Polyphosphates",

author = "Bewsher, {A. D.} and Polya, {D. A.} and Lythgoe, {P. R.} and Bruckshaw, {I. M.} and Manning, {D. A C}",

year = "2001",

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doi = "10.1016/S0021-9673(01)00553-2",

language = "English",

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Bewsher, AD, Polya, DA, Lythgoe, PR, Bruckshaw, IM & Manning, DAC 2001, 'Analysis of fountain solutions for anionic components, including alkylbenzenesulfonates, carboxylates and polyphosphates, by a combination of ion-exchange and ion-exclusion chromatography and inductively coupled plasma atomic emission spectrometry', Journal of Chromatography A, vol. 920, no. 1-2, pp. 247-253. https://doi.org/10.1016/S0021-9673(01)00553-2

Analysis of fountain solutions for anionic components, including alkylbenzenesulfonates, carboxylates and polyphosphates, by a combination of ion-exchange and ion-exclusion chromatography and inductively coupled plasma atomic emission spectrometry. / Bewsher, A. D.; Polya, D. A.; Lythgoe, P. R. et al.
In: Journal of Chromatography A, Vol. 920, No. 1-2, 27.06.2001, p. 247-253.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Analysis of fountain solutions for anionic components, including alkylbenzenesulfonates, carboxylates and polyphosphates, by a combination of ion-exchange and ion-exclusion chromatography and inductively coupled plasma atomic emission spectrometry

AU - Bewsher, A. D.

AU - Polya, D. A.

AU - Lythgoe, P. R.

AU - Bruckshaw, I. M.

AU - Manning, D. A C

PY - 2001/6/27

Y1 - 2001/6/27

N2 - A method for the quantitative determination of the major anionic constituents of fountain solutions, typically mono-, di- and hydroxycarboxylates, alkylbenzenesulfonates, and inorganic anions, including orthophosphate and polyphosphates, is presented here for the first time. The analytical problems arising from extensive co-elution of many of these analytes on an ion-exchange column have been resolved through a combination of (i) careful selection of the concentration gradient of the sodium hydroxide eluent; (ii) parallel analysis by ion-exclusion chromatography; and (iii) determination of total phosphorus by inductively coupled plasma atomic emission spectrometry. © 2001 Elsevier Science B.V.

AB - A method for the quantitative determination of the major anionic constituents of fountain solutions, typically mono-, di- and hydroxycarboxylates, alkylbenzenesulfonates, and inorganic anions, including orthophosphate and polyphosphates, is presented here for the first time. The analytical problems arising from extensive co-elution of many of these analytes on an ion-exchange column have been resolved through a combination of (i) careful selection of the concentration gradient of the sodium hydroxide eluent; (ii) parallel analysis by ion-exclusion chromatography; and (iii) determination of total phosphorus by inductively coupled plasma atomic emission spectrometry. © 2001 Elsevier Science B.V.

KW - Alkylbenzenesulfonates

KW - Carboxylic acids

KW - Fountain solutions

KW - Inorganic anions

KW - Organosulfur compounds

KW - Polyphosphates

U2 - 10.1016/S0021-9673(01)00553-2

DO - 10.1016/S0021-9673(01)00553-2

M3 - Article

SN - 1873-3778

VL - 920

SP - 247

EP - 253

JO - Journal of Chromatography A

JF - Journal of Chromatography A

IS - 1-2

ER -

Bewsher AD, Polya DA, Lythgoe PR, Bruckshaw IM, Manning DAC. Analysis of fountain solutions for anionic components, including alkylbenzenesulfonates, carboxylates and polyphosphates, by a combination of ion-exchange and ion-exclusion chromatography and inductively coupled plasma atomic emission spectrometry. Journal of Chromatography A. 2001 Jun 27;920(1-2):247-253. doi: 10.1016/S0021-9673(01)00553-2