Anion complexation, transport and structural studies of a series of bis-methylurea compounds.

Martina Olivari; Riccardo Montis; Louise E. Karagiannidis; Peter N. Horton; Lucy K. Mapp; Simon J. Coles; Mark E. Light; Philip A. Gale; Claudia Caltagirone

doi:10.1039/c4dt02893g

Anion complexation, transport and structural studies of a series of bis-methylurea compounds.

Martina Olivari, Riccardo Montis, Louise E. Karagiannidis, Peter N. Horton, Lucy K. Mapp, Simon J. Coles, Mark E. Light, Philip A. Gale^*, Claudia Caltagirone

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A new family of bis-methylureas (L¹-L⁶) have been synthesised and their ability to bind anions both in solution and in the solid state and to transport them through lipid membrane have been studied. From the solid state studies it has emerged that various conformations can be adopted by the receptors allowing the isolation of complexes of different stoichiometries (from 1:1 to 1:3). The transport studies highlighted the possibility to use bis-methylureas to mediate Cl^- transport across membranes.

Original language	English
Pages (from-to)	2138-2149
Number of pages	12
Journal	Dalton Transactions
Volume	44
Issue number	5
DOIs	https://doi.org/10.1039/c4dt02893g
Publication status	Published - 7 Feb 2015

Access to Document

10.1039/c4dt02893g

Cite this

@article{bca62a43b1fd42b5923b2d86d0fcde00,

title = "Anion complexation, transport and structural studies of a series of bis-methylurea compounds.",

abstract = "A new family of bis-methylureas (L1-L6) have been synthesised and their ability to bind anions both in solution and in the solid state and to transport them through lipid membrane have been studied. From the solid state studies it has emerged that various conformations can be adopted by the receptors allowing the isolation of complexes of different stoichiometries (from 1:1 to 1:3). The transport studies highlighted the possibility to use bis-methylureas to mediate Cl- transport across membranes.",

author = "Martina Olivari and Riccardo Montis and Karagiannidis, {Louise E.} and Horton, {Peter N.} and Mapp, {Lucy K.} and Coles, {Simon J.} and Light, {Mark E.} and Gale, {Philip A.} and Claudia Caltagirone",

year = "2015",

month = feb,

day = "7",

doi = "10.1039/c4dt02893g",

language = "English",

volume = "44",

pages = "2138--2149",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Anion complexation, transport and structural studies of a series of bis-methylurea compounds.

AU - Olivari, Martina

AU - Montis, Riccardo

AU - Karagiannidis, Louise E.

AU - Horton, Peter N.

AU - Mapp, Lucy K.

AU - Coles, Simon J.

AU - Light, Mark E.

AU - Gale, Philip A.

AU - Caltagirone, Claudia

PY - 2015/2/7

Y1 - 2015/2/7

N2 - A new family of bis-methylureas (L1-L6) have been synthesised and their ability to bind anions both in solution and in the solid state and to transport them through lipid membrane have been studied. From the solid state studies it has emerged that various conformations can be adopted by the receptors allowing the isolation of complexes of different stoichiometries (from 1:1 to 1:3). The transport studies highlighted the possibility to use bis-methylureas to mediate Cl- transport across membranes.

AB - A new family of bis-methylureas (L1-L6) have been synthesised and their ability to bind anions both in solution and in the solid state and to transport them through lipid membrane have been studied. From the solid state studies it has emerged that various conformations can be adopted by the receptors allowing the isolation of complexes of different stoichiometries (from 1:1 to 1:3). The transport studies highlighted the possibility to use bis-methylureas to mediate Cl- transport across membranes.

UR - http://www.scopus.com/inward/record.url?scp=84921646049&partnerID=8YFLogxK

U2 - 10.1039/c4dt02893g

DO - 10.1039/c4dt02893g

M3 - Article

AN - SCOPUS:84921646049

SN - 1477-9226

VL - 44

SP - 2138

EP - 2149

JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

Anion complexation, transport and structural studies of a series of bis-methylurea compounds.

Abstract

Access to Document

Other files and links

Fingerprint

Cite this