Anion control in the lonothermal synthesis of coordination polymers

Zhuojia Lin; David S. Wragg; John E. Warren; Russell E. Morris

doi:10.1021/ja0737671

Anion control in the lonothermal synthesis of coordination polymers

Zhuojia Lin, David S. Wragg, John E. Warren, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

Abstract

Two anionic 3D coordination frameworks (EMIm)2[Co3(TMA)2(OAc)2] 1 and (EMIm)[Co(TMA)] 2, one condensed hydroxide network [Co5(OH)2(OAc)8](H2O)x 3, and one 2D layer compound (EMIm)[Co2(TMA)4H7(22bpy)2] 4 were prepared from three relevant ionic liquids of 1-ethyl 3-methyl imidazolium bromide (EMIm-Br), EMIm bistriflamide (EMIm-Tf2N), and mixtures of the two. The use of anions in ionic liquids plays a significant role in solvent polarity/hydrophibicity, which in turn controls the structures of materials formed in the ionothermal synthesis. The use of mixed anion ionic liquids opens up many possibilities to further tailor the properties of ionic liquids for ionothermal synthesis applications. The ionic liquid anions are not incorporated into the resultant materials. Copyright © 2007 American Chemical Society.

Original language	English
Pages (from-to)	10334-10335
Number of pages	1
Journal	Journal of the American Chemical Society
Volume	129
Issue number	34
DOIs	https://doi.org/10.1021/ja0737671
Publication status	Published - 29 Aug 2007

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10.1021/ja0737671

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@article{818b32b23bca45988c631294cf14b19b,

title = "Anion control in the lonothermal synthesis of coordination polymers",

abstract = "Two anionic 3D coordination frameworks (EMIm)2[Co3(TMA)2(OAc)2] 1 and (EMIm)[Co(TMA)] 2, one condensed hydroxide network [Co5(OH)2(OAc)8](H2O)x 3, and one 2D layer compound (EMIm)[Co2(TMA)4H7(22bpy)2] 4 were prepared from three relevant ionic liquids of 1-ethyl 3-methyl imidazolium bromide (EMIm-Br), EMIm bistriflamide (EMIm-Tf2N), and mixtures of the two. The use of anions in ionic liquids plays a significant role in solvent polarity/hydrophibicity, which in turn controls the structures of materials formed in the ionothermal synthesis. The use of mixed anion ionic liquids opens up many possibilities to further tailor the properties of ionic liquids for ionothermal synthesis applications. The ionic liquid anions are not incorporated into the resultant materials. Copyright {\textcopyright} 2007 American Chemical Society.",

author = "Zhuojia Lin and Wragg, \{David S.\} and Warren, \{John E.\} and Morris, \{Russell E.\}",

note = "34",

year = "2007",

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doi = "10.1021/ja0737671",

language = "English",

volume = "129",

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T1 - Anion control in the lonothermal synthesis of coordination polymers

AU - Lin, Zhuojia

AU - Wragg, David S.

AU - Warren, John E.

AU - Morris, Russell E.

N1 - 34

PY - 2007/8/29

Y1 - 2007/8/29

N2 - Two anionic 3D coordination frameworks (EMIm)2[Co3(TMA)2(OAc)2] 1 and (EMIm)[Co(TMA)] 2, one condensed hydroxide network [Co5(OH)2(OAc)8](H2O)x 3, and one 2D layer compound (EMIm)[Co2(TMA)4H7(22bpy)2] 4 were prepared from three relevant ionic liquids of 1-ethyl 3-methyl imidazolium bromide (EMIm-Br), EMIm bistriflamide (EMIm-Tf2N), and mixtures of the two. The use of anions in ionic liquids plays a significant role in solvent polarity/hydrophibicity, which in turn controls the structures of materials formed in the ionothermal synthesis. The use of mixed anion ionic liquids opens up many possibilities to further tailor the properties of ionic liquids for ionothermal synthesis applications. The ionic liquid anions are not incorporated into the resultant materials. Copyright © 2007 American Chemical Society.

AB - Two anionic 3D coordination frameworks (EMIm)2[Co3(TMA)2(OAc)2] 1 and (EMIm)[Co(TMA)] 2, one condensed hydroxide network [Co5(OH)2(OAc)8](H2O)x 3, and one 2D layer compound (EMIm)[Co2(TMA)4H7(22bpy)2] 4 were prepared from three relevant ionic liquids of 1-ethyl 3-methyl imidazolium bromide (EMIm-Br), EMIm bistriflamide (EMIm-Tf2N), and mixtures of the two. The use of anions in ionic liquids plays a significant role in solvent polarity/hydrophibicity, which in turn controls the structures of materials formed in the ionothermal synthesis. The use of mixed anion ionic liquids opens up many possibilities to further tailor the properties of ionic liquids for ionothermal synthesis applications. The ionic liquid anions are not incorporated into the resultant materials. Copyright © 2007 American Chemical Society.

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U2 - 10.1021/ja0737671

DO - 10.1021/ja0737671

M3 - Article

SN - 0002-7863

VL - 129

SP - 10334

EP - 10335

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 34

ER -

Anion control in the lonothermal synthesis of coordination polymers

Abstract

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CCDC 665917: Experimental Crystal Structure Determination

CCDC 665916: Experimental Crystal Structure Determination

CCDC 665915: Experimental Crystal Structure Determination

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Anion control in the lonothermal synthesis of coordination polymers

Abstract

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Datasets

CCDC 665917: Experimental Crystal Structure Determination

CCDC 665916: Experimental Crystal Structure Determination

CCDC 665915: Experimental Crystal Structure Determination

Cite this