Asymmetric fluoro-organomercurials. Part 2. The synthesis and characterization of the fluorovinyl-mercurials RHgCXCF2 (R = Ph, Fc; X = F, Cl): The single crystal x-ray structures of PhHgCF:CF2, FcHgCF:CF2 and FcHgCCl:CF2 [Fc = (C5H5)Fe(C5H4-)]

Alan K Brisdon; Ian R Crossley; Robin G Pritchard; Ghazala Sadiq

Asymmetric fluoro-organomercurials. Part 2. The synthesis and characterization of the fluorovinyl-mercurials RHgCXCF2 (R = Ph, Fc; X = F, Cl): The single crystal x-ray structures of PhHgCF:CF2, FcHgCF:CF2 and FcHgCCl:CF2 [Fc = (C5H5)Fe(C5H4-)]

Alan K Brisdon, Ian R Crossley, Robin G Pritchard, Ghazala Sadiq

Research output: Contribution to journal › Article › peer-review

Abstract

The asym. fluorovinyl mercurials RHgCX:CF2 (X = F, R = Ph (79% yield), R = Fc (93%); X = Cl, R = Ph (88%), R = Fc (89%)) were prepd. from RHgCl and LiCX:CF2, the later being derived from the reaction of CF3CH2F (X = F) or CF3CH2Cl (X = Cl) and BuLi. All the complexes were fully characterized by spectroscopic methods and, apart from PhHgCCl:CF2, the compds. are sufficiently stable to be studied by single-crystal x-ray diffraction, making this the 1st report of structurally characterized asym. fluorovinyl mercurial complexes RHg(CX:CF2). In the solid state all of the structurally characterized complexes demonstrate asym. Hg-C distances and extensive intramol. Hg????????????F and Hg????????????????2-arene interactions are obsd. [on SciFinder(R)]

Original language	English
Pages (from-to)	2125-2130
Journal	J. Organomet. Chem. FIELD Full Journal Title:Journal of Organometallic Chemistry
Volume	692
Issue number	11
Publication status	Published - 2007

Keywords

Bond length (carbon-metal, mercury
prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes)
NMR (multinuclear, 19F, 13C
Crystal structure
Molecular structure (of asym. fluorovinyl phenylmercury and ferrocenylmercury complexes)
Supramolecular structure (prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes)
Group IIB element complexes Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes)
fluoro alkane lithiation reaction phenylmercury ferrocenylmercury chloride
crystal mol structure asym fluorovinyl phenylmercury ferrocenylmercury complex prepn

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Brisdon, A. K., Crossley, I. R., Pritchard, R. G., & Sadiq, G. (2007). Asymmetric fluoro-organomercurials. Part 2. The synthesis and characterization of the fluorovinyl-mercurials RHgCXCF2 (R = Ph, Fc; X = F, Cl): The single crystal x-ray structures of PhHgCF:CF2, FcHgCF:CF2 and FcHgCCl:CF2 [Fc = (C5H5)Fe(C5H4-)]. J. Organomet. Chem. FIELD Full Journal Title:Journal of Organometallic Chemistry, 692(11), 2125-2130.

Brisdon, Alan K ; Crossley, Ian R ; Pritchard, Robin G et al. / Asymmetric fluoro-organomercurials. Part 2. The synthesis and characterization of the fluorovinyl-mercurials RHgCXCF2 (R = Ph, Fc; X = F, Cl): The single crystal x-ray structures of PhHgCF:CF2, FcHgCF:CF2 and FcHgCCl:CF2 [Fc = (C5H5)Fe(C5H4-)]. In: J. Organomet. Chem. FIELD Full Journal Title:Journal of Organometallic Chemistry. 2007 ; Vol. 692, No. 11. pp. 2125-2130.

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title = "Asymmetric fluoro-organomercurials. Part 2. The synthesis and characterization of the fluorovinyl-mercurials RHgCXCF2 (R = Ph, Fc; X = F, Cl): The single crystal x-ray structures of PhHgCF:CF2, FcHgCF:CF2 and FcHgCCl:CF2 [Fc = (C5H5)Fe(C5H4-)]",

abstract = "The asym. fluorovinyl mercurials RHgCX:CF2 (X = F, R = Ph (79% yield), R = Fc (93%); X = Cl, R = Ph (88%), R = Fc (89%)) were prepd. from RHgCl and LiCX:CF2, the later being derived from the reaction of CF3CH2F (X = F) or CF3CH2Cl (X = Cl) and BuLi. All the complexes were fully characterized by spectroscopic methods and, apart from PhHgCCl:CF2, the compds. are sufficiently stable to be studied by single-crystal x-ray diffraction, making this the 1st report of structurally characterized asym. fluorovinyl mercurial complexes RHg(CX:CF2). In the solid state all of the structurally characterized complexes demonstrate asym. Hg-C distances and extensive intramol. Hg????????????F and Hg????????????????2-arene interactions are obsd. [on SciFinder(R)]",

keywords = "Bond length (carbon-metal, mercury, prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes), NMR (multinuclear, 19F, 13C, Crystal structure, Molecular structure (of asym. fluorovinyl phenylmercury and ferrocenylmercury complexes), Supramolecular structure (prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes), Group IIB element complexes Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes), fluoro alkane lithiation reaction phenylmercury ferrocenylmercury chloride, crystal mol structure asym fluorovinyl phenylmercury ferrocenylmercury complex prepn",

author = "Brisdon, {Alan K} and Crossley, {Ian R} and Pritchard, {Robin G} and Ghazala Sadiq",

note = "CAN 147:31178 29-9 Organometallic and Organometalloidal Compounds Journal 0022-328X written in English 658-71-9P; 938168-24-2P; 938168-26-4P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (crystal structure; prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes); 75-88-7 (HCFC-133a); 100-56-1 (Phenylmercury chloride); 811-97-2 (HFC-134a); 1273-75-2 (Ferrocenylmercury chloride) Role: RCT (Reactant), RACT (Reactant or reagent) (prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes); 938168-25-3P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes)",

year = "2007",

language = "English",

volume = "692",

pages = "2125--2130",

journal = "J. Organomet. Chem. FIELD Full Journal Title:Journal of Organometallic Chemistry",

publisher = "Elsevier BV",

number = "11",

}

Brisdon, AK, Crossley, IR, Pritchard, RG & Sadiq, G 2007, 'Asymmetric fluoro-organomercurials. Part 2. The synthesis and characterization of the fluorovinyl-mercurials RHgCXCF2 (R = Ph, Fc; X = F, Cl): The single crystal x-ray structures of PhHgCF:CF2, FcHgCF:CF2 and FcHgCCl:CF2 [Fc = (C5H5)Fe(C5H4-)]', J. Organomet. Chem. FIELD Full Journal Title:Journal of Organometallic Chemistry, vol. 692, no. 11, pp. 2125-2130.

Asymmetric fluoro-organomercurials. Part 2. The synthesis and characterization of the fluorovinyl-mercurials RHgCXCF2 (R = Ph, Fc; X = F, Cl): The single crystal x-ray structures of PhHgCF:CF2, FcHgCF:CF2 and FcHgCCl:CF2 [Fc = (C5H5)Fe(C5H4-)]. / Brisdon, Alan K; Crossley, Ian R; Pritchard, Robin G et al.
In: J. Organomet. Chem. FIELD Full Journal Title:Journal of Organometallic Chemistry, Vol. 692, No. 11, 2007, p. 2125-2130.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Asymmetric fluoro-organomercurials. Part 2. The synthesis and characterization of the fluorovinyl-mercurials RHgCXCF2 (R = Ph, Fc; X = F, Cl): The single crystal x-ray structures of PhHgCF:CF2, FcHgCF:CF2 and FcHgCCl:CF2 [Fc = (C5H5)Fe(C5H4-)]

AU - Brisdon, Alan K

AU - Crossley, Ian R

AU - Pritchard, Robin G

AU - Sadiq, Ghazala

N1 - CAN 147:31178 29-9 Organometallic and Organometalloidal Compounds Journal 0022-328X written in English 658-71-9P; 938168-24-2P; 938168-26-4P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (crystal structure; prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes); 75-88-7 (HCFC-133a); 100-56-1 (Phenylmercury chloride); 811-97-2 (HFC-134a); 1273-75-2 (Ferrocenylmercury chloride) Role: RCT (Reactant), RACT (Reactant or reagent) (prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes); 938168-25-3P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes)

PY - 2007

Y1 - 2007

N2 - The asym. fluorovinyl mercurials RHgCX:CF2 (X = F, R = Ph (79% yield), R = Fc (93%); X = Cl, R = Ph (88%), R = Fc (89%)) were prepd. from RHgCl and LiCX:CF2, the later being derived from the reaction of CF3CH2F (X = F) or CF3CH2Cl (X = Cl) and BuLi. All the complexes were fully characterized by spectroscopic methods and, apart from PhHgCCl:CF2, the compds. are sufficiently stable to be studied by single-crystal x-ray diffraction, making this the 1st report of structurally characterized asym. fluorovinyl mercurial complexes RHg(CX:CF2). In the solid state all of the structurally characterized complexes demonstrate asym. Hg-C distances and extensive intramol. Hg????????????F and Hg????????????????2-arene interactions are obsd. [on SciFinder(R)]

AB - The asym. fluorovinyl mercurials RHgCX:CF2 (X = F, R = Ph (79% yield), R = Fc (93%); X = Cl, R = Ph (88%), R = Fc (89%)) were prepd. from RHgCl and LiCX:CF2, the later being derived from the reaction of CF3CH2F (X = F) or CF3CH2Cl (X = Cl) and BuLi. All the complexes were fully characterized by spectroscopic methods and, apart from PhHgCCl:CF2, the compds. are sufficiently stable to be studied by single-crystal x-ray diffraction, making this the 1st report of structurally characterized asym. fluorovinyl mercurial complexes RHg(CX:CF2). In the solid state all of the structurally characterized complexes demonstrate asym. Hg-C distances and extensive intramol. Hg????????????F and Hg????????????????2-arene interactions are obsd. [on SciFinder(R)]

KW - Bond length (carbon-metal, mercury

KW - prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes)

KW - NMR (multinuclear, 19F, 13C

KW - Crystal structure

KW - Molecular structure (of asym. fluorovinyl phenylmercury and ferrocenylmercury complexes)

KW - Supramolecular structure (prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes)

KW - Group IIB element complexes Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and structures of asym. fluorovinyl mercury complexes via phenylmercury or ferrocenylmercury chloride and fluoro alkanes)

KW - fluoro alkane lithiation reaction phenylmercury ferrocenylmercury chloride

KW - crystal mol structure asym fluorovinyl phenylmercury ferrocenylmercury complex prepn

M3 - Article

VL - 692

SP - 2125

EP - 2130

JO - J. Organomet. Chem. FIELD Full Journal Title:Journal of Organometallic Chemistry

JF - J. Organomet. Chem. FIELD Full Journal Title:Journal of Organometallic Chemistry

IS - 11

ER -

Brisdon AK, Crossley IR, Pritchard RG, Sadiq G. Asymmetric fluoro-organomercurials. Part 2. The synthesis and characterization of the fluorovinyl-mercurials RHgCXCF2 (R = Ph, Fc; X = F, Cl): The single crystal x-ray structures of PhHgCF:CF2, FcHgCF:CF2 and FcHgCCl:CF2 [Fc = (C5H5)Fe(C5H4-)]. J. Organomet. Chem. FIELD Full Journal Title:Journal of Organometallic Chemistry. 2007;692(11):2125-2130.