TY - GEN
T1 - Asymmetric hydrogenation of nitroalkenes using Clostridium sporogenes
AU - Sadeghi, Abbas
AU - Hatziantoniou, Dimitris
AU - Gardiner, John M
AU - Stephens, Gillian
N1 - CAN 143:458633 16-5 Fermentation and Bioindustrial Chemistry Chemical Engineering,UMIST,Manchester,UK. Conference written in English. 50-99-7 (D-Glucose); 63-91-2 (L-Phenylalanine); 705-60-2 (2-Nitro-1-phenyl-1-propene); 1333-74-0 (Hydrogen) Role: BCP (Biochemical process), BIOL (Biological study), PROC (Process) (asym. hydrogenation of nitroalkenes using Clostridium sporogenes); 17322-34-8P (2-Nitro-1-phenylpropane) Role: BMF (Bioindustrial manufacture), BIOL (Biological study), PREP (Preparation) (asym. hydrogenation of nitroalkenes using Clostridium sporogenes); 70712-51-5 (Enoate reductase) Role: BSU (Biological study, unclassified), BIOL (Biological study) (asym. hydrogenation of nitroalkenes using Clostridium sporogenes)
PY - 2003
Y1 - 2003
N2 - The growth conditions for prodn. of C sporogenes were optimized to obtain maximal biocatalytic activity in harvested cells. The reaction conditions for C = C redn. using harvested cells were also optimized. The efficiency of electron donors for reducing cinnamate was in the order hydrogen>phenylalanine>glucose. The enantiopurity of the nitroalkene product depended on substrate concn., incubation time and pH in the reaction. [on SciFinder (R)]
AB - The growth conditions for prodn. of C sporogenes were optimized to obtain maximal biocatalytic activity in harvested cells. The reaction conditions for C = C redn. using harvested cells were also optimized. The efficiency of electron donors for reducing cinnamate was in the order hydrogen>phenylalanine>glucose. The enantiopurity of the nitroalkene product depended on substrate concn., incubation time and pH in the reaction. [on SciFinder (R)]
KW - Clostridium sporogenes
KW - Fermentation
KW - Hydrogenation (asym. hydrogenation of nitroalkenes using Clostridium sporogenes)
KW - pH (biol. effects of
KW - asym. hydrogenation of nitroalkenes using Clostridium sporogenes)
KW - Alkenes Role: BCP (Biochemical process), BIOL (Biological study), PROC (Process) (nitro
KW - Alkanes Role: BMF (Bioindustrial manufacture), BIOL (Biological study), PREP (Preparation) (nitro
KW - Clostridium nitroalkene hydrogenation
M3 - Conference contribution
VL - 4
BT - Majmoa-i Maghalat-i Sevomin Hemayesh Maliy Biotechnology Jomhoriy-i Islame-i Iran, Mashhad, Islamic Republic of Iran, Sept. 9-11, 2003
ER -