Atomic details of near-transition state conformers for enzyme phosphoryl transfer revealed by MgF-3 rather than by phosphoranes.

Chemistry

• Conformational Isomer 100%
• Transition State 100%
• Phosphoryl 100%
• Phosphorane 100%
• Transfer Reaction 66%
• Structure 33%
• Donor 33%
• Crystal Structure 33%
• Nuclear Overhauser Effect 33%
• Fluorine 33%
• Transition State Analog 33%
• Sugar Phosphate 33%
• Atomic Coordinate 33%
• 19F NMR Spectroscopy 33%
• Chemical Shift 33%
• NMR Spectroscopy 33%
• Electron Density 33%
• Reaction Intermediate 33%

Biochemistry, Genetics and Molecular Biology

• Phosphoglucomutase 100%
• Conformation 66%
• Crystal Structure 33%
• Static Electricity 33%
• Hydrogen Bond 33%
• Transition State Analog 33%
• Sugar Phosphate 33%