Aurophilicity under pressure:: a combined crystallographic and in situ spectroscopic study

Alice E. O'Connor; Nedaossadat Mirzadeh; Suresh K. Bhargava; Timothy L. Easun; Martin Schroeder; Alexander J. Blake

doi:10.1039/c6cc00923A

Aurophilicity under pressure: a combined crystallographic and in situ spectroscopic study

Alice E. O'Connor, Nedaossadat Mirzadeh, Suresh K. Bhargava, Timothy L. Easun, Martin Schroeder, Alexander J. Blake

Research output: Contribution to journal › Article › peer-review

54 Downloads (Pure)

Abstract

High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

Original language	English
Pages (from-to)	6769-6772
Journal	Chemical Communications
Volume	52
Issue number	41
DOIs	https://doi.org/10.1039/c6cc00923A
Publication status	Published - 2016

Access to Document

10.1039/c6cc00923A

c6cc00923aFinal published version, 2.95 MBLicence: CC BY

Cite this

@article{25f32e71eef44bf39beba1a9ca27e30d,

title = "Aurophilicity under pressure:: a combined crystallographic and in situ spectroscopic study",

abstract = "High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.",

author = "O'Connor, {Alice E.} and Nedaossadat Mirzadeh and Bhargava, {Suresh K.} and Easun, {Timothy L.} and Martin Schroeder and Blake, {Alexander J.}",

year = "2016",

doi = "10.1039/c6cc00923A",

language = "English",

volume = "52",

pages = "6769--6772",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "41",

}

TY - JOUR

T1 - Aurophilicity under pressure:

T2 - a combined crystallographic and in situ spectroscopic study

AU - O'Connor, Alice E.

AU - Mirzadeh, Nedaossadat

AU - Bhargava, Suresh K.

AU - Easun, Timothy L.

AU - Schroeder, Martin

AU - Blake, Alexander J.

PY - 2016

Y1 - 2016

N2 - High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

AB - High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

U2 - 10.1039/c6cc00923A

DO - 10.1039/c6cc00923A

M3 - Article

SN - 1359-7345

VL - 52

SP - 6769

EP - 6772

JO - Chemical Communications

JF - Chemical Communications

IS - 41

ER -

Aurophilicity under pressure: a combined crystallographic and in situ spectroscopic study

Abstract

Access to Document

Fingerprint

Cite this